National Institute Of Materials Physics - Romania

Publications

839 articles found

231. Properties of textile and leather materials treated with new hybrid SiO2/TiO2/poly(2,2 '-bithiophene) nanocomposites

Authors: Chirila, L; Gaidau, C; Stroe, M; Baibarac, M; Stanca, M; Radulescu, DM; Radulescu, DE; Alexe, CA

Published: 2019, , DOI: 10.35530/IT.070.03.1634

The aim of this study was to investigate the influence of new hybrid composites of TiO2 or SiO2 nanoparticles with poly(2,2'-bithiophene) on 50% cotton/50% polyester fabric and sheep skin leather surface properties. The dispersion-based newly made nanocomposites were analyzed to determine conductivity, particle size, polydispersity and Zeta potential. The finished textile and leather materials were characterized in terms of functionalization treatments performance by: surface resistivity, water contact behaviour, physical-mechanical characteristics and photocatalytic properties. SEM analysis was used to investigate the distribution of nanoparticles on the textile and leather materials surface. Textile materials treated with SiO2/poly(2,2'-bithiophene) nanocomposite with concentration 98 wt% nanoparticles of SiO2 and leather treated with poly SiO2/poly(2,2'-bithiophene) nanocomposite with concentration of 95 wt% nanoparticles of SiO2 showed lower resistivity values, confirming the conductive properties of silica. The higher photodegradation efficiency of functionalized materials has been obtained for textile material treated with poly TiO2/(2,2'-bithiophene) with concentration of 95 wt% nanoparticles of TiO2 and for leather material treated with TiO2/poly(2,2'-bithiophene) with concentration of 98 wt% nanoparticles of TiO2, respectively.

232. DENSITY OF ADSORBED SURFACE SPECIES FOR CYANOPHENYL ALKYL BENZOATES CONFINED TO AEROSIL A380: DEVELOPMENT OF THE EVALUATING ALGORITHM FOR ATTACHMENT BY TWO TYPES OF BONDS

Authors: Frunza, S; Frunza, L; Ganea, CP; Zgura, I; Schonhals, A

Published: 2019, UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN-SERIES A-APPLIED MATHEMATICS AND PHYSICS, 81, 236, DOI:

We found previously how to estimate the density of the adsorbed surface species in the case of the molecules interacting to the oxide support surface by one type of bond. Here this algorithm is developed for the case of the molecules which can be bonded to the support surface by two types of bonds. The adsorption assumptions are similar to those considered in the case of only one type of bond. The calculation is exemplified for some composites of cyanophenyl alkylbenzoates (CPnBs) (n is the number of carbon atoms in the alkyl chain) interacting with Aerosil A380. The interaction takes place by hydrogen bonding between the -OH groups or the support and the functional groups of the CPnB molecules. The estimated values of the total surface density of CPnBs agree well with those found for the composites containing related but simpler molecules.

233. INVESTIGATION OF THE PHOTOELECTROCHEMICAL BEHAVIOR OF NANOCARBON/MESOPOROUS TiO2 FILMS

Authors: Sima, M; Vasile, E; Sima, A

Published: OCT-DEC 2019, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 14, 941, DOI:

In this work, we report the influence of nanocarbon deposited on mesoporous TiO2 by spray method on photoelectrochemical performance of the formed photoanodes. Scanning electron microscopy and transmission electron microscopy images confirmed presence of carbon nanoparticles on the surface of anatase TiO2 films. Nanocarbon decorated TiO2 photoanodes were characterized by electrochemical impedance spectroscopy and Mott-Schottky analysis. Charge recombination process was evaluated by measurement of open-circuit voltage decay after interruption the illumination Only a small enhancement of photoelectrochemical performance of these photoanodes was observed. It was attributed to increasing of charge carrier density as a result of nanocarbon deposition on TiO2 film.

234. (Fe, Nd) codoped ZnO micro- and nanostructures with multifunctional characteristics like photocatalytic activity, optical and ferromagnetic properties

Authors: Diamandescu, L; Cernea, M; Tolea, F; Secu, EC; Trusca, R; Secu, M; Enculescu, M

Published: DEC 1 2018, CERAMICS INTERNATIONAL, 44, 21975, DOI: 10.1016/j.ceramint.2018.08.310

Zn1-x-yFexNdyO, x = 0.02 and y = 0.00-0.05 were successfully synthesized via a hydrothermal method at 200 degrees C. XRD and Mossbauer spectroscopy indicated that (Fe, Nd) codoped ZnO, calcined at 700 degrees C, 3 h in air, contains hexagonal ZnO phase as main phase and traces of ZnFe2O4; no phase containing neodymium was observed. In this study, a strong powder morphology dependence on Nd concentration and calcination temperature was evidenced by SEM. The photocatalytic properties were found to depend on the sample morphology and Nd content. Thermoluminescence signal is weak compared to the undoped ZnO and the curves shape was almost independent on the doping level and dependent on the calcination temperature and was related to the structural defects induced by the synthesis and calcination. Photoluminescence spectra showed that the green-yellow band due to the oxygen related defects, decreases by Fe and Nd-codoping. Thermo-magnetization curves measured in low applied fields and the magnetic hysteresis loops recorded in the temperature range 5-380 K, indicate two superimposed magnetic regimes, one predominant above 100 K the other below 100 K. The observed magnetic order is not directly related to the dopant Fe or Nd ions, but to different type of defects.

235. Hierarchical functionalization of electrospun fibers by electrodeposition of zinc oxide nanostructures

Authors: Matei, E; Busuioc, C; Evanghelidis, A; Zgura, I; Enculescu, M; Beregoi, M; Enculescu, I

Published: NOV 15 2018, APPLIED SURFACE SCIENCE, 458, 563, DOI: 10.1016/j.apsusc.2018.06.143

Electrospun sub-micrometer polymer fiber mats represent an interesting substrate which can be employed as a transparent conducting electrode. Functionalization by using nanostructures represents a convenient way of increasing the range of applications. The present paper describes an electrodeposition process which can be applied for preparing ZnO nanostructures covered fibers in a straightforward manner. Poly(methyl methacrylate) fiber mats were obtained by electrospinning using metal frame collectors. Subsequent metallization by DC sputtering was used, these microstructured electrodes being thermally transferred onto glass substrates and further employed as working electrodes for the electrochemical deposition of ZnO. The transparency of the metal covered webs, a function of fiber density, is comparable to that of conventional transparent conductive oxides electrodes such as ITO. The same enhanced control of the ZnO electrodeposition process was observed for the case of the web electrodes as for the classic case of deposition on transparent conducting oxides or on metallic substrates. Structural, optical, morphological and wetting properties were investigated and correlated with the electrodeposition conditions. The photocatalytic properties of ZnO covered fibers were tested through the decomposition of methylene blue thin films under UV irradiation.

236. Structural and optical properties of optimized amorphous GeTe films for memory applications

Authors: Galca, AC; Sava, F; Simandan, ID; Bucur, C; Dumitru, V; Porosnicu, C; Mihai, C; Velea, A

Published: NOV 1 2018, JOURNAL OF NON-CRYSTALLINE SOLIDS, 499, 7, DOI: 10.1016/j.jnoncrysol.2018.07.007

Chalcogenide amorphous materials, such as GeTe, are known to exhibit deposition dependent optical and structural properties. The formation of a single and homogeneous amorphous GeTe (a-GeTe) phase is questionable since the deposited films can be mixtures of monoelemental nanoclusters. In this work, we employed two deposition techniques, pulsed laser deposition from a polycrystalline GeTe target and co-sputtering from two distinct Ge and Te targets, respectively, to obtain a-GeTe films. To improve the homogeneity of the amorphous phase obtained by magnetron sputtering, the substrate temperature was varied from room temperature up to 180 degrees C. The samples were investigated by X-ray diffraction, X-ray reflectometry, X-ray photoelectron spectroscopy and spectroscopic ellipsometry. It was found that the film mass density, optical bandgap, refractive index and absolute reflectivity become progressively larger with increasing substrate temperature, due to the minimization of voids fraction and the number of dangling bonds in the amorphous structure. Moreover, X-ray photoelectron spectroscopy results prove the formation of Ge-Te bonds and therefore of the GeTe alloy at the optimal substrate temperature of 180 degrees C. This study reveals the importance of optimizing the deposition conditions for obtaining a specific amorphous phase, which enables the atomic rearrangements responsible for fast phase-change needed in memory applications.

237. Networked mesoporous SnO2 nanostructures templated by Brij (R) 35 with enhanced H2S selective performance

Authors: Stanoiu, A; Simion, CE; Sackmann, A; Baibarac, M; Florea, OG; Osiceanu, P; Teodorescu, VS; Somacescu, S

Published: NOV 1 2018, MICROPOROUS AND MESOPOROUS MATERIALS, 270, 101, DOI: 10.1016/j.micromeso.2018.05.008

Sensors based networked mesoporous SnO2 nanostructures templated by non-ionic surfactant - Brij (R) 35 were prepared via hydrothermal chemistry route. Specific patterns of the structure, morphology, surface chemistry and sensing properties were obtained by pH and autogenous pressure tuning. Consequently, the as-obtained SnO2 powders were subjected to extensive BET, Raman, TEM, HRTEM and XPS complementary investigations. The sensitive films were obtained by screen printing deposition of the powders onto commercial Al2O3 substrates. The gas sensing properties were assessed towards different hazardous gas species: CO, CH4, NH3, NO2, SO2 and H2S over a wide range of operating temperatures. Our particular SnO2 HP sensor synthesized at high autogenous pressure showed the highest selective-sensitivity to H2S (< 5 ppm) under 50% relative humidity (RH). The enhancement in the H2S sensitivity at low operating temperature under infield conditions was found to be closely connected to the morphological aspects and surface chemistry, peculiarities that can be assessed as consequences of the chemical tuning.

238. Electrochemical Synthesis of the Composites Based on Multi-Wall Carbon Nanotubes and Polypyrrole Doped with Phosphomolybdic Acid Heteropolyanions and Their Vibrational Properties

Authors: Baibarac, M; Serbschi, C; Stroe, M

Published: NOV 2018, INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 13, 10526, DOI: 10.20964/2018.11.07

Using cyclic voltammetry, Raman scattering and infrared (IR) spectroscopy, new findings concerning the electrochemical synthesis of composites based on multi-wall carbon nanotubes (MWNTs) and polypyrrole (PPY) doped with H3PMo12O40 heteropolyanions are described in this report. To better understand the electrochemical mechanism behind the synthesis of these composites, the influence of the concentrations of pyrrole and the electrolytes of H3PMo12O40 and H2SO4 on the cyclic voltammogram profile is studied. The formation of PPY doped with H3PMo12O40 heteropolyanions onto the MWNT surface is demonstrated by complementary studies of Raman scattering and IR spectroscopy.

239. Rolling dopant and strain in Y-doped BiFeO3 epitaxial thin films for photoelectrochemical water splitting

Authors: Haydous, F; Scarisoreanu, ND; Birjega, R; Ion, V; Lippert, T; Dumitrescu, N; Moldovan, A; Andrei, A; Teodorescu, VS; Ghica, C; Negrea, R; Dinescu, M

Published: OCT 25 2018, SCIENTIFIC REPORTS, 8, DOI: 10.1038/s41598-018-34010-9

We report significant photoelectrochemical activity of Y-doped BiFeO3 (Y-BFO) epitaxial thin films deposited on Nb: SrTiO3 substrates. The Y-BFO photoanodes exhibit a strong dependence of the photocurrent values on the thickness of the films, and implicitly on the induced epitaxial strain. The peculiar crystalline structure of the Y-BFO thin films and the structural changes after the PEC experiments have been revealed by high resolution X-ray diffraction and transmission electron microscopy investigations. The crystalline coherence breaking due to the small ionic radius Y-addition was analyzed using Willliamson-Hall approach on the 2 theta-omega scans of the symmetric (00l) reflections and confirmed by high resolution TEM (HR-TEM) analysis. In the thinnest sample the lateral coherence length (L-parallel to) is preserved on larger nanoregions/ nanodomains. For higher thickness values L-parallel to is decreasing while domains tilt angles (alpha(tilt)) is increasing. The photocurrent value obtained for the thinnest sample was as high as J(ph) = 0.72 mA/cm(2), at 1.4 V(vs. RHE). The potentiostatic scans of the Y-BFO photoanodes show the stability of photoresponse, irrespective of the film's thickness. There is no clear cathodic photocurrent observation for the Y-BFO thin films confirming the n-type semiconductor behavior of the Y-BFO photoelectrodes.

240. Lincomycin-embedded PANI-based coatings for biomedical applications

Authors: Popescu-Pelin, G; Fufa, O; Popescu, RC; Savu, D; Socol, M; Zgura, I; Holban, AM; Vasile, BS; Grumezescu, V; Socol, G

Published: OCT 15 2018, APPLIED SURFACE SCIENCE, 455, 666, DOI: 10.1016/j.apsusc.2018.06.016

We report on the successful laser transfer of biocompatible composite coatings based on polyaniline (PANI) embedded with magnetite (PANI-Fe3O4) and Lincomycin hydrochloride (PANI-Lincomycin) or Lincomycin-functionalized magnetite (PANI-Fe3O4@Lincomycin) by matrix assisted pulsed laser evaporation (MAPLE) technique. The physico-chemical investigations revealed relevant data regarding the stoichiometric deposition, morphology and topography of the as-deposited coatings. Regarding the MAPLE coatings, the FTIR studies evidenced the vibrational bands characteristic to pristine PANI material, while the SEM investigations unveiled a preferential particulate morphology (with aggregates shape and size depending on the deposited material). Additionally, the AFM measurements indicated variations of RMS value, following the Lincomycin and magnetite incorporation. The wettability measurements displayed a hydrophilic behavior of the synthesized coatings, while the electrochemical studies emphasized an enhanced resistance against corrosion in simulated body fluid when compared with bare Ti. Cellular viability, immunofluorescence and SEM results proved that the MAPLE coatings were suitable materials for beneficial adhesion, spreading and proliferation of osteoblast-like cells (MG-63). Moreover, an increased efficiency was evidenced against Staphylococcus aureus biofilm development. The multifunctional properties of the laser processed composite coatings - confirmed by cumulative biocompatible, antimicrobial and anticorrosive behaviors - recommend them as promising solutions for biomedical applications.