National Institute Of Materials Physics - Romania

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111. A new method for obtaining the magnetic shape anisotropy directly from electron tomography images
Authors: Radu, C; Vlaicu, ID; Kuncser, AC

Published: JUL 5 2022, BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 13, DOI: 10.3762/bjnano.13.51

A new methodology to obtain magnetic information on magnetic nanoparticle (MNP) systems via electron tomography techniques is reported in this work. The new methodology is implemented in an under-development software package called Magn3t, written in Python and C++. A novel image-filtering technique that reduces the highly undesired diffraction effects in the tomography tiltseries has been also developed in order to increase the reliability of the correlations between morphology and magnetism. Using the Magn3t software, the magnetic shape anisotropy magnitude and direction of magnetite nanoparticles has been extracted for the first time directly from transmission electron tomography.
112. Beyond superconductivity towards novel biomedical, energy, ecology, and heritage applications of MgB2
Authors: Badica, P; Batalu, D

Published: JUL 3 2022, GREEN CHEMISTRY LETTERS AND REVIEWS, 15, DOI: 10.1080/17518253.2022.2124891

Twenty years passed since the discovery of superconductivity in MgB2. Although there is much progress, the use of superconductors, in general, and of MgB2 in particular, remains limited. On the other hand, in the last 10 years MgB2 became a material of great interest for emergent applications, such as propellants, batteries, and catalysis, as a source material to obtain 2D borophene-like materials (e.g. BH borophane), biomedical field (taking advantage of its promising antimicrobial, antitumoral, biodegradable, and biocompatible features), heritage and ecology being the latest trends. These new directions place MgB2 as a material well integrated with nature cycles that can promote the concept of one eco- and health-friendly, with many envisioned practical purposes. This type of material is at the core of a clean and sustainable economy promoting new developments, boosting the older ones (e.g. superconductivity) and minimizing the costs for the transition to new and modern materials and technologies. In this work, we review recent trends and new directions of MgB2 applications and discuss their potential impact.
113. The sustainable materials roadmap
Authors: Titirici, M; Baird, SG; Sparks, TD; Yang, SM; Brandt-Talbot, A; Hosseinaei, O; Harper, DP; Parker, RM; Vignolini, S; Berglund, LA; Li, YY; Gao, HL; Mao, LB; Yu, SH; Diez, N; Ferrero, GA; Sevilla, M; Szilagyi, PA; Stubbs, CJ; Worch, JC; Huang, YP; Luscombe, CK; Lee, KY; Luo, H; Platts, MJ; Tiwari, D; Kovalevskiy, D; Fermin, DJ; Au, H; Alptekin, H; Crespo-Ribadeneyra, M; Ting, VP; Fellinger, TP; Barrio, J; Westhead, O; Roy, C; Stephens, IEL; Nicolae, SA; Sarma, SC; Oates, RP; Wang, CG; Li, ZB; Loh, XJ; Myers, RJ; Heeren, N; Gregoire, A; Perisse, C; Zhao, XY; Vodovotz, Y; Earley, B; Finnveden, G; Bjorklund, A; Harper, GDJ; Walton, A; Anderson, PA

Published: JUL 1 2022, JOURNAL OF PHYSICS-MATERIALS, 5, 032001, DOI: 10.1088/2515-7639/ac4ee5

Over the past 150 years, our ability to produce and transform engineered materials has been responsible for our current high standards of living, especially in developed economies. However, we must carefully think of the effects our addiction to creating and using materials at this fast rate will have on the future generations. The way we currently make and use materials detrimentally affects the planet Earth, creating many severe environmental problems. It affects the next generations by putting in danger the future of the economy, energy, and climate. We are at the point where something must drastically change, and it must change now. We must create more sustainable materials alternatives using natural raw materials and inspiration from nature while making sure not to deplete important resources, i.e. in competition with the food chain supply. We must use less materials, eliminate the use of toxic materials and create a circular materials economy where reuse and recycle are priorities. We must develop sustainable methods for materials recycling and encourage design for disassembly. We must look across the whole materials life cycle from raw resources till end of life and apply thorough life cycle assessments (LCAs) based on reliable and relevant data to quantify sustainability. We need to seriously start thinking of where our future materials will come from and how could we track them, given that we are confronted with resource scarcity and geographical constrains. This is particularly important for the development of new and sustainable energy technologies, key to our transition to net zero. Currently 'critical materials' are central components of sustainable energy systems because they are the best performing. A few examples include the permanent magnets based on rare earth metals (Dy, Nd, Pr) used in wind turbines, Li and Co in Li-ion batteries, Pt and Ir in fuel cells and electrolysers, Si in solar cells just to mention a few. These materials are classified as 'critical' by the European Union and Department of Energy. Except in sustainable energy, materials are also key components in packaging, construction, and textile industry along with many other industrial sectors. This roadmap authored by prominent researchers working across disciplines in the very important field of sustainable materials is intended to highlight the outstanding issues that must be addressed and provide an insight into the pathways towards solving them adopted by the sustainable materials community. In compiling this roadmap, we hope to aid the development of the wider sustainable materials research community, providing a guide for academia, industry, government, and funding agencies in this critically important and rapidly developing research space which is key to future sustainability.
114. Antimicrobial Properties of TiO2 Microparticles Coated with Ca- and Cu-Based Composite Layers
Authors: Bucuresteanu, R; Ionita, M; Chihaia, V; Ficai, A; Trusca, RD; Ilie, CI; Kuncser, A; Holban, AM; Mihaescu, G; Petcu, G; Nicolaev, A; Costescu, RM; Husch, M; Parvulescu, V; Ditu, LM

Published: JUL 2022, INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 23, 6888, DOI: 10.3390/ijms23136888

The ability of TiO2 to generate reactive oxygen species under UV radiation makes it an efficient candidate in antimicrobial studies. In this context, the preparation of TiO2 microparticles coated with Ca- and Cu-based composite layers over which Cu(II), Cu(I), and Cu(0) species were identified is presented here. The obtained materials were characterized by a wide range of analytical methods, such as X-ray diffraction, electron microscopy (TEM, SEM), X-ray photoelectron (XPS), and UV-VIS spectroscopy. The antimicrobial efficiency was evaluated using qualitative and quantitative standard methods and standard clinical microbial strains. A significant aspect of this composite is that the antimicrobial properties were evidenced both in the presence and absence of the light, as result of competition between photo and electrical effects. However, the antibacterial effect was similar in darkness and light for all samples. Because no photocatalytic properties were found in the absence of copper, the results sustain the antibacterial effect of the electric field (generated by the electrostatic potential of the composite layer) both under the dark and in light conditions. In this way, the composite layers supported on the TiO2 microparticles' surface can offer continuous antibacterial protection and do not require the presence of a permanent light source for activation. However, the antimicrobial effect in the dark is more significant and is considered to be the result of the electric field effect generated on the composite layer.
115. Independent and complementary bio-functional effects of CuO and Ga2O3 incorporated as therapeutic agents in silica- and phosphate- based bioactive glasses
Authors: Tite, T; Popa, AC; Stuart, BW; Fernandes, HR; Chirica, IM; Lungu, GA; Macovei, D; Bartha, C; Albulescu, L; Tanase, C; Nita, S; Rusu, N; Grant, DM; Ferreira, JMF; Stan, GE

Published: JUL 2022, JOURNAL OF MATERIOMICS, 8, DOI: 10.1016/j.jmat.2021.12.009

The incorporation of therapeutic-capable ions into bioactive glasses (BGs), either based on silica (SBGs) or phosphate (PBGs), is currently envisaged as a proficient path for facilitating bone regeneration. In conjunction with this view, the single and complementary structural and bio-functional roles of CuO and Ga2O3 (in the 2-5 mol% range) were assessed, by deriving a series of SBG and PBG formulations starting from the parent glass systems, FastOs (R) BG -38.5SiO2-36.1CaO-5.6P2O5-19.2MgO-0.6CaF2, and 50.0P2O5-35.0CaO-10.0Na2O-5.0 Fe2O3 (mol%), respectively, using the process of melt-quenching. The inter-linked physico-chemistry -biological response of BGs was assessed in search of bio-functional triggers. Further light was shed on the structural role -as network former or modifier -of Cu and Ga, immersed in SBG and PBG matrices. The preliminary biological performance was surveyed in vitro by quantification of Cu and Ga ion release under homeostatic conditions, cytocompatibility assays (in fibroblast cell cultures) and antibacterial tests (against Staphylococcus aureus). The similar (Cu) and dissimilar (Ga) structural roles in the SBG and PBG vitreous networks governed their release. Namely, Cu ions were leached in similar concentrations (ranging from 10-35 ppm and 50-110 ppm at BG doses of 5 and 50 mg/mL, respectively) for both type of BGs, while the release of Ga ions was 1-2 orders of magnitude lower in the case of SBGs (i.e., 0.2-6 ppm) compared to PBGs (i.e., 9-135 ppm). This was attributed to the network modifier role of Cu in both types of BGs, and conversely, to the network former (SBGs) and network modifier (PBGs) roles of Ga. All glasses were cytocompatible at a dose of 5 mg/mL, while at the same concentration the antimicrobial efficiency was found to be accentuated by the coupled release of Cu and Ga ions from SBG. By collective assessment, the most prominent candidate material for the further development of implant coatings and bone graft substitutes was delineated as the 38.5SiO2-34.1CaO-5.6P2O5-16.2MgO-0.6CaF2-2.0CuO-3.0Ga2O3 (mol%) SBG system, which yiel-ded moderate Cu and Ga ion release, excellent cytocompatibility and marked antibacterial efficacy. (c) 2021 The Chinese Ceramic Society. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
116. Bioconjugates of mercaptocarboxylic acids functionalized AuNP and superoxide dismutase for superoxide electrochemical monitoring
Authors: Sanz, CG; Crisan, DN; Leote, RJB; Onea, M; Barsan, MM

Published: JUL 2022, MICROCHIMICA ACTA, 189, 245, DOI: 10.1007/s00604-022-05352-z

The use of gold nanoparticles/superoxide dismutase (AuNP/SOD) bioconjugates is described as building blocks in SOD biosensor development for the quantification of superoxide in cell culture media. AuNP functionalization with 11-mercaptoundecanoic acid (MUA) and 4-mercaptobenzoic acid (MBA) (AuNPMUA and AuNPMBA) was used to improve SOD immobilization through EDC/NHS coupling using their -COOH terminus, leading to the formation of more stable bioconjugates. AuNP and AuNP/SOD bioconjugates were characterized by SEM to determine their size and morphology, UV-Vis for optical properties, FT-IR, and Raman spectroscopies for chemical functional group analysis and EDX for elemental analysis. Electrochemical methods were used to characterize the Au/AuNP-modified electrodes. For the optimization of the biosensor architecture, different AuNP/enzyme bioconjugates were prepared by varying the amount of both enzyme and AuNP, as well as their incubation time. Finally, the biosensors incorporating the bioconjugates were characterized by fixed potential amperometry and voltammetric analysis in order to establish the enzymatic mechanism and to elucidate the best biosensor architecture for monitoring superoxide in cell culture media. The best sensitivity value for superoxide detection corresponded to 41.2 nA mu M cm(-2), achieved by a biosensor based on AuNPMBA/SOD bioconjugates monitored through fixed potential amperometry at 0.3 V vs. Ag/AgCl, with a limit of detection of 1.0 mu M, and overall very good operational stability, maintaining 91% of the initial sensitivity after 30 days. Finally, the optimized biosensor was employed for the quantification of successive additions of superoxide in cell culture media, with excellent recovery values.
117. PC-12 Cell Line as a Neuronal Cell Model for Biosensing Applications
Authors: Oprea, D; Sanz, CG; Barsan, MM; Enache, TA

Published: JUL 2022, BIOSENSORS-BASEL, 12, 500, DOI: 10.3390/bios12070500

PC-12 cells have been widely used as a neuronal line study model in many biosensing devices, mainly due to the neurogenic characteristics acquired after differentiation, such as high level of secreted neurotransmitter, neuron morphology characterized by neurite outgrowth, and expression of ion and neurotransmitter receptors. For understanding the pathophysiology processes involved in brain disorders, PC-12 cell line is extensively assessed in neuroscience research, including studies on neurotoxicity, neuroprotection, or neurosecretion. Various analytical technologies have been developed to investigate physicochemical processes and the biosensors based on optical and electrochemical techniques, among others, have been at the forefront of this development. This article summarizes the application of different biosensors in PC-12 cell cultures and presents the modern approaches employed in neuronal networks biosensing.
118. MgB2 with Addition of Cubic BN and Ge2C6H10O7 Obtained by Spark Plasma Sintering Technique
Authors: Ionescu, AM; Aldica, G; Popa, S; Enculescu, M; Sandu, V; Pasuk, I; Burdusel, M; Grigoroscuta, MA; Miu, L; Badica, P

Published: JUL 2022, JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, DOI: 10.1007/s10948-022-06350-1

High density (94-98% of the theoretical density) MgB2 samples added with C6H10Ge2O7 and cubic BN with compositions (MgB2)(1-x)(Ge2C6H10O7)(0.0028)(cBN)(x) (x = 0.003, 0.005, 0.007, 0.01) and (MgB2)(1-y)(Ge2C6H10O7)(y)(cBN)(0.005) (y = 0.0014, 0.0028, 0.005, 0.0075) were obtained by spark plasma sintering technique. For optimum doped samples with x = 0.005-0.007 and y = 0.0028-0.005, a weak enhancement of zero-field critical current density J(c0), irreversibility field H-irr, and volume pinning force F-p,F-max was determined. This behavior is very different from similar samples added with a single additive for which H-irr has a large enhancement. Consequently, it suggests the presence of opposite structural and microstructural effects induced by the additives. These effects, on the one hand, are discussed to decrease the sensitivity of MgB2 superconducting properties in the co-added samples comparative to samples added with C6H10Ge2O7, and, on the other hand, they contribute to anomalies that were found when assessing the pinning force-related parameters by the universal scaling law.
119. Electron trapping in magnetic driven graphene quantum dots
Authors: Pena, A

Published: JUL 2022, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 141, 115245, DOI: 10.1016/j.physe.2022.115245

In this paper we present an in-depth theoretical investigation of an electron scattering process on a graphene quantum dot (GQD) supposed to a perpendicular magnetic field. As it is well known, because of Klein tunneling, an electrostatic potential is not helpful to localize an electron inside a GQD. However, we report here that in the case of a magnetic driven GQD, there emerge scattering resonances characterized by trapped electronic states inside the dot for finite periods of time, otherwise known as quasi-bound states. Using a real space scattering analysis, we highlight in a very intuitive manner how the quasi-bound states are generated and, for a comprehensive investigation, we evaluate their corresponding lifetime (trapping time). As well, we explore the case of an electrostatically biased GQD. We show that this configuration may be very advantageous regarding the control of the trapping times which reach values much higher than in the unbiased case.
120. Recent Development in Nanoconfined Hydrides for Energy Storage
Authors: Comanescu, C

Published: JUL 2022, INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 23, 7111, DOI: 10.3390/ijms23137111

Hydrogen is the ultimate vector for a carbon-free, sustainable green-energy. While being the most promising candidate to serve this purpose, hydrogen inherits a series of characteristics making it particularly difficult to handle, store, transport and use in a safe manner. The researchers' attention has thus shifted to storing hydrogen in its more manageable forms: the light metal hydrides and related derivatives (ammonia-borane, tetrahydridoborates/borohydrides, tetrahydridoaluminates/alanates or reactive hydride composites). Even then, the thermodynamic and kinetic behavior faces either too high energy barriers or sluggish kinetics (or both), and an efficient tool to overcome these issues is through nanoconfinement. Nanoconfined energy storage materials are the current state-of-the-art approach regarding hydrogen storage field, and the current review aims to summarize the most recent progress in this intriguing field. The latest reviews concerning H-2 production and storage are discussed, and the shift from bulk to nanomaterials is described in the context of physical and chemical aspects of nanoconfinement effects in the obtained nanocomposites. The types of hosts used for hydrogen materials are divided in classes of substances, the mean of hydride inclusion in said hosts and the classes of hydrogen storage materials are presented with their most recent trends and future prospects.

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