National Institute Of Materials Physics - Romania

Samples of LaNi5-xFex were prepared by arc melting and subsequent melt spinning procedure. Structural, magnetic and Mossbauer investigations were performed for physical characterization while the hydrogen storage properties were carefully analyzed. Detailed discussions concerning the sample's quality, the site assignment, the effect of temperature and applied fields on hyperfine parameters and the related Debye temperatures were provided. (C) 2008 Elsevier B.V. All rights reserved.

Six tetranuclear complexes [Fe(III)(3)Ln(mu(3)-O)(2)(CCl3COO)(8)(H2O)(THF)(3)]center dot THF center dot C7H16 [Ln=Gd(III) (1), Tb(III) (2), Dy(III) (3), Ho(III) (4), Y(III) (5), and Lu(III) (6)] have been studied by magnetic susceptibility and Moumlssbauer spectroscopy. These isostructural molecules have a "butterfly" structure core consisting of two Fe(2)Ln(mu(3)-O) triangular "wings" which share a common Ln-Fe "body"; the dihedral angle between the wings is ca. 148 degrees. The coordination spheres of the iron ions are essentially distorted octahedral. The lanthanides are eight-coordinate with coordination polyhedra that may be described as distorted tetragonal bipyramids. Variable-temperature solid-state magnetic susceptibility in the temperature range 1.8-300 K and magnetization at 1.8 K for compounds 1-6 were measured. The spin state of Fe is S=5/2 in all cases. In compounds 5 and 6, where Ln(III) (Y and Lu, respectively) is diamagnetic, the three Fe atoms form an obtuse isosceles triangle with antiferromagnetic interactions J(Fe-Fe)=-50 K between the wing-tip Fe-w and body Fe-b atoms, and negligible interaction between the Fe-w's, resulting in a ground state of effective spin S=5/2 per cluster. In the complexes with paramagnetic lanthanide ions, the interaction between the Fe-3 triangle and the Ln(III) center is described by an effective exchange constant which is antiferromagnetic and 1 order of magnitude weaker. Besides, at 3 K incipient spin blocking, characteristic of single molecule magnets, was found to occur in the out-of-phase component of the ac susceptibility in {Fe3TbO2}, {Fe3DyO2}, and {Fe3HoO2}. The activation energy of a Debye process describing the magnetization reversal has been determined to be, E-a approximate to 8, 9, and 10 K for the Ln=Tb, Dy, and Ho, respectively, and the prefactor tau(0)approximate to 10(-7) s. The high spin states of the Fe(III) centers were confirmed by the Moumlssbauer spectra, in which two distinguishable Fe sites could be resolved above 80 K, corresponding to the Fe-w and Fe-b sites, respectively. Relatively larger values of the quadrupole splitting of the Moumlssbauer spectra were observed for the Fe-w pair as compared with that for the Fe-b, and both quadrupole splittings diminished with increasing temperature. At 3 K the Moumlssbauer spectra showed a state with blocked spins (sextets) for the {Fe3TbO2} and {Fe3DyO2} cases. From the E-a and tau(0), determined in the ac susceptibility, the relaxation time at 3 K is estimated as tau approximate to 10(-5)-10(-6) s much longer than the time window of Moumlssbauer spectroscopy and compatible with the single molecule magnet behavior. In the presence of a strong magnetic field the moments of the Ln(III) cation and the Fe-3 triangle are polarized. For some compounds at low temperature a magnetic pattern (sextet) for each of the three Fe sites appeared, and the antiferromagnetic coupling within the Fe-3 cluster was directly proved by the opposite trend of the field dependence of the two Fe-w sextets as compared with the Fe-b third one.

In order to study the mechanism of the small n-value for Bi2212, E - J characteristics were measured carefully for various kinds of Bi2212 tapes and round wires in high magnetic fields. Some of wires were heat-treated in a magnetic field of 5 T. We found that the n-values of all the samples increase by the in-field heat-treatment at 5 T. In addition, we analyzed the E - J properties by the combination of the percolation model based on the local J(c) distribution and the two directional J(c) distribution model. The improvement of the n-value by the in-field heat treatment can be understood by the change of the aspect-ratio of the grains. Therefore, the aspect-ratio of the grains plays an important role in the current transport influencing not only J(c) but also n-value.

We attempted to grow non-c axis heterostructures of substrate-IS type with S = BSCCO and I = (Sr, Ca)CuO(2). A careful selection of the films-substrate relationship is revealed as a key condition toward growth of layered heterostructures with different orientations. However this powerful principle, that is also a mandatory condition, is not sufficient in order to obtain high quality structures. The reasons are discussed looking for further solutions. Our comparative analysis is expanded to other heterostructures we reported in other works trying to reveal some of the more general problems of the non c-axis heterostructures growth.

For power applications of superconducting films, the critical current density (J(c)) and the thickness of the film (d) should be as high as possible. Since J(c) decreases with both thickness and magnetic field, artificial pinning centers in addition to natural ones are required to keep J(c) high. The earliest cost-effective method used for introducing artificial pinning centers was the so-called substrate decoration, i.e., growing nanoscale islands (nano-dots) of certain materials on the substrate prior to the deposition of the superconducting thin film. Later on other two approaches proved to be successful: building up a layered distribution of a second phase using a multilayer deposition (quasi-superlattices) and distributing a secondary phase in the film from a compositionally changed target. Several materials have been used for the creation of artificial pinning centers. Here we report on the artificial pinning centers induced in YBCO thick films by substrate decoration and quasi-superlattice approaches using nano-dots of Ag, Au, Pd or non-superconducting YBCO. The cross-sectional AFM images show evidence of c-axis correlated columnar defects. These defects significantly contribute to the pinning of magnetic flux and increase critical current in the films.

The laser pyrolysis became a useful tool, providing various ways, in production of nano materials. The iron Mossbauer spectroscopy is one very accurate method in evidencing the physical properties and related processes in the nano scale compounds. The effect of pressure, laser spot area and induced combustion, of gas mixture and laser power on the phase composition and inside particle distribution, grain size as well as the related phenomena were investigated by temperature dependent Mossbauer spectroscopy. A selection of most relevant properties is presented and discussed in details.

There are four topologically different paths to interchange two single-component winding vortices in a two-band superconductor having a weak inter-band interaction, where each band has its own superconducting component and its own phase, theta(v), other than the ordinary quantum phase, Theta (v is the index of the band and Theta is defined at the region of theta(1) = theta(2).). The acquired phase for the interchange of two single-winding vortices depends on the path, and three values Theta(soliton),-Theta(soliton) and 0, are observed. Theta(soliton) is the phase-slip accompanying the inter-band phase difference soliton (i-soliton). The interchange requires the creation and annihilation of the i-soliton and gives rise to an ambiguity in the statistics. (C) 2008 Elsevier B.V. All rights reserved.

We report on the pulsed laser deposition and characterization of thick (1.27 mu m) films ablated from a nanocrystalline YBa2Cu3O7-delta (YBCO) target doped with 4 wt% BaZrO3 (BZO), nYBCO/BZO. DC magnetization measurements have shown a four-to five-fold increase in the critical current density J(c) and a three- to four-fold increase in the maximum pinning force in comparison with 1 mu m thick films grown from a commercial microcrystalline YBCO target, at both 77.3 and 65 K. We have found that the frequency-dependent critical current densities J(c)(f(0)/f) estimated from susceptibility measurements are linear in a double-logarithmic plot ( where f is the frequency of the AC field and f(0) is a macroscopic attempt frequency of about 10(6) Hz), consistent with a logarithmic dependence of the pinning potential on the current density, and are again several times higher in nYBCO/BZO thick films. From the slopes of the J(c)(f(0)/f) dependences we have also estimated the values of pinning potentials in fields between 3 and 5 T.

Mossbauer spectroscopy studies of Fe-Co/MgO catalysts proved that a high dispersion degree of Fe may be achieved for catalysts containing Fe/Co in a ratio close to 1. During materials processing. the presence of hydrogen at high temperatures, even for short time, induced an increased particle size of the catalytic Fe. The evaluation of various iron species from their areas in the Mossbauer spectra revealed the dependence of the nanotube amount on (FeCo alloy + Fe2+) content in the catalyst, in good agreement with literature mechanisms. The Raman spectra show that carbon nanotubes synthesized from ethanol in argon flow on 4.5%Fe:4.5%Co/MgO are richer in low diameter (0.7-1.0nm) tubes than those obtained at low ethanol pressure, in agreement with the effects of hydrogen reported in literature. The close similarity with the Raman spectra of Aldrich double-walled carbon nanotubes and from literature, recommends the syntheses in argon flow as better conditions for double-walled carbon nanotube growth.

We report on the fabrication of MgO nanorods and nanowires by a novel, all-self-assembled method, using Pulsed Laser Deposition. The seeds for the formation of these one-dimensional nanostructures consisted of self-assembled gold nanodots. Gold was used due to its well-known catalytic effect. Dimensions and surface density of the Au nano-dots, investigated by Atomic Force Microscopy, depend on the deposition conditions and the number of laser pulses. Morphology of the MgO nanorods and nanowires was investigated by SEM, and was found to depend strongly on the deposition conditions and on the architecture of the Au nanodots on the decorated substrates.