National Institute Of Materials Physics - Romania

UV-VIS transmission and fluorescence spectroscopy have been used to study some intrinsic properties of crystalline films of pure metadinitrobenzene (m-DNB) and, pure and doped benzil. We have evaluated the band gap energy, E-g = 2.92 eV, emphasising the near classical semiconductor behaviour of m-DNB. The two bands split of the (n, pi*) level is assumed to be the origin the two edges absorption in benzil films with the energetic thresholds at E-g1 = 2.84 eV and E-g2 = 3.55 eV. The red shift of the emission peak in m-DNB films has been correlated with the process of self-absorption of the emitted radiation in the thicker film. The effect of the impurities on the shape and position of the emission peaks in benzil has been investigated and we have observed no significant shift of the absorption peak situated at 3.25 eV. We also have identified a three steps process for the relaxation of the excited crystalline lattice of benzil involving the geometrical change of the (S-1) excited state, the intersystem crossing and the radiative decay by phosphorescence with a peak at 2.30 eV. The small blue shift of this emission peak in benzil highly doped with sodium has been attributed to the modification of the molecular geometry of benzil as a result of the change in the trans-planar molecular configuration induced by the chemical reaction between the atoms of alkali metal and the carbonyl groups. (C) 2004 Elsevier B.V All rights reserved.

Manganese and copper doped CdS nanowires were obtained by the template technique in a two step process. In the first step metallic alloy CdMnCu nano and microwires were electrodeposited in ion track membranes with pore diameters in the range 150 nm-2 mum. In the following step the resulted nanowires were anodized in a sodium sulphide alkaline solution. Electron microscopy results show participation of the whole metallic wire in the anodization process; manganese and copper doped CdS wires are obtained The composition of micro and nanowires was determined by energy dispersive X-ray analysis.

Hydroxyapatite (HA) thin films has been successfully deposited by Nd:YAG laser ablation lambda = 532 nm. The morphology and microstructure of the deposited layers was studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high resolution electron microscopy (HREM). Polycrystalline HA films were directly obtained with the substrate at 300 degreesC and without introducing water vapors in the deposition chamber. Electron paramagnetic resonance (EPR) measurements show that the oxygen stoichiometry in the HA films is also maintained. Depositions performed at lambda = 335 nm laser wavelength and 300 degreesC substrate temperature resulted in polycrystalline layers of mixed composition of HA and tricalciumphosphate (TCP). (C) 2004 Elsevier Ltd. All rights reserved.

The atomic ordering of the amorphous diamond-like carbon at the scale larger than short-range order is directly related to the characteristics of the array of interstitial voids. The large interstitial voids are responsible for the first diffraction peak, while the smaller ones (second and third order size of the voids) are responsible especially for the intensity and position of the second peaks in the interference function (structure factor).

A binary telluride (CdTe) as well as a ternary telluride (PbSeTe) were electrodeposited in the pores of a track-etched polycarbonate membrane, resulting nanowires and nanotubes. Either acid or alkaline solutions were used for preparing CdTe compound, whereas the ternary PbSe1-xTex compound was deposited from an acid solution, only. The investigation of electrode mechanisms was performed by cyclic voltammetry. The nanostructures were visualized using scanning electron microscopy (SEM).

Modelling of several large molecular clusters possible to be formed in non-crystalline arsenic chalcogenides (As2S3, As2Se3 or mixed compositions) during cooling down of the melts has been performed. The structure of minimum free energy was calculated in the frame of valence force field theory using a Monte-Carlo-Metropolis method. The structural characteristics of the clusters were computed after energy relaxation. There was demonstrated that specific cluster configurations of the type nano-hat, nano-pie and nanotube are crystallo-chemically compatible with the non-crystalline structure of the arsenic chalcogenides.

Selenium-sulphur layers prepared by warm pressing or deposited by pulsed laser deposition (PLD) on silicon wafers were subjected to laser pulses in order to test the possibility of recording the optical information in these glassy materials. There was demonstrated that the contrast of reflectivity between the irradiated places and the amorphous matrix could be used for storage of information at a reasonable density.

Surface-enhanced Raman scattering (SERS) and cyclic voltammetry (CV) were used to investigate oxidation-reduction processes of single-wall carbon nanotube (SWNT) films deposited on Au supports in 0.5 M H2SO4 solutions. In the potential range (0; +1000) and (0; +1500)mV versus saturated calomel electrode (SCE), the oxidation-reduction reactions of SWNT films are quasi-reversible and irreversible, respectively. Anodic polarization of SWNT films until +1000 mV versus SCE produced compounds similar to the bisulfate intercalated graphite. Regardless of excitation wavelength, i.e. 1064 or 676.4 nm, variation in the Raman spectra exhibited a decrease in the intensity of the bands associated with the radial breathing mode (RBM) situated in the 120-240 cm(-1) spectral range. Also an increase in the intensity of the D band is accompanied an up-shift of this band. A gradual decrease of the Breit-Wigner-Fano component was observed at lambda(exc) = 676.4 mn. Partial restoration of the Raman spectra was achieved by a subsequent alkaline solution treatment. Potentials higher than +1000 mV versus SCE resulted in SWNTs breakage and fragments of different length were formed such as closed-shell fullerene. This was observed in the SERS spectrum by: (i) the disappearance of the RBM band, (ii) the increased D-band shifted to ca. 1330 cm(-1) and (iii) the appearance of a new band at 1494 cm(-1), frequently observed also in the Raman spectrum of fullerenes on the type C-70, C-84, C-119, as well as in its derivative compounds (e.g. C60O, clathrates, etc.). Appearance and increase in the intensity of the Raman band at 1494 cm(-1) as result of an anodic polarization of the SWNT film in solution of H2SO4 0.5 M in 1-butanol is a further evidence of the nanotubes breakage. (C) 2004 Elsevier B.V. All rights reserved.

Modeling of nano-tube clusters based on As,S(Se)(3) has been performed. The structural data were calculated on a single nano-tube model of As2S3. For the first time electron microscope images of nanometer size objects in As2Se3 and AS(5.5)Se(4.5) glass have been observed and discussed.

Scanning electron microscopy, Raman scattering, UV-VIS absorption spectroscopy and low temperature photoluminescence (PL) were used to examine small particles produced by the chemical reaction between Pb(NO3)(2) and KI in different liquid media: water, methanol, ethanol and acetonitrile. By stoichiometric changes in the synthesis reaction, platelets of PbI2 and rods probably of KPbI3 are produced. Regardless of shape and size, these particles exhibit almost the same PL, which consists of two intense bands centred around the 2.5 (E band) and 2.0 eV (G band), in turn similar to that of a crystalline slide or a micrometric powder, both prepared from a PbI2 single-crystal grown from the melt. Crystalline PbI2 platelets exhibit an E band with two components, at 2.49 (E-F band) and 2.47 eV (E-T band), originating in the recombination of the free and trapped excitons produced by inter-band irradiation. A close relation between the enhancement of the E-T and G band reveals that they are linked to the surface defects. For the rod-like particles, the PL spectrum is somewhat similar to that of a Pb2+ ion introduced into an alkaline halide lattice, which as for any ns(2) ion displays two emission bands, A(T) and A(X), whose correspondents are E and G bands.