National Institute Of Materials Physics - Romania

The Pd-TPPTS complex (TPPTS - trisodium salt of 3,3',3 ''-phosphanetriyl benzenesulfonic acid) and PdCl42- salt heterogenised onto Zn2AlNO3 layered double hydroxide (LDH) using an ion-exchange procedure, have been shown to be efficient green catalysts in the cycloisomerisation reaction of acetylenic carboxylic acids to the corresponding 5-membered heterocycles.

Ferrite catalysts were prepared following two routes, i.e. the hydrothermal one and the calcination of an oxide mixture. In the first route sodium hydroxide, ferrous sulfate and the sulfate of the substituting ion (Mn, Ni) were used. The ferrites obtained using this route was NixFe3-xO4 (x = 0.5) and MnxFe3-xO4 (x similar to 0.65). Following the second route were prepared three samples: NiFe2O4, Ni0.5Zn0.5Fe2O4 and MnFe2O4. Two of them contain the corresponding ferrites while the latter is a presintered oxide mixture (Fe2O3-Mn2O3). All the samples were fully characterized using chemical analysis, X-ray fluorescence spectroscopy and EDX, nitrogen adsorption-desorption isotherms at -196 degrees C, X-ray diffraction (XRD), FTIR, scanning electron microscopy and XPS. The catalytic activity evaluation was made using a mixture of 1700 ppm vol. of toluene and air flowing at 100 ml min(-1) raising the temperature up to 600 degrees C in steps of 25 degrees C. Among these systems the sample representing the presintered Fe2O3-Mn2O3 mixture showed the highest activity. (C) 2008 Elsevier B.V. All rights reserved.

Fe3O4 colloids modified by the chiral ligand cinchonidine were prepared with the goal of obtaining a magnetic and catalytic nano-material and were subsequently embedded in silica to form a heterogeneous catalyst. The systems were characterized by TEM and XRD measurements, while the Mossbauer technique was applied for measuring the magnetic properties of the Fe3O4 colloids. The hyperfine magnetic field distribution was consistent with one type of Fe oxide, namely, the magnetite (Fe304). These colloids, both as 'quasi-homogenous catalysts' (or soluble heterogeneous catalysts) and embedded in silica (heterogeneous catalysts) were employed in the selective hydrogenolysis of complex bicyclo[2.2.2]oct-7-enes (bicyclo[2.2.2]oct-2-enes when unsubstituted). (C) 2008 Published by Elsevier B.V.