National Institute Of Materials Physics - Romania

GeTe and GaSb thin films obtained by pulsed laser deposition were investigated by spectroscopic ellipsometry at controlled temperatures. The GeTe films were fully amorphous, while the GaSb films were partially crystalized in the as-deposited state. The Tauc-Lorentz model was employed to fit the experimental data. From the temperature study of the optical constants, it was observed the crystallization in the 150-160 degrees C range of GeTe amorphous films and between 230 and 240 degrees C of GaSb amorphous phase. A second transition in the resonance energy and the broadening parameter of the Lorentz oscillator was observed due to the crystallization of Sb after 250 degrees C. The temperatures of 85 degrees C and 130 degrees C are noticed as the start of the relaxation of the amorphous GeTe phase and as-deposited GaSb. The peaks of the imaginary part of the dielectric function red shifted after the phase change, while the variation with temperature of the crystalline phase follows the Varshni law. The electron-phonon coupling constants are 2.88 and 1.64 for c-GeTe and c-GaSb, respectively. An optical contrast up to 60% was obtained for GeTe films and a maximum value of 7.5% is revealed in the case GaSb, which is altered by the partial crystallinity of the as-deposited films. (C) 2015 AIP Publishing LLC.

The non-absorption of photons with energies below the bandgap (E-g) and the thermalization of photons with energies higher than E-g are the dominant loss processes of single-junction solar cells. Rare earth doped glasses give the opportunity to convert the incident photons wavelength and hence to increase or decrease their energies. The conversion of photons energies by "up or down conversion" leads to the possibility to increase the efficiencies of all classes of single-junction solar cells. Depending on the nature of doping materials, two low energy photons can be converted into one high-energy photon (up-conversion), or one high energy photon, can be converted into two low energy photons (down-conversion). In this paper, Pr3+-Yb3+ down-conversion co-doped ZBLA glasses were tested as encapsulation materials for silicon solar cells. The J-V characterizations were done under solar simulator irradiation. The influence of Yb3+ concentration on the solar cells performances was investigated, showing that an optimum value between 0.5 and 2 mol% conducts to an increase of the device efficiency comparing to mono-doped ZBLA material. (C) 2015 Elsevier B.V. All rights reserved.

Enhancement at low temperatures of the Raman scattering excited by laser light situated near the edge of the fundamental absorption band is often encountered when studying nanoscale structures. Theory devoted to this phenomenon has established that it originates in an exciton-phonon interaction process, known as the Frohlich interaction, Such a phenomenon was observed in PbI2. The experimental data conclude that the enhancement of the Raman emission results from: (i) an optical excitation near edge of fundamental absorption band; (ii) it is conditioned by the existence of excitonic PL; (iii) its occurrence is different over stokes and anti-stokes Raman branches as result of the different overlapping of the Raman spectral range and the excitonic PL band profile; and (iv) it appears more intense in micrometric powders or in bulk crystalline material. These data are interpreted as stimulated Raman effect resulting from the mixing of the pump laser light and the excitonic light. (C) 2015 Elsevier Ltd. All rights reserved.

Mn doped ZnO films and wires, having different manganese concentrations were synthesized by thermal oxidation of the corresponding ZnMn alloy films and wires electrodeposited on a gold substrate. Structural and optical properties were addressed with scanning electron microscopy, X-ray diffraction (XRD), Raman scattering and photoluminescence (PL). To estimate the manganese concentration in Mn doped ZnO films, X-ray photoelectron spectroscopy was used. XRD patterns indicate that the incorporation of Mn2+ ions into the Zn2+ site of ZnO lattice takes place. Quenching of the ZnO PL appears due to Mn2+ ions in the ZnO lattice. Moreover, a significant decrease in the green emission of ZnO is reported in the case of the Mn doped ZnO wire array with a Mn concentration of 1.45%. The wurtzite ZnO has a total of 12 phonon modes, namely, one longitudinal acoustic (LA), two transverse acoustic (TA), three longitudinal optical (LO), and six transverse optical branches. Compared to the undoped ZnO, a gradual up-shift of the Raman lines assigned to the 2LA and A(1) (LO) vibrational modes, from 482 and 567 cm(-1) to 532 and 580 cm(-1), respectively, takes place for the Mn doped ZnO films having a Mn concentration between 2 and 15%. Additionally, in the case of the Mn doped ZnO films with 7 and 15% Mn concentration, Raman spectra show the appearance and increase in the relative intensity of the ZnO Raman line assigned to the TA + LO vibrational mode in the 600-750 cm(-1) spectral range. For the Mn-doped ZnO wires, the presence of the Raman line peaking at 527 cm(-1) confirms the insertion of Mn2+ ions in ZnO lattice. (C) 2015 Elsevier B.V. All rights reserved.

The radical polymerization of aniline hydrochloride (ANIHCl) in the presence of ammonium persulfate was studied. 1D-Polyaniline (PANI) with fibrillar morphologies was obtained in the presence of anionic surfactants. The changes of the PANI-template structures in aqueous solution were studied using static fluorescence measurements. The dispersed PANI nanoparticles were characterized using dynamic light scattering, scanning electron microscopy (SEM), and Raman and Fourier transform infrared spectroscopies. The thermal analysis and the electrical conductivity of the dried samples were also performed. The fluorescence measurements indicated that nanocrystals of ANIHCl form in water complexes with the anionic surfactants at smaller concentrations than the critical micellar concentration. The same method revealed that other organic complexes with sulfonate groups do not induce an increase of the hydrophobic region due to short hydrocarbon tails. The SEM micrographs and Raman spectra revealed that the PANI nanofibers are compact and different compared to the nanoparticles prepared without surfactants.

Photoluminescence properties of the glass-ceramics microrods containing Eu3+-doped LiYF4 nanocrystals have been studied and characterized. Judd-Ofelt parameters and quantum efficiency has been computed from luminescence spectra and discussed by comparison to the glass ceramic bulk and pellet. The radiative decay rate A(rad) is higher in the glass ceramic rods (221 s(-1)) than in the glass ceramic bulk (130 s(-1)) but the quantum efficiency computed is very low (21%) compared to the glass-ceramic bulk (97%). There are effective non-radiative decay channels that might be related to an influence of the dimensional constraints imposed by the membrane pores during xerogel formation and subsequent glass ceramization. (C) 2015 Elsevier B.V. All rights reserved.

In this work, the architecture of ZnO particles was found to be changed from nano-whiskers to flowers via the addition of fullerenes in the reaction mixture consisting of zinc chloride, sodium hydroxide and sodium dodecyl sulfate. The change in the morphological structure of ZnO particles is accompanied by a decrease in the photoluminescence (PL) intensity and the appearance of a new Raman line at 1594 cm(-1) that indicates the formation of the compound ZnC60. The growth of the ZnO flower-like particles occurs simultaneously with an aggregation process of C-60 in highly ordered structures, as evidenced in the Raman spectrum by a line at 2934 cm I. A mechanism for the growth of the ZnO flower-like particles is proposed in this work. (C) 2015 Elsevier B.V. All rights reserved.

In this study we aimed to evaluate the biocompatibility and antimicrobial activity of kanamycin functionalized 5 nm-magnetite (Fe3O(4)@ KAN) nanoparticles thin films deposited by Matrix Assisted Pulsed Laser Evaporation (MAPLE) technique. A laser deposition regime was established in order to stoichiometrically transfer Fe3O4@ KAN thin films on silicone and glass substrates. Morphological and physico-chemical properties of powders and coatings were characterized by XRD, TEM, SEM, AFM and IR microscopy(IRM). Our nanostructured thin films have proved efficiency in the prevention of microbial adhesion and mature biofilms development as a result of antibiotic release in its active form. Furthermore, kanamycin functionalized nanostructures exhibit a good biocompatibility, both in vivo and in vitro, demonstrating their potential for implants application. This is the first study reporting the assessment of the in vivo biocompatibility of a magnetite-antimicrobial thin films produced by MAPLE technique. (C) 2014 Elsevier B.V. All rights reserved.

This paper presents some studies about the preparation by matrix-assisted pulsed laser evaporation (MAPLE) technique of heterostructures with single layer of arylene based polymer, poly[N-(2-ethylhexy1)2.7-carbazoly1 vinylene]/AMC16 and poly[N-(2-ethylhexy1)2.7-carbazolyl 1.4-phenylene ethynylene]/AMC22, and with layers of these polymers mixed with Buckminsterfullerene/C-60 in the weight ratio of 1:2 (AMC16: C60) and 1:3 (AMC22: C60). The deposited layers have been characterized by spectroscopic (UV-Vis-NIR, PL, FTIR) and microscopic (SEM, AFM) methods. The effect of the polymer particularities on the optical and electrical properties of the structures based on polymer and polymer: C-60 mixed layer has been analyzed. The study of the electrical properties has revealed typical solar cell behavior for the heterostructure prepared by MAPLE on glass/ITO/PEDOT-PSS with AMC16, AMC22 and AMC22: C-60 layer, confirming that this method is adequate for the preparation of polymeric and mixed active layers for solar cells applications. The highest photovoltaic effect was shown by the solar cell structure realized with single layer of AMC16 polymer: g1a55/ITO/PEDOT-PSSIA1VIC16/A1. (C) 2014 Elsevier B.V. All rights reserved.

Laser pulse processing of surfaces and thin films is a useful tool for amorphous thin films crystallization, surface nanostructuring, phase transformation and modification of physical properties of thin films. Here we show the effects of nanostructuring produced at the surface and under the surface of amorphous GeTiO films through laser pulses using fluences of 10-30 mJ/cm(2). The GeTiO films were obtained by RF magnetron sputtering with 50:50 initial atomic ratio of Ge:TiO2. Laser irradiation was performed by using the fourth harmonic (266 nm) of a Nd:YAG laser. The laser-induced nanostructuring results in two effects, the first one is the appearance of a wave-like topography at the film surface, with a periodicity of 200 nm and the second one is the structure modification of a layer under the film surface, at a depth that is related to the absorption length of the laser radiation. The periodicity of the wave-like relief is smaller than the laser wavelength. In the modified layer, the Ge atoms are segregated in spherical amorphous nanoparticles as a result of the fast diffusion of Ge atoms in the amorphous GeTiO matrix. The temperature estimation of the film surface during the laser pulses shows a maximum of about 500 degrees C, which is much lower than the melting temperature of the GeTiO matrix. GeO gas is formed at laser fluences higher than 20 mJ/cm(2) and produces nanovoids in the laser-modified layer at the film surface. A glass transition at low temperatures could happen in the amorphous GeTiO film, which explains the formation of the wave-like topography. The very high Ge diffusivity during the laser pulse action, which is characteristic for liquids, cannot be reached in a viscous matrix. Our experiments show that the diffusivity of atomic and molecular species such as Ge and GeO is very much enhanced in the presence of the laser pulse field. Consequently, the fast diffusion drives the formation of amorphous Ge nanoparticles through the segregation of Ge atoms in the GeTiO matrix. The nanostructuring effects induced by the laser irradiation can be used in functionalizing the surface of the films.