National Institute Of Materials Physics - Romania

Zn1-x-yFexNdyO, x = 0.02 and y = 0.00-0.05 were successfully synthesized via a hydrothermal method at 200 degrees C. XRD and Mossbauer spectroscopy indicated that (Fe, Nd) codoped ZnO, calcined at 700 degrees C, 3 h in air, contains hexagonal ZnO phase as main phase and traces of ZnFe2O4; no phase containing neodymium was observed. In this study, a strong powder morphology dependence on Nd concentration and calcination temperature was evidenced by SEM. The photocatalytic properties were found to depend on the sample morphology and Nd content. Thermoluminescence signal is weak compared to the undoped ZnO and the curves shape was almost independent on the doping level and dependent on the calcination temperature and was related to the structural defects induced by the synthesis and calcination. Photoluminescence spectra showed that the green-yellow band due to the oxygen related defects, decreases by Fe and Nd-codoping. Thermo-magnetization curves measured in low applied fields and the magnetic hysteresis loops recorded in the temperature range 5-380 K, indicate two superimposed magnetic regimes, one predominant above 100 K the other below 100 K. The observed magnetic order is not directly related to the dopant Fe or Nd ions, but to different type of defects.

Electrospun sub-micrometer polymer fiber mats represent an interesting substrate which can be employed as a transparent conducting electrode. Functionalization by using nanostructures represents a convenient way of increasing the range of applications. The present paper describes an electrodeposition process which can be applied for preparing ZnO nanostructures covered fibers in a straightforward manner. Poly(methyl methacrylate) fiber mats were obtained by electrospinning using metal frame collectors. Subsequent metallization by DC sputtering was used, these microstructured electrodes being thermally transferred onto glass substrates and further employed as working electrodes for the electrochemical deposition of ZnO. The transparency of the metal covered webs, a function of fiber density, is comparable to that of conventional transparent conductive oxides electrodes such as ITO. The same enhanced control of the ZnO electrodeposition process was observed for the case of the web electrodes as for the classic case of deposition on transparent conducting oxides or on metallic substrates. Structural, optical, morphological and wetting properties were investigated and correlated with the electrodeposition conditions. The photocatalytic properties of ZnO covered fibers were tested through the decomposition of methylene blue thin films under UV irradiation.

Organometallic compounds could be an excellent alternative to the organic active layers for solar cells due to several better properties like thermal and chemical stability. These organometallic compounds are electron donor materials which are easily used in donor-acceptor heterojunctions in these solar cells. One of the main problems for the active media in the solar cells is connected with the exciton diffusion length which limits the thickness of the donor layer in these donor-acceptor heterojunctions. A way to improve the exciton diffusion length is better charge transfer between the donor and acceptor facilitating the exciton diffusion towards the electrodes of the solar cells. The adding of electronegative ions or chemical groups could also influence the band alignment between the donor and acceptor smoothing the charge transport across the solar cells.

Contamination of water with heavy metals such as lead is a major worldwide problem because they affect the physiological functions of living organisms, cause cancer, and damage the immune system. Hydroxyapatite, (Ca-5(PO4)(3)OH) is considered one of the most effective materials for removing heavy metals from contaminated water. The hydroxyapatite nanopowders (N-HAp) obtained by a co-precipitation method were used in this research to determine the effectiveness in removing lead ions from contaminated solutions. In this study, we have investigated the structure and morphology of N-HAp nanopowders using X-ray diffraction (XRD), electronic transmission microscopy (TEM), and scanning electron microscopy (SEM). The structure information was also obtained by spectroscopy measurements. The Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy measurements revealed the presence of peaks corresponding to the phosphate and hydroxyl groups. The ability of N-HAp nanopowders to adsorb lead ions from aqueous solutions were established. The results of the kinetic and equilibrium studies on the removal of Pb (II) from aqueous solution revealed that the adsorption of lead (II) cations is due to the surface reaction with the hydroxyl terminal groups on the adsorbent and the combination of the positive charges of the metal cations with the negative charges on the adsorbent surfaces. These observations could validate the use of these ceramic nanopowders in ecological remediation strategies.

Zinc- (Zn) doped hydroxyapatite (HAp) were prepared by sol-gel method. Zinc-doped hydroxyapatite (ZnHAp) and HAp were analyzed by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The Rietveld analysis revealed that the HAp and 7ZnHAp powders obtained by sol-gel method have a monophasic hydroxyapatite structure belonging to the P6(3/m) spatial group. The results obtained from the ultrasound characterization of HAp and ZnHAp are also presented in this study. The effect of zinc concentration on properties that were deduced from ultrasonic measurements are studied in the case of a significant zinc concentration (x(Zn) = 0.07). From the values of the ultrasonic waves velocities were determined by the pairs of elastic coefficients of the suspensions (Young modulus E, Poisson coefficient nu), which have proven to be similar to those determined by other authors.

In this study, we compared the structural, morphological, and optical properties of a series of Zn1-xFexO (x = 0.00, 0.01, and 0.03) powders synthesized via a hydrothermal route with and without cetyltrimethylammonium bromide as a cationic surfactant. Our results highlighted the critical effects of the surfactant and the iron concentration on the structure, morphology, and optical properties of ZnO. X-ray diffraction, Mossbauer spectroscopy, and X-ray photoelectron spectroscopy analyses indicated the presence of a single phase comprising ZnO with a hexagonal wurtzite structure in all samples and a single oxidation state (+3) for the iron (Fe3+) that replaced Zn2+ in the ZnO structure. Morphological investigations by scanning electron microscopy showed that the surfactant and Fe3+ dopant greatly affected the shape of the ZnO grains, which varied between sheets and rod-like flowers. We found that the morphological and photocatalytic properties of the two series of samples comprising iron-doped ZnO with and without the surfactant were in opposition. We propose a possible growth mechanism for the ZnO polycrystalline grains in the presence of the Fe dopant and/or surfactant. The photocatalytic properties increased for the samples prepared with surfactant as the iron content increased, which was confirmed by ultraviolet-visible reflection measurements. The photocatalytic activities of the samples prepared without surfactant decreased in both the ultraviolet and visible spectral regions as the iron content increased in the samples.

We investigate the spectral and transport properties of a diatomic square lattice with hopping to the next-nearest-neighbors and broken time-reversal symmetry, which behaves as a Chern insulator. In a finite-size approach, the attention is paid to the formation of chiral edge states in the topological insulating phase, but also in the semimetallic one. The edge states are revealed in the ribbon and plaquette geometries by analytical and numerical methods, significant differences being produced by the specific atomic connectivity at the boundary. The Hall resistance R-H is calculated in the plaquette geometry using the Landauer-Mittiker approach. The chiral edge states located in the unique gap of the energy spectrum manifest themselves by quantized values R-H = +/- h/e(2) specific to the Chern insulator. The semimetallic system containing chiral edge states embedded in the quasicontinuum of bulk states shows a disorder-driven AQHE as a consequence of the Anderson localization process.

Co-doped CeO2 thin films were grown from a bulk target with starting composition Ce0.95Yb0.04Er0.01O2 by pulsed laser deposition (PLD) on a p(+)-n-n(+) single crystal silicon diode. The PLD laser fluence was varied between 1.7 J/cm(2) and 3.7 J/cm(2). The device with the film grown for a laser fluence of 2.3 J/cm(2) delivers the highest performance taking advantage of the up conversion (UC) effect provided by this film. Namely, the increase in the relative power conversion efficiency of the device is 12.1% and 39.2% for illumination under 1 and 2.1 sun, respectively, and its relative external quantum efficiency is 8.2% when illuminated with 980 nm light. The film grown for the optimum 2.3 J/cm(2) fluence shows good target-film composition transfer and a granular morphology with a low roughness. The UC mechanism consists of efficient energy transfer between spatially separated Yb3+ and Er3+ ions, i.e. the absorption of infrared light photons by the Yb3+ ions (F-2(7/2) -> F-2(5/2) transition) is followed by a two-step energy transfer process to neighboring Er3+ ions and by their characteristic luminescent emissions ((H-2(11/2), S-4(3/2)) -> I-4(15/2)) and (F-4(9/2) -> I-4(15/2)).

Organic heterostructures based on zinc phthalocyanine (ZnPc) and perylene tetracarboxylic dianhydride (PTCDA) were deposited by matrix-assisted pulsed laser evaporation (MAPLE) technique on conductive flexible substrate (ITO/PET) in three configurations: ZnPc/PTCDA (stacked layers), ZnPc:PTCDA (blend) and ZnPc/ZnPc:PTCDA/PTCDA. The effect of the configuration on the optical and electrical properties of the obtained heterostructures was investigated. For all heterostructures was observed an improved optical absorption in visible domain. The I-V characteristics recorded under illumination, revealed higher short circuit current (I (SC)) values for the ZnPc:PTCDA and ZnPc/ZnPc:PTCDA/PTCDA structures in comparison with that of the ZnPc/PTCDA structure. The results proved that by MAPLE can be obtained flexible organic heterostructures (in different configurations) with properties adequate for applications in flexible electronics and solar cell fields.

This work involves the synthesis and characterization of Cu2ZnSnS4 (CZTS) layers. The films were prepared on ITO/glass substrate by ecofriendly and simple single-step electrodeposition method followed by sulfurization and annealing at 500 degrees C under Argon flow. By using two different complexing agents, the electrodeposition process can give better results. Therefore, the effect of combining the trisodium citrate - TC to multiple cornplexing agents (cetyl trimethyl ammonium bromide - CTAB, ethylene diamine tetra acetic acid - EDTA, Boric Acid - BA, Glutamic Acid - GA and Tartaric Acid - TA) is investigated. The characterization of the absorber films was done by X-ray diffraction (XRD) analysis, Raman spectroscopy, Scanning Electron Microscopy and Diffuse Reflectivity. The combination of TC and CTAB is suggested to be the best pair of complexing agents within the combinations used in this work.