National Institute Of Materials Physics - Romania

Co-MgO granular films presenting TMR effects were prepared by thermo-ionic vacuum arc (TVA) method with the simultaneous ignition of plasma in Co and MgO vapors, respectively. The processing method is suitable for the simultaneous preparation of films of different relative content of Co in the MgO insulating matrix. Morphologic, structural and magnetic behaviors were analyzed in as prepared and annealed samples. The influence of the Co content on the magnetic properties of the prepared films was analyzed, in correlation with tunneling magneto-resistance effects. The tunneling magneto-resistance effect is maximal for certain Co content. This behavior was interpreted by the contrary effects of decreasing the average size of the magnetic grains, and hence the average inter-grains distance at higher Co relative content, and the enhanced magnetic disorder in very fine grains dispersed in the insulating matrix. This mechanism was suggested by the comportment of as prepared and thermally annealed samples.

Nano-technology is a very attractive area of research and innovation because it allows the current trends in miniaturization to continue. The transition from micro scale to nano scale devices has already taken place in many applications such as electronics, magnetic recording and nano-biophysics. However, as we scale down the size of the structures and devices, it becomes obvious that the classical behavior will break down at the nano-scale and an interesting superposition of classical and quantum effects will emerge. Therefore, the validity of classical physics is questioned and many aspects of physics are now being revisited from the point of view of nano-technologies. In line with the new developments in miniaturization and nano-technologies, we propose in this letter a simple mechanism that applies the Faraday effect at the nano-scale in order to create a possible solid-state energy nano-generator device. The proposed nano-generator functionality is based oil what we shall call the Super-Paramagnetic Electromotive Force (SPEF) effect. This has the potential to produce a very small voltage on short time scales by converting directly thermal energy at room temperature to electromotive energy Without the need for external work or mechanical motion.

Field Activated Sintering Techniques (FAST) are increasingly used to consolidate metal and ceramic powders. They combine application of a pulsed electrical current with external pressure to activate the densification process. The nature of electrical field/current interaction with powder systems is not clear yet. In this regard, in-situ transport measurements and microstructural analyses were carried out during pulsed current application in the FAST processing of Ni powders. Our experimental results were compared with existing electrical conduction theories and observed effects were relatively well explained qualitatively within these theories. Under electrical field it was confirmed that no voltage-current phase-shift occurs at elevated operating interfacial temperatures. For the field situation a higher applied pressure is decreasing the contact instability among particles contacts and of the sintering onset temperature. Microstructural investigations of the FAST-sintered samples indicate rather distribution of the higher density regions and a considerable increase of neck formation above 340 degrees C.

Co-MgO granular films presenting TMR effects were prepared by thermo-ionic vacuum arc method with the simultaneous ignition of plasma in Co and MgO vapors. Morphologic, structural and magnetic behaviors were analyzed in as prepared and annealed samples. The influence of the Co content on the magnetic properties of the prepared films was analyzed, in correlation with tunneling magneto-resistance effects. The tunneling magneto-resistance effect is maximal for certain Co content. This behavior was interpreted by the contrary effects of decreasing the average size of the magnetic grains, and hence the average inter-grains distance at higher Co relative content, and the enhanced magnetic disorder in very fine grains dispersed in the insulating matrix.

We have studied the multiharmonic ac susceptibility response of HgBa2Ca4Cu5Oy (Hg:1245), a multilayered high-temperature superconductor (HTS) having two crystallographically inequivalent CuO2 planes in a unit cell with very imbalanced carrier concentrations. Vortex melting lines are well described by the commonly accepted model of melting with moderate anisotropy factors of 40-50, depending on the doping level. The diamagnetic response with applied fields parallel to superconducting (a,b) planes also shows a quite robust supercurrent along the c axis. Our results are also discussed in connection with contradictory models and experiments regarding the coexistence of superconductivity and antiferromagnetism in HTSs.

We investigated MOCVD growth of c-axis two-layer and three-layer stacked heterostructures on (100) SrTiO3 of SI, IS or SIS type. S denotes high temperature superconductor thin films of YBa2Cu3O7 (Y-123), Bi2Sr2Ca2Cu3O10 (Bi-2223) or Bi2Sr2CaCu2O8 (Bi-2212), while I stands for insulating thin films of (Ba, Ca) CuO2 or (Sr, Ca) CuO2. X-ray diffraction, atomic force microscopy and measurements of resistivity versus temperature were performed after the deposition of each layer. The best results, suitable for further device fabrication, were obtained for the SIS structure (100) SrTiO3/Bi-2223/(Sr, Ca) CuO2/Bi-2212. Similar structures with I = (Ba, Ca) CuO2 have shown higher impurity phases and lower superconducting quality of the top superconducting layer. For two-layer or three-layer structures, Bi-2223 as a top layer could not be obtained and, instead, a phase with Bi-2212 formed. Structures with (100) SrTiO3/Y-123/(Sr, Ca) CuO2/Y-123 or (100) SrTiO3/Y-123/(Ba, Ca) CuO2/Y-123 were also promising, but a current leak often occurred due to greater roughness. Structures with Y-123 are less sensitive to growth temperature than those with BSCCO.

Critical temperature T-c of the Li-2(Pd1-xPtx)(3) B was reported to be 7-8 K for x = 0 and 2.2-2.8 K for x = 1. In this article we present our preliminary results on behavior of magnetization-temperature curves with starting composition of Pd-B precursor, y-Li concentration in LiyPd3B and post-annealing of the Pd-end compound. Results suggest that to maximize T-c ratio Pd: B should be close to 3: 1, while y-Li has to be optimum. The lowest T-c for LiyPd3B was 4.4-4.6 K, while post-annealings at 560 degrees C allowed enhancement of T-c up to 8.2-8.4 K. Compositions Li(2)Z(3)B with Z = Ni, Ru, Rh, Re, Ag are not superconducting down to 1.8 K. Exception is composition with Re showing superconductivity due to Re3B compound. All samples were prepared by arc melting. (c) 2007 Elsevier B.V. All rights reserved.

The Fe-Pt-rich alloys has recently attracted a lot of interest for their potential development of the hard magnetic L1(0) (also denoted gamma(1)) FePt phase with high magnetocrystalline anisotropy. An alloy with the nominal composition Fe65Pt25Nb2B8 has been synthesised by rapid quenching of the melt. The phase evolution in the as-cast ribbons was monitored by energy dispersive X-ray diffraction of the synchrotron radiation. It is shown that the Fe65Pt25Nb2B8 alloy is completely crystallized in the as-cast state. With increasing temperature a partial disorder-order phase transformation with occurrence of hard magnetic L1(0) phase is observed. This transformation is directly related to thermal and pressure effects in the sample. With applying pressure, the phase transformation between cubic and tetragonal FePt symmetry is more pronounced and is accompanied by a strong uniaxial lattice expansion. The results are extremely promising for the direct formation from the melt of an exchange coupled hard-soft magnetic alloy with initial formation of the tetragonal hard magnetic L1(0) FePt phase. (C) 2006 Elsevier B.V. All rights reserved.

Exchange coupling between alternatively dispersed hard and soft magnetic phases, gives rise to exchange spring magnets with enhanced energy product (BH)(max) that are believed to represent a novel class of permanent magnets with improved properties. The synthesis of a hybrid nanocomposite system made of soft magnetic Fe3B melt spun ribbon and hard magnetic Fe-Pt thin film, obtained by e-beam co-deposition in ultrahigh vacuum onto the ribbons, is reported. Scanning electron microscopy, transmission electron microscopy and X-ray diffraction are used for structural characterization of these hybrid samples. Magnetic measurements provide observation of a drastic decrease of the saturation magnetization, compatible with the exchange coupling between hard and soft magnetic phases in the melt spun/thin film samples.

Intermetallic Fe-Pt-Nb-B alloys with 3 different compositions have been synthesized by rapid solidification technique and their phase structure was characterized by means of X-ray diffraction and Mossbauer spectrometry. It is shown that Fe68Pt21Nb2B9 and Fe65Pt25Nb2B8 as-east samples consist mainly of A1 soft magnetic f.c.c. Fe-Pt phase, while the Fe68Pt13Nb2B17 as-cast sample exhibits topological short-range order, typical for amorphous ribbons. Crystallization processes in the amorphous sample and phase evolution with the temperature have been studied using differential scanning calorimetry (DSC). The occurrence of exothermic peaks is related to structural transformations in the alloys and the crystallization process is shown to be highly dependent upon the heating rate in the DSC process. (C) 2006 Elsevier B.V. All rights reserved.