National Institute Of Materials Physics - Romania

Publications

169 articles found

91. Time-gated down-/up-conversion emission of Ho-CeO2 and Ho, Yb-CeO2 nanoparticles

Authors: Avram, D; Porosnicu, I; Cojocaru, B; Florea, M; Tiseanu, C

Published: NOV 2016, , DOI: 10.1016/j.jlumin.2016.07.026

92. Defect induced tunable near infrared emission of Er-CeO2 by heterovalent co-dopants

Authors: Florea, M; Avram, D; Cojocaru, B; Tiseanu, I; Parvulescu, V; Tiseanu, C

Published: JUL 21 2016, , DOI: 10.1039/c6cp02754g

93. Graphene from Alginate Pyrolysis as a Metal-Free Catalyst for Hydrogenation of Nitro Compounds

Authors: Trandafir, MM; Florea, M; Neatu, F; Primo, A; Parvulescu, VI; Garcia, H

Published: JUL 7 2016, , DOI: 10.1002/cssc.201600197

94. Advances in luminescence of lanthanide doped Y2O3: case of S-6 sites

Authors: Avram, D; Cojocaru, B; Florea, M; Tiseanu, C

Published: MAY 1 2016, , DOI: 10.1364/OME.6.001635

95. Cross-coupling of p-xylene to 2,2 ',5,5 '-tetramethyl 1,1 '-biphenyl on supported vanadia catalysts

Authors: Mitran, G; Pavel, OD; Florea, M; Parvulescu, VI

Published: MAR 25 2016, , DOI: 10.1016/j.apcata.2016.01.010

96. Hydrogen production from glycerol steam reforming over molybdena-alumina catalysts

Authors: Mitran, G; Pavel, OD; Florea, M; Mieritz, DG; Seo, DK

Published: MAR 5 2016, , DOI: 10.1016/j.catcom.2016.01.029

97. Exploring porous nanosilica-TEMPO as heterogeneous aerobic oxidation catalyst: the influence of supported gold clusters

Authors: Shakir, AJ; Florea, M; Culita, DC; Ionita, G; Ghica, C; Stavarache, C; Hanganu, A; Ionita, P

Published: FEB 2016, JOURNAL OF POROUS MATERIALS, 23, 254, DOI: 10.1007/s10934-015-0076-9

TEMPO stable free radical has been supported on porous silica nanoparticles in different ways and the resulted materials have been tested as heterogeneous oxidation catalyst of three benzylic alcohols using air as final oxidant and nitrosonium tetrafluoroborate as cocatalyst. Good to excellent yields were obtained. The catalytic system consists in fact in two coupled cycles, NO/NO2 and TEMPO+/TEMPO, able to convert under mild conditions (room temperature, air, metal and halogen free condition) alcohols into aldehydes or ketones. Under these conditions, supported TEMPO on silica nanoparticles containing gold clusters lowers the efficiency of the catalyst.

98. Synthesis of ceria nanopowders by microwave-assisted hydrothermal method for dry reforming of methane

Authors: Matei-Rutkovska, F; Postole, G; Rotaru, CG; Florea, M; Parvulescu, VI; Gelin, P

Published: JAN 30 2016, , DOI: 10.1016/j.ijhydene.2015.12.097

99. An adamantane-based COF: stability, adsorption capability, and behaviour as a catalyst and support for Pd and Au for the hydrogenation of nitrostyrene (vol 6, pg 8344, 2016)

Authors: Trandafir, MM; Pop, L; Hadade, ND; Florea, M; Neatu, F; Teodorescu, CM; Duraki, B; van Bokhoven, JA; Grosu, I; Parvulescu, VI; Garcia, H

Published: 2016, CATALYSIS SCIENCE & TECHNOLOGY, 6, 8573, DOI: 10.1039/c6cy90113a

100. An adamantane-based COF: stability, adsorption capability, and behaviour as a catalyst and support for Pd and Au for the hydrogenation of nitrostyrene

Authors: Trandafir, MM; Pop, L; Hadade, ND; Florea, M; Neatu, F; Teodorescu, CM; Duraki, B; van Bokhoven, JA; Grosu, I; Parvulescu, VI; Garcia, H

Published: 2016, Catalysis Science & Technology, 6, 8354, DOI: 10.1039/c6cy01631f

A bimodal (micro/mesoporous) COF was synthesized by coupling tetrakis-1,3,5,7-(4'-iodophenyl) adamantane with 4,4'-diethynylbiphenyl following a Sonogashira protocol. The COF preparation strategy led, however, to the incomplete recovery of the palladium catalyst and ICP-OES analysis indicated that around 0.1 wt% palladium remained inside the pores. Noteworthily, the remnant palladium catalyst is still accessible and can be valorised in additional catalytic reactions like the hydrogenation of nitrostyrene. Further deposition of 0.5 wt% active metals (like palladium or gold) enhanced the catalytic activity and tuned the catalyst selectivity with respect to analogous metal catalysts prepared using active carbon as a support. The resulting COF-supported metal NPs are stable and recyclable catalysts. Under normal conditions, this COF is also able to adsorb large amounts of weak electrophilic gases like carbon dioxide.