NIMP| Andrei GALATANU, Author at NIMP

Education

2000, PhD in Physics, Solid State Physics, University of Bucharest, Faculty of Physics

1994, Diplom Enegineer (MSc in Physics), Solid State Physics, Technological University of Viena, Faculty of Physics

Positions

2004- present: Senior researcher 2nd grade, Senior researcher 1st grade since 2005 in NIMP and also coordinator of Applications compartment of NIMP since 2014 - Research in condensed matter and advanced materials physics, project director for several research projects with ~4 M€ total funding

September 2001 – September 2004: Invited researcher, Research in condensed matter and advanced materials physics, especially in U based compounds at ASRC (Advanced Science Research Center), JAEA Tokai, Japonia

1994 – 2001: Reasarch assistent, Reasearcher, Senior researcher 3rd grade, 2nd grade in NIMP Research in condensed matter and advanced materials physics

Research interests

Condensed Matter Physics, Materials Physics

Expertize

transport phenomena, structural & morphology, magnetic properties, calorimetry, Mössbauer spectroscopy, other spectroscopic methods, thermo-mechanical characterization, different techniques for sample preparation, automatization of experimental setups

Books

"Introduction to Physics of SCES”, (Ed. Tehnica, 2011), E. Bauer, A. Galatanu, C.E.A. Grigorescu

ISBN 978-973-31-2337-8

Patents

U00038/13.11.2019

U00039/13.11.2019

Projects

1. INNOVATIVE STRUCTURAL MATERIALS FOR FISSION AND FUSION

Project Type: , Start Date: 2022-09-01 End Date: 2026-08-01

Publications

1. Simulation and study of the milling parameters on CuFeTaTiW multicomponent alloy

Authors: Martins, R; Conçalves, AP; Correia, JB; Galatanu, A; Alves, E; Dias, M

Published: 2024 MAR 2024, NUCLEAR MATERIALS AND ENERGY, 38, 101568, DOI: 10.1016/j.nme.2023.101568

The CuFeTaTiW multicomponent alloy has been devised as an interlayer thermal barrier in nuclear fusion re-actors. In order to predict the phase constitution of this alloy, two different lines of work were performed: (a) simulation using Molecular dynamics and Monte Carlo and (b) study of the influence of mechanical alloying parameters on the structures formed. The simulation results show that the most stable structure is achieved starting from a bcc type-structure and using Monte Carlo simulation. In fact, in these conditions the separation into two bcc phases Fe-Ta-W and Cu-Ti is predicted at room temperature. However, the experimental preparation of the materials with mechanical alloying revealed that from 2 h of milling a single bcc phase is formed. The structure of the milled powder was not much influenced by the amount of the process control agent and the by the size of the W starting particles, but generally there was formation of Ta2H from the reaction between the powders and the process control agent.

2. Mock-ups fabrication by HRP technology with advanced W-alloy monoblocks for DEMO divertor target

Authors: Crea, F; Böswirth, B; Cacciotti, E; Galatanu, A; Greuner, H; García-Rosales, C; Lorusso, P; Roccella, S; Sal, E; Verdini, L; Wirtz, M

Published: APR 2024, FUSION ENGINEERING AND DESIGN, 201, 114232, DOI: 10.1016/j.fusengdes.2024.114232

Tungsten is the primary candidate armour material for the divertor target of the European demonstration fusion power plant. During operation at high temperature, pure tungsten is subject to fracture and recrystallization which results in a loss of strength and worsening of the thermal properties. Additionally, loss-of-coolant accidents with simultaneous air ingress can generate volatile and radioactive tungsten oxides. Advanced W-alloys were developed as alternative and upgrading armour materials of pure tungsten, such as potassium-doped tungsten laminates and self-passivating tungsten alloys. Three mock-ups were manufactured using potassium-doped tungsten laminates, W-10Cr-0.5Y and W-10Cr-0.5Y-0.5Zr as armour materials, each of them consisting of n degrees 4 blocks. The fabrication required optimization and upscaling of the ITER-like process which foresees oxygen-free high conductivity copper as interlayer joined to W-alloy armour block and CuCrZr ITER grade pipe welded to the Cu/W-alloy blocks by hot radial pressing. For quality control of the fabrication steps, non-destructive examination by ultrasonic testing was done on the monoblocks as received, after casting, after hot radial pressing and after high heat flux testing. The results demonstrated that these W-alloys can be used as armour materials of the European demonstration fusion power plant divertor target.

3. Development of sub-miniaturised testing methodology for W/Cu joints extracted from the ITER-specification monoblock

Authors: Poleshchuk, K; Terentyev, D; Chang, C; Galatanu, A; Gavrilov, S; Zhou, H; Verbeken, K

Published: SEP 2023, FUSION ENGINEERING AND DESIGN, 194, 113925, DOI: 10.1016/j.fusengdes.2023.113925

A testing methodology and a new "anchor"geometry for tensile samples were developed for evaluation of the W/Cu joint strength between the W monoblock and the CuCrZr cooling pipe joined via the Cu interlayer in the ITER-specification monoblock. The proposed samples can be machined from the ITER-specification monoblock. These monoblock tensile samples are designed for uniaxial tests allowing their remote manipulation for testing in hot cells after neutron irradiation, which is crucial for the assessment of the effect of this irradiation. For validation purposes, tensile tests with standard miniaturised dog-bone samples were performed using prototype block-to-block joints (W/CuCrZr) produced with the field-assisted sintering technique. The results are obtained from the conventional and the new tensile samples. Conventional samples were machined from the W/CuCrZr block-to-block joints, while the new "anchor"tensile samples were machined from the W/CuCrZr block-toblock joints and ITER monoblock containing the W block and Cu interlayer. A good agreement in the evaluation of the joint strength was obtained. The fracture surfaces and the joint interface were investigated with scanning electron microscopy. Micro-hardness was characterised across the joint interface.

4. Thermoelectric properties of p-type Mg2Si0.3Sn0.7 doped with silver and gallium

Authors: Assahsahi, I; Popescu, B; El Bouayadi, R; Zejli, D; Enculescu, M; Galatanu, A

Published: MAY 25 2023, JOURNAL OF ALLOYS AND COMPOUNDS, 944, 169270, DOI: 10.1016/j.jallcom.2023.169270

Structure, composition, and transport properties of Mg2-xAgx(Si0.3Sn0.7)1-yGay (x = {0, 0.021, y = {0, 0.02, 0.04, 0.061) solid solutions produced by melting followed by spark plasma sintering are investigated. The preparation method is adjusted to control sample stoichiometry and phase composition. Doping with two types of dopants at different sites, while employing synthesis methods which generate a small amount of secondary phase, is an uncommon approach in this materials, expected to enhance their thermoelectric performance. An enhanced carrier concentration but diminished mobility is observed in the samples with higher amounts of dopant, which leads to the highest values of the power factor, for Mg1.98Ag0.02Si0.27Sn0.67Ga0.06 in a narrow temperature range (575-675 K) around the peak value, of 9.10-4 Wm-1 K-2 at 625 K. The two types of dopants have opposing effects on the thermal conductivity, with Ag promoting strong phonon scattering and decreasing its values while Ga increases them because of its en-hanced carrier concentration. The rather high thermal conductivity values of the double doped compounds produce low values of the ZT without exceeding 0.29 at 627 K for Mg1.98Ag0.02Si0.3Sn0.7 sample.(c) 2023 Elsevier B.V. All rights reserved.

5. Microengineering Design for Advanced W-Based Bulk Materials with Improved Properties

Authors: Galatanu, M; Enculescu, M; Galatanu, A; Ticos, D; Dumitru, M; Ticos, C

Published: MAR 2023, NANOMATERIALS, 13, 1012, DOI: 10.3390/nano13061012

In fusion reactors, such as ITER or DEMO, the plasma used to generate nuclear reactions will reach temperatures that are an order of magnitude higher than in the Sun's core. Although the plasma is not supposed to be in contact with the reactor walls, a large amount of heat generated by electromagnetic radiation, electrons and ions being expelled from the plasma will reach the plasma-facing surface of the reactor. Especially for the divertor part, high heat fluxes of up to 20 MW/m(2) are expected even in normal operating conditions. An improvement in the plasma-facing material (which is, in the case of ITER, pure Tungsten, W) is desired at least in terms of both a higher recrystallization temperature and a lower brittle-to-ductile transition temperature. In the present work, we discuss three microengineering routes based on inclusions of nanometric dispersions, which are proposed to improve the W properties, and present the microstructural and thermophysical properties of the resulting W-based composites with such dispersions. The materials' behavior after 6 MeV electron irradiation tests is also presented, and their further development is discussed.

6. Obtaining and characterisation of thermoelectric Mg2Si compound via wet and dry mechanical alloying and spark plasma sintering

Authors: Cebotari, V; Popa, F; Marinca, TF; Neamtu, BV; Sechel, NA; Galatanu, M; Galatanu, A; Chicinas, I

Published: SEP-OCT 2023, JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 26, DOI: 10.1016/j.jmrt.2023.09.167

Mg2Si thermoelectric compound was obtained by dry and wet (isohexane and benzene) mechanical alloying route. The Mg2Si compound was characterised by X-ray diffraction, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), laser particle size analysis and thermoelectric measurements. After 14 h of milling, the complete reaction of the elements is achieved by both routes. The powders particle size distribution obtained after 14 h of dry or wet milling (using benzene) reveals a bimodal curve. The wet milling moves the particle size distribution towards smaller particle sizes. The SEM analysis confirms the results of particles size analysis. DSC analyses performed for samples milled up to 14 h present stress relief and recrystallisation thermal events. For the benzene wet-milled sample, the DSC curve shows an additional thermal event at 350'C, associated with benzene removal. Thermoelectric properties were determined on spark plasma sintered compacts. The milling process with benzene leads to a higher value of Seebeck coefficient (z580 mV/K). The electrical conductivity is low at room temperature and increases exponentially with temperature. (c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

7. Behavior of Cu-Y2O3 and CuCrZr-Y2O3 composites before and after irradiation

Authors: Martins, R; Antao, F; Correia, JB; Tejado, E; Pastor, J; Galatanu, A; Carvalho, PA; Alves, E; Dias, M

Published: JUN 2023, NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 539, DOI: 10.1016/j.nimb.2023.03.011

The Cu-Y2O3 and CuCrZr-Y2O3 materials have been devised as thermal barriers in nuclear fusion reactors. It is expected that in the nuclear environments, the materials should be working on extreme conditions of irradiation. In this work the Cu-Y2O3 and CuCrZr-Y2O3 were prepared and then irradiated in order to understand the surface irradiation resistance of the material. The composites were prepared in a glove box and consolidated with spark plasma sintering. The microstructures revealed regions of Y2O3 dispersion and Y2O3 agglomerates both in the Cu matrix and in the CuCrZr. The irradiated samples did not show any surface modification indicating that the materials seem to be irradiation resistant in the present situation. The thermal conductivity values for all the samples measured are lower than pure Cu and higher than pure W, however are higher than those expected, and therefore, the application of these materials as thermal barriers is compromised.

8. The inclusion of ceramic carbides dispersion in In and Yb filled CoSb3 and their effect on the thermoelectric performance

Authors: Popescu, B; Galatanu, M; Enculescu, M; Galatanu, A

Published: FEB 10 2022, JOURNAL OF ALLOYS AND COMPOUNDS, 893, DOI: 10.1016/j.jallcom.2021.162400

In this work, thermoelectric properties of the nanocomposite materials produced via ball milling followed by spark plasma sintering from In0.2Yb0.2Co4Sb12 double filled skutterudite (SKT) with silicon and tungsten carbide inclusions are investigated. The nanocomposites with low volume ratios of beta-SiC and '-WC have a significantly increased power factor, while the lattice thermal conductivity is lowered only for beta-SiC composites. The power factor enhancement in '-WC/SKT composite compensates the increase of its thermal conductivity, and as a consequence, the maximum value of the figure of merit, 0.97, is attained for 0.33 v% 'WC at 450 degrees C, with 15% higher than that of the simple skutterudite sample. (c) 2021 Elsevier B.V. All rights reserved.

9. Influence of the synthesis parameters on the transport properties of Mg2Si0.4Sn0.6 solid solutions produced by melting and spark plasma sintering

Authors: Assahsahi, I; Popescu, B; Enculescu, M; Galatanu, M; Galca, AC; El Bouayadi, R; Zejli, D; Galatanu, A

Published: APR 2022, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 163, DOI: 10.1016/j.jpcs.2021.110561

In this work, the influence of the preparation route on the structural, morphological, and thermoelectric properties of the Mg2Si0.4Sn0.6 solid solutions is investigated. The synthesis based on melting the constituent elements in a closed graphite crucible followed by spark plasma sintering allows mixing elements with a large difference of their melting temperatures and a good control of sample stoichiometry. The optimized synthesis route is validated by the doped V and Sb samples, which yield good thermoelectric performance. The n-type doping leads to two orders of magnitude increase of the carrier concentration, and thus a subsequent increase of the electrical conductivity, which, in turn, augments greatly the power factor of the Mg1.98V0.02Si0.385Sn0.6Sb0.015 to 42.61 x10(-4) Wm(-1)K 2 at 650K. Although doping slightly enlarges the thermal conductivity, a peak value of the figure of merit ZT similar to 1.15 is obtained at 723K, which is 20 times higher than the ZT of un-doped material.

10. Direct and remote induced actuation in artificial muscles based on electrospun fiber networks

Authors: Bunea, MC; Beregoi, M; Evanghelidis, A; Galatanu, A; Enculescu, I

Published: JUL 29 2022, SCIENTIFIC REPORTS, 12, 13084, DOI: 10.1038/s41598-022-16872-2

The present work reports a new configuration of soft artificial muscle based on a web of metal covered nylon 6/6 micrometric fibers attached to a thin polydimethylsiloxane (PDMS) film. The preparation process is simple and implies the attachment of metalized fiber networks to a PDMS sheet substrate while heating and applying compression. The resulting composite is versatile and can be cut in different shapes as a function of the application sought. When an electric current passes through the metallic web, heat is produced, leading to local dilatation and to subsequent controlled deformation. Because of this, the artificial muscle displays a fast and ample movement (maximum displacement of 0.8 cm) when applying a relatively low voltage (2.2 V), a consequence of the contrast between the thermal expanse coefficients of the PDMS substrate and of the web-like electrode. It was shown that the electrical current producing this effect can originate from both direct electric contacts, and untethered configurations i.e. radio frequency induced. Usually, for thermal activated actuators the heating is produced by using metallic films or conductive carbon-based materials, while here a fast heating/cooling process is obtained by using microfiber-based heaters. This new approach for untethered devices is an interesting path to follow, opening a wide range of applications were autonomous actuation and remote transfer of energy are needed.

11. Structural and transport properties of Cu2CoSnS4 films prepared by spray pyrolysis

Authors: El Khouja, O; Assahsahi, I; Nouneh, K; Touhami, ME; Secu, M; Talbi, A; Khaaissa, Y; Matei, E; Stancu, V; Galatanu, A; Galca, AC

Published: NOV 1 2022, CERAMICS INTERNATIONAL, 48, DOI: 10.1016/j.ceramint.2022.07.185

In the present work, stannite Cu2CoSnS4 (CCTS) films were elaborated using spray pyrolysis method on soda-lime glass, at different deposition temperatures (T-d = 250, 300, and 350 degrees C), followed by different chosen sulfurization temperatures (T-s = 450, 500, and 550 degrees C). X-ray diffraction (XRD) revealed the nearly single-phase formation of CCTS films at 300 degrees C deposition temperature. After sulfurization in argon flow, the XRD lines become narrower, the average crystallite size expanding above 70 nm. The Raman spectroscopy analysis confirmed the stannite structure formation, as well as the presence CoS2 secondary phases, which reduces at higher sulfurization temperature (550 degrees C). The energy dispersive spectroscopy results indicated atomic ratios of Cu/Co/Sn/S close to the ideal stoichiometric ratio 2:1:1:4. The room temperature photoluminescence emission is recorded with maximum in the 1.35-1.40 eV range. Thermoelectric properties are measured up to 130 degrees C, the films show poor power factor as a result of small positive Seebeck coefficients 10-45 Of K -1 and low electrical conductivity despite of having relatively high carrier concentration (similar to 10(20) cm(-3)).

12. Enhanced magnetocaloric properties of La0.8K0.2-xPbxMnO3 nanoparticles by optimizing Pb doping concentrations

Authors: Bouzid, SA; Essoumhi, A; Rostas, AM; Kuncser, AC; Negrila, CC; Iacob, N; Galatanu, A; Popescu, B; Sajieddine, M; Galca, AC; Kuncser, V

Published: JUN 15 2022, CERAMICS INTERNATIONAL, 48, DOI: 10.1016/j.ceramint.2022.02.239

Polycrystalline La(0.8)K(0.2-x)Pb(x)MnO3 (x = 0.05, 0.10, 0.15, 0.20) ceramics were successfully prepared by flash combustion route and their structural, morphological, magnetic and magnetocaloric properties were investi-gated. Structural analyses using X-ray diffraction reveal that all samples are crystallized in the rhombohedral structure and belong to R <(3) over bar > c space group. The increase of Pb doping does not modify the crystalline structure but changes the grain size and lattice parameters. X-ray photoelectron spectroscopy (XPS) fitting results of Mn 2p peaks confirmed the coexistence of Mn3+ and Mn4+ ions which contribute to the double exchange interactions improving the ferromagnetic order in the samples. The magnetization's temperature and magnetic field de-pendences indicate a second-order ferromagnetic-paramagnetic transition of the ceramics. A significant mag-netic entropy change near room temperature was observed for La0.8K0.1Pb0.1MnO3, showing considerable magnetocaloric properties. Furthermore, electron paramagnetic resonance spectroscopy (EPR) was also used to examine the ferromagnetic-paramagnetic transition.

13. Irradiation of W and K-Doped W Laminates without or with Cu, V, Ti Interlayers under a Pulsed 6 MeV Electron Beam

Authors: Ticos, D; Galatanu, M; Galatanu, A; Dumitru, M; Mitu, ML; Udrea, N; Scurtu, A; Ticos, CM

Published: FEB 2022, MATERIALS, 15, 956, DOI: 10.3390/ma15030956

Small multilayered laminated samples consisting of stacks of W (or K-doped W) foils without an interlayer or with interlayers from Cu, V, and Ti were exposed to a pulsed electron beam with an energy of 6 MeV in several irradiation sessions. All samples maintained their macroscopic integrity, suggesting that the W-metal laminate concept is compatible with high heat flux applications. The surface of the samples was analyzed using a scanning electron microscope (SEM) before and after each irradiation session. The experimental results indicate that electron beam irradiation induces obvious modifications on the surface of the samples. Morphological changes such as the appearance of nanodroplets, nanostructures, and melting and cracking, depending on the sample type and the electron beam fluence, are observed. The irradiation is carried out in a vacuum at a pressure of 2 to 4 x 10(-2) torr, without active cooling for the samples. The structures observed on the surface of the samples are likely due to electron beam heating and vaporization followed by vapor condensation in the volume adjacent to the surface.

14. Damage threshold of CuCrFeTiV high entropy alloys for nuclear fusion reactors

Authors: Dias, M; Magalha, S; Antao, F; da Silva, RC; Gonsalves, AP; Carvalho, PA; Correia, JB; Galatanu, A; Alves, E

Published: OCT 15 2022, NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 529, DOI: 10.1016/j.nimb.2022.09.003

A CuCrFeTiV high entropy alloy was prepared and irradiated with swift heavy ions in order to check its adequacy for use as a thermal barrier in future nuclear fusion reactors. The alloy was prepared from the elemental powders by ball milling, followed by consolidation by spark plasma sintering at 1178 K and 65 MPa. The samples were then irradiated at room temperature with 300 keV Ar+ ions with fluences in the 3 x 1015 to 3 x 1018 Ar+/cm2 range to mimic neutron-induced damage accumulation during a duty cycle of a fusion reactor. Structural changes were investigated by X-ray diffraction, and scanning electron microscopy and scanning transmission electron microscopy, both coupled with X-ray energy dispersive spectroscopy. Surface irradiation damage was detected for high fluences (3 x 1018 Ar+/cm2) with formation of blisters of up to 1 mu m in diameter. Cross-sectional scanning transmission electron microscopy showed the presence of intergranular cavities only in the sample irradiated with 3 x 1018 Ar+/cm2, while all irradiation experiments produced intragranular nanometric-sized bubbles with increased density for higher Ar+ fluence. The Williamson-Hall method revealed a decrease in the average crystallite size and an increase in residual strain with increasing fluence, consistent with the formation of Ar+ bubbles at the irradiated surface.

15. Influences of Dispersions' Shapes and Processing in Magnetic Field on Thermal Conductibility of PDMS-Fe3O4 Composites

Authors: Stancu, V; Galatanu, A; Enculescu, M; Onea, M; Popescu, B; Palade, P; Aradoaie, M; Ciobanu, R; Pintilie, L

Published: JUL 2021, MATERIALS, 14, DOI: 10.3390/ma14133696

Composites of magnetite (Fe3O4) nanoparticles dispersed in a polydimethylsiloxane (PDMS) matrix were prepared by a molding process. Two types of samples were obtained by free polymerization with randomly dispersed particles and by polymerization in an applied magnetic field. The magnetite nanoparticles were obtained from magnetic micrograins of acicular goethite (alpha-FeOOH) and spherical hematite (alpha-Fe2O3), as demonstrated by XRD measurements. The evaluation of morphological and compositional properties of the PDMS:Fe3O4 composites, performed by SEM and EDX, showed that the magnetic particles were uniformly distributed in the polymer matrix. Addition of magnetic dispersions promotes an increase of thermal conductivity compared with pristine PDMS, while further orienting the powders in a magnetic field during the polymerization process induces a decrease of the thermal conductivity compared with the un-oriented samples. The shape of the magnetic dispersions is an important factor, acicular dispersions providing a higher value for thermal conductivity compared with classic commercial powders with almost spherical shapes.

16. The effects of mechanical alloying on the physical and thermal properties of CuCrFeTiV alloy

Authors: Antao, F; Dias, M; Correia, JB; Galatanu, A; Galatanu, M; Mardolcar, UV; Myakush, A; Cruz, MM; Casaca, A; da Silva, RC; Alves, E

Published: JAN 2021, MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 263, DOI: 10.1016/j.mseb.2020.114805

The present work reports the production and key properties of the CuCrFeTiV high entropy alloy synthetized mechanical alloying and spark plasma sintering. The milled powders and the as-sintered samples were analysed through scanning electron microscopy, coupled with energy dispersive X-ray spectroscopy and particle induced X-ray emission. Magnetic properties together with electrical resistivity, thermal conductivity, specific heat differential thermal analysis were also evaluated on the consolidated samples. The powders reveal an increasing content in iron as the millings are prolonged up to 20 h. The elemental composition of the sintered alloy, determined through particle induced X-ray emission, confirms the final composition after mechanical alloying with an increase of iron and a decrease in the remaining elements. Furthermore, although the alloy presents electrical resistivity typical of a high entropy alloy, a ferromagnetic behaviour was found, consistently with major Fe content as detected in prior observations. Finally, thermal measurements show that this CuCrFeTiV entropy alloy possesses thermal properties suitable for its potential use as thermal barriers.

17. Beneficial effects of a WC addition in FAST-densified tungsten

Authors: Novak, S; Kocen, M; Zavagnik, AS; Galatanu, A; Galatanu, M; Tarancon, S; Tejado, E; Pastor, JY; Jenus, P

Published: JAN 20 2020, MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 772, DOI: 10.1016/j.msea.2019.138666

The particle reinforcement of fusion-relevant tungsten through the incorporation of tungsten sub-carbide W2C particles at the grain boundaries is demonstrated as an effective way of eliminating the harmful W oxide, enhancing densification and stabilising the composite's microstructure and flexural strength at room and high temperatures. The W2C particles are formed in situ during the sintering by carbon diffusion from WC nano-particles added as a precursor to the W matrix. Even in an extremely fast sintering process using Field-Assisted Sintering Technology (FAST, 1900 degrees C, 5 min), the added WC completely transforms to W2C, resulting in a W-W2C composite. While at least 5 vol % of WC nanoparticles are needed to eliminate the oxide, approximately 10 vol % result in a W-W2C composite with favourable characteristics: high density, high flexural strength at RT (>1200 MPa) as well as at elevated temperatures, and high thermal conductivity, which remains above 100 W/mK up to 1000 degrees C.

18. Effect of Cr and V coatings on W base material in W-Eurofer brazed joints for fusion applications

Authors: de Prado, J; Sanchez, M; Stan, G; Galatanu, A; Urena, A

Published: OCT 2020, FUSION ENGINEERING AND DESIGN, 159, DOI: 10.1016/j.fusengdes.2020.111748

Titanium diffusion in tungsten is an undesirable phenomenon that may cause the drop of mechanical and thermal fatigue properties of tungsten base material and components in future fusion reactors. To avoid such as problematic, the effectiveness of two different diffusion coatings, deposited onto W base materials by means of RF magnetron sputtering (Cr and V layers), has been studied to analyze its impact on the operative brazing aspects of the W-Eurofer joints. Coatings with two different thicknesses were deposited over tungsten base material prepared using different surface roughness (0.08 and 0.09 mu m). The results indicated that Ti diffusion into tungsten base material after the brazing process was suppressed in all cases while the consecution of full metallic continuity was reached. However, both Cr and V layers were dissolved during the brazing process due to the high solubility of both elements into beta-Ti. Mechanical properties of the joints dropped especially when Cr is used but a strength higher than 100 MPa was obtained in the case of using V layers.

19. Optical Properties of Composites Based on Graphene Oxide and Polystyrene

Authors: Stroe, M; Cristea, M; Matei, E; Galatanu, A; Cotet, LC; Pop, LC; Baia, M; Danciu, V; Anghel, I; Baia, L; Baibarac, MA

Published: MAY 2020, MOLECULES, 25, DOI: 10.3390/molecules25102419

In this work, new optical properties of composites based on polystyrene (PS) microspheres and graphene oxide (GO) are reported. The radical polymerization of styrene in the presence of benzoyl peroxide, pentane and GO induces the appearance of new ester groups in the PS macromolecular chains remarked through an increase in the absorbance of the infrared (IR) band at 1743 cm(-1). The decrease in the GO concentration in the PS/GO composites mass from 5 wt.% to 0.5 wt.% induces a diminution in the intensities of the D and G Raman bands of GO simultaneous with a down-shift of the D band from 1351 to 1322 cm(-1). These variations correlated with the covalent functionalization of the GO layers with PS. For the first time, the photoluminescent (PL) properties of PS/GO composites are reported. The PS microspheres are characterized by a PL band at 397 nm. Through increasing the GO sheets' concentration in the PS/GO composite mass from 0.5 wt.% to 5 wt.%, a PS PL quenching process is reported. In addition, in the presence of ultraviolet A (UVA) light, a photo-degradation process of the PS/GO composite having the GO concentration equal to 5 wt.% is demonstrated by the PL studies.

20. Development of W-monoblock divertor components with embedded thermal barrier interfaces

Authors: Galatanu, M; Cioca, M; Ighigeanu, A; Ruiu, G; Enculescu, M; Popescu, B; Galatanu, A

Published: SEP 2019, FUSION ENGINEERING AND DESIGN, 146, 1354, DOI: 10.1016/j.fusengdes.2019.02.074

In the case of DEMO fusion reactor, the divertor should be able to extract a steady heat flux of about 10 MW/m(2). A promising concept is the W-monoblock which should be connected to a CuCrZr or an advanced Cu ODS alloy pipe passing through the W component. Taking into account the optimum operating temperature windows for W and existing Cu-based alloys and the thermal expansion coefficients mismatch of these two materials, a "thermal barrier" interface material is inserted in between in order to mitigate the thermal stresses and to optimize the heat flow through divertor components. In this work we investigate the feasibility to realize such divertor components using materials produced by FAST (field assisted sintering technology). This powder metallurgy technique was used firstly to produce W or W-based composites and the thermal barriers in an almost final shape and then to join the materials in realistic divertor mock-ups. The thermal barrier materials are various Cu-based composites which are included both as single material or as functionally graded components. The interface quality between different materials is investigated by scanning electron microscopy and the heat flow through components is evaluated using simulations.

21. Sintering and irradiation of copper-based high entropy alloys for nuclear fusion

Authors: Dias, M; Antao, F; Catarino, N; Galatanu, A; Galatanu, M; Ferreira, P; Correia, JB; da Silva, RC; Goncalves, AP; Alves, E

Published: SEP 2019, FUSION ENGINEERING AND DESIGN, 146, 1828, DOI: 10.1016/j.fusengdes.2019.03.044

In this study, CuxCrFeTiV (x = 0.21, 0.44, 1 and 1.7 M ratio) high entropy alloys have been devised for thermal barriers between the plasma facing tungsten tiles and the copper-based heat sink in the first wall of nuclear fusion reactors. The high entropy alloys were produced by ball milling the elemental powders, followed by consolidation with spark plasma sintering. Irradiation of the equiatomic CuCrFeTiV sample was carried out at room temperature with Ai(+) (300 keV) beams with a fluence of 3 x 10(20) at/m(2). Structural changes prior and after irradiation were investigated by scanning electron microscopy, coupled with energy dispersive X-ray spectroscopy, X-ray diffraction and thermal diffusivity. Preliminary results showed the presence of heterogenous and multiphasic microstructures in all samples. Moreover, with the increase of the Cu content it is possible to observe the formation of Cu-rich structures. The diffractogram of the CuCrFeTiV sample revealed major peaks of a BCC crystal structure and minor peaks of a FCC crystal structure. In addition, after irradiation no modifications in the CuCrFeTiV microstructure or in the diffractogram were observed.

22. Thermophysical and mechanical properties of W-Cu laminates produced by FAST joining

Authors: Galatanu, A; Galatanu, M; Enculescu, M; Reiser, J; Sickinger, S

Published: SEP 2019, FUSION ENGINEERING AND DESIGN, 146, 2374, DOI: 10.1016/j.fusengdes.2019.03.193

W-laminates are multi layered composites realized from alternately stacked W and a second metal foils. Such materials are promising candidates for W-based structural materials for fusion reactors like DEMO or beyond concepts, due to the fact that cold-rolled ultrafine-grained thin W foils show exceptional properties in terms of ductility, toughness and ductile to brittle transition (DBT), in contrast to classic bulk W materials. Therefore, different routes to transfer the W foils properties to bulk materials have been investigated. In this work we present the results obtained for W-Cu laminates produced via a FAST (Field Assisted Sintering Technique) joining route. The main advantages of FAST resides in the short processing time, with subsequent lower recrystallization detrimental effects. Structural and thermophysical properties show that the best materials are obtained for about 100 mu m thick W foils and 50-100 mu m thick Cu foils, while tensile and Charpy impact tests results show that the FAST processed W-Cu laminates are similar to the W-Cu laminates obtained by diffusion bonding.

23. Flexible Delivery Patch Systems based on Thermoresponsive Hydrogels and Submicronic Fiber Heaters

Authors: Evanghelidis, A; Beregoi, M; Diculescu, VC; Galatanu, A; Ganea, P; Enculescu, I

Published: DEC 3 2018, SCIENTIFIC REPORTS, 8, DOI: 10.1038/s41598-018-35914-2

This paper proposes a novel, flexible, low cost administration patch which could be used as a non-invasive, controlled transdermal drug delivery system. The fabricated device consists in a flexible microfiber architecture heater covered with a thermoresponsive hydrogel, namely poly(N-isopropylacrylamide), as a matrix for the incorporation of active molecules. The manufacturing process consists of two main steps. First, the electrospun poly(methyl methacrylate) fiber networks are sputter coated with a thin gold layer and attached to flexible poly(ethylene terephthalate) substrates to obtain the heating platforms. Second, the heaters are encapsulated in poly(ethylene terephthalate) foils and covered with poly(N-isopropylacrylamide) hydrogel sheets. In order to illustrate the functionality of the fabricated patch, the hydrogel layer is loaded with methylene blue aqueous solution and is afterwards heated via Joule effect, by applying a voltage on the metalized fibers. The methylene blue releasing profiles of the heated patch are compared with those of the unheated one and the influence of parameters such as hydrogel composition and morphology, as well as the applied voltage values for microheating are investigated. The results indicate that the fabricated patch can be used as a drug administration instrument, while its performance can be tuned depending on the targeted application.

24. High temperature thermo-physical properties of SPS-edW-Cu functional gradient materials

Authors: Galatanu, M; Enculescu, M; Galatanu, A

Published: FEB 2018, MATERIALS RESEARCH EXPRESS, 5, DOI: 10.1088/2053-1591/aaa860

The divertor of a fusion reactor like DEMO requires materials able to withstand high heat fluxes and neutron irradiation for several years. For the water cooling concept of this essential part of the reactor, the most likely plasma facing material will be W, while the heatsink material considered is CuCrZr or an improved version of such a Cu-based alloy. To realize W-Cu alloy joints able to withstand thousands of thermal cycles can be difficult due to the difference between the thermal expansion coefficients of these materials. In this work we investigate the possibility to realize such joints by using W-Cu functional gradient materials (FGMs) produced from nanometric and micrometric metallic powders mixtures and consolidated by spark plasma sintering at about 900 degrees C. Morphological and thermal properties investigations, performed for typical compositions, shows that the best results are obtained using powders with micrometric dimensions. A resulting 1 mm thick, 3 layers W-Cu FGM produced by this simple method shows a remarkable almost constant thermal conductivity value of 200 W m(-1) K-1, from room temperature up to 1000 degrees C.

25. Thermophysical properties of Cu-ZrO2 composites as potential thermal barrier materials for a DEMO W-monoblock divertor

Authors: Galatanu, M; Enculescu, M; Galatanu, A

Published: FEB 2018, FUSION ENGINEERING AND DESIGN, 127, 184, DOI: 10.1016/j.fusengdes.2018.01.011

DEMO fusion reactor divertor is expected to extract a heat flux of about 10 MW/m(2). One of the most promising concept design for it is the W-monoblock, which should be connected to a CuCrZr or an advanced Cu ODS alloy pipe passing through the W component. Since the optimum operating temperature windows for W and existing Cu alloys are far away from overlapping, a suited interface is needed to keep the adjacent materials as close as Possible to their respective temperature operating windows. The interface material should therefore have a low enough thermal conductivity to act as a thermal barrier and a thermal expansion coefficient suited to protect the W-pipe joint from stresses induced by the different thermo-mechanical properties of W and Cu-alloys. As interface materials we have considered Cu-ZrO2 composites produced by powder metallurgy route. Such materials can be realized in an unexpected large compositional range (up to at least 90% ZrO2 volume concentration) and be easily further joined to both W and Cu-alloys by an electrical field assisted technology. We analyse their microstructure and thermo-physical properties both as single materials and included in W-thermal barrier-CuCrZr 3-layers systems in comparison to those of previously produced Cu-ased composites and commercially available Cu foams.

26. Cracks and nanodroplets produced on tungsten surface samples by dense plasma jets

Authors: Ticos, CM; Galatanu, M; Galatanu, A; Luculescu, C; Scurtu, A; Udrea, N; Ticos, D; Dumitru, M

Published: MAR 15 2018, APPLIED SURFACE SCIENCE, 434, 1128, DOI: 10.1016/j.apsusc.2017.11.057

Small samples of 12.5 mm in diameter made from pure tungsten were exposed to a dense plasma jet produced by a coaxial plasma gun operated at 2 kJ. The surface of the samples was analyzed using a scanning electron microscope (SEM) before and after applying consecutive plasma shots. Cracks and craters were produced in the surface due to surface tensions during plasma heating. Nanodroplets and micron size droplets could be observed on the samples surface. An energy-dispersive spectroscopy (EDS) analysis revealed that the composition of these droplets coincided with that of the gun electrode material. Four types of samples were prepared by spark plasma sintering from powders with the average particle size ranging from 70 nanometers up to 80 mu m. The plasma power load to the sample surface was estimated to be 4.7 MJ m(-2) s(-1/2) per shot. The electron temperature and density in the plasma jet had peak values 17 eV and 1.6 x 10(22) m(-3), respectively. (C) 2017 National Institute for Laser, Plasma, and Radiation Physics (INFLPR). Published by Elsevier B.V. All rights reserved.

27. Melt infiltrated tungsten-copper composites as advanced heat sink materials for plasma facing components of future nuclear fusion devices

Authors: Von Muller, A; Ewert, D; Galatanu, A; Milwich, M; Neu, R; Pastor, JY; Siefken, U; Tejado, E; You, JH

Published: NOV 2017, FUSION ENGINEERING AND DESIGN, 124, 459, DOI: 10.1016/j.fusengdes.2017.01.042

The exhaust of power and particles is regarded as a major challenge in view of the design of a magnetic confinement nuclear fusion demonstration power plant (DEMO). In such a reactor, highly loaded plasma facing components (PFCs), like the divertor targets, have to withstand both severe heat flux loads and considerable neutron irradiation. Existing divertor target designs make use of monolithic tungsten (W) and copper (Cu) material grades that are combined in a PFC. Such an approach, however, bears engineering difficulties as W and Cu are materials with inherently different thermomechanical properties and their optimum operating temperature windows do not overlap. Against this background, W Cu composite materials are promising candidates regarding the application to the heat sink of highly loaded PFCs. The present contribution summarises recent results regarding the manufacturing and characterisation of such W Cu composite materials produced by means of liquid Cu melt infiltration of open porous W preforms. On the one hand, this includes composites manufactured by infiltrating powder metallurgically produced W skeletons. On the other hand, W Cu composites based on textile technologically produced fibrous reinforcement preforms are discussed. (C) 2017 The Author(s). Published by Elsevier B.V.

28. Cu-based composites as thermal barrier materials in DEMO divertor components

Authors: Galatanu, M; Enculescu, M; Ruiu, G; Popescu, B; Galatanu, A

Published: NOV 2017, FUSION ENGINEERING AND DESIGN, 124, 1134, DOI: 10.1016/j.fusengdes.2017.02.031

For DEMO fusion reactor an expected heat flux of about 10MW/m(2) should be extracted by the divertor which will have, most likely, an armour part made of W and a following heat sink part made of Cu, or ODS Cu alloy. Unfortunately, for these materials the optimum operating temperature windows do not overlap. Thermal barrier materials are interface materials included in such components, aiming to keep the temperatures of both armour and heat sink parts in the corresponding operating windows, and to mitigate the effects of their different thermomechanical properties. Here we propose a simple spark plasma sintering route to create Cu-based composites with a high content (10-40 vol%) of various dispersed materials (Al or Y oxides, C, SiC), allowing a fine tuning of the content and a large pool of predefined shapes and dimensions. The resulting specimens can be further joined to armour and heatsink components via a similar electrical field assisted technology. Micro-structural and thermal properties are investigated for these materials allowing to select the most suited materials in view of their thermal conductivity and thermal expansion coefficients. (C) 2017 The Authors. Published by Elsevier B.V.

29. Thermal conductivity and diffusivity of Cu-Y alloys produced by different powder metallurgy routes

Authors: Carro, G; Munoz, A; Monge, MA; Savoini, B; Galatanu, A; Galatanu, M; Pareja, R

Published: NOV 2017, FUSION ENGINEERING AND DESIGN, 124, 1160, DOI: 10.1016/j.fusengdes.2017.01.017

Full density Cu-1%Y and Cu-0.8%Y alloys have been produced by different powder metallurgy routes and subsequent hot isostatic pressing. Some of the alloys have been subjected to equal channel angular pressing (ECAP) via B-c route up to 8 passes. ECAP deformation homogenizes and refines the microstructure up to attaining a sub-micron grain structure. Thermal properties have been characterized by the laser flash method in the temperature range 373-773 K. The ECAP process, irrespective of the production route, enhanced the thermal conductivity to values similar to those for CuCrZr (ITER grade). The linear thermal expansion coefficient was temperature independent for all materials. (C) 2017 Elsevier B.V. All rights reserved.

30. Direct and contactless electrical control of temperature of paper and textile foldable substrates using electrospun metallic-web transparent electrodes

Authors: Busuioc, C; Evanghelidis, A; Galatanu, A; Enculescu, I

Published: OCT 10 2016, SCIENTIFIC REPORTS, 6, DOI: 10.1038/srep34584

Multiple and complex functionalities are a demand nowadays for almost all materials, including common day-to-day materials such as paper, textiles, wood, etc. In the present report, the surface temperature control of different types of materials, including paper and textiles, was demonstrated by Joule heating of metallic-web transparent electrodes both by direct current and by RF induced eddy currents. Polymeric submicronic fiber webs were prepared by electrospinning, and metal sputtering was subsequently performed to transform them into flexible transparent electrodes. These electrodes were thermally attached to different substrates, including paper, textiles and glass. Using thermochromic inks, we demonstrated a high degree of control of the substrates' surface temperature by means of the Joule effect. Metallic fiber webs appear to be excellently suited for use as transparent electrodes for controlling the surface temperature of common materials, their highly flexible nature being a major advantage when dealing with rough, bendable substrates. This kind of result could not be achieved on bendable substrates with rough surfaces such as paper or textiles while employing classical transparent electrodes i.e. metal oxides. Moreover, contactless heating with induced currents is a premiere for transparent electrodes and opens up a score of new application fields.

31. Consolidation of W-Ta composites: Hot isostatic pressing and spark and pulse plasma sintering

Authors: Dias, M; Guerreiro, F; Correia, JB; Galatanu, A; Rosinski, M; Monge, MA; Munoz, A; Alves, E; Carvalho, PA

Published: OCT 2015, FUSION ENGINEERING AND DESIGN, 98-99, 1955, DOI: 10.1016/j.fusengdes.2015.06.178

Composites consisting of tantalum fiber/powder dispersed in a nanostructured W matrix have been consolidated by spark and pulse plasma sintering as well as by hot isostatic pressing. The microstructural observations revealed that the tungsten-tantalum fiber composites consolidated by hot isostatic pressing and pulse plasma sintering presented a continuous layer of Ta2O5 phase at the W/Ta interfaces, while the samples consolidated by spark plasma sintering evidenced a Ta+Ta2O5 eutectic mixture due to the higher temperature of this consolidation process. Similar results have been obtained for the tungsten-tantalum powder composites. A (W, Ta) solid solution was detected around the prior nanostructured W particles in tungsten-tantalum powder composites consolidated by spark and pulse plasma sintering. Higher densifications were obtained for composites consolidated by hot isostatic pressing and pulse plasma sintering. (C) 2015 Elsevier B.V. All rights reserved.

32. Low-activation W-Si-C composites for fusion application

Authors: Ivekovic, A; Galatanu, A; Novak, S

Published: NOV 2015, FUSION ENGINEERING AND DESIGN, 100, 645, DOI: 10.1016/j.fusengdes.2015.08.013

W-Si-C composites were fabricated by active filler controlled pyrolysis of W powder (high tungsten content) and W-SiC powder mixtures (low tungsten content), infiltrated by a preceramic polymer and heat treated at temperatures from 1600 to 2000 degrees C. Material with high volume fraction of W in initial powder-polymer mixture, formed a composite material composed of W, W2C and W5Si3 with closed porosity in a single polymer infiltration and pyrolysis (PIP) cycle. After heat treatment at 1700 degrees C the material exhibited flexural strength above 350 MPa, hardness of 7.8 GPa and indentation modulus of 250 GPa. Room temperature thermal conductivity of the composite was rather low, 23 Wm(-1) K-1, however, thermal conductivity increased with increasing temperature achieving 35 Wm(-1) K-1 at 1000 degrees C. The effect of W as active filler in W-SiC powder mixtures with low volume fraction of tungsten was negligible. Therefore, six polymer infiltration and pyrolysis cycles were used to achieve significant densification with 15% porosity. The material fabricated at 1800 degrees C was composed of SiC, WC and WSi2 and exhibited flexural strength of 400 MPa and room temperature thermal conductivity of 100 W m(-1) K-1, which decreased to 32 W m(-1) K-1 at 1000 degrees C. (C) 2015 Elsevier B.V. All rights reserved.

33. Iron oxide magnetic nanoparticles with versatile surface functions based on dopamine anchors

Authors: Mazur, M; Barras, A; Kuncser, V; Galatanu, A; Zaitzev, V; Turcheniuk, KV; Woisel, P; Lyskawa, J; Laure, W; Siriwardena, A; Boukherroub, R; Szunerits, S

Published: 2013, NANOSCALE, 5, 2702, DOI: 10.1039/c3nr33506b

The synthesis of multifunctional magnetic nanoparticles (MF-MPs) is one of the most active research areas in advanced materials as their multifunctional surfaces allow conjugation of biological and chemical molecules, thus making it possible to achieve target-specific diagnostic in parallel to therapeutics. We report here a simple strategy to integrate in a one-step reaction several reactive sites onto the particles. The preparation of MF-MPs is based on their simultaneous modification with differently functionalized dopamine derivatives using simple solution chemistry. The formed MF-MPs show comparable magnetic properties to those of naked nanoparticles with almost unaltered particle size of around 25 nm. The different termini, amine, azide and maleimide functions, enable further functionalization of MF-MPs by the grafting-on approach. Michael addition, Cu(I) catalyzed << click >> chemistry and amidation reactions are performed on the MF-MPs integrating subsequently 6-(ferrocenyl)-hexanethiol, horseradish peroxidase (HRP) and mannose.

34. Direct sintering of SiC-W composites with enhanced thermal conductivity

Authors: Galatanu, M; Popescu, B; Enculescu, M; Tiseanu, I; Craciunescu, T; Galatanu, A

Published: OCT 2013, FUSION ENGINEERING AND DESIGN, 88, 2602, DOI: 10.1016/j.fusengdes.2013.05.036

Different types of SiC-W composites have been realized by spark plasma sintering in a single step process starting with beta SiC nanometric powder, W nanometric and micrometric sized powders, and W foils. SEM, EDX, XRD and X-ray tomography have been used to analyze the sample morphology while the thermal properties of the resulting materials have been investigated up to 1000 degrees C using a LFA thermal analyzer. The results show the possibility to produce dense W-SiC composites, with enhanced thermal conductivity using a relatively simple route. (C) 2013 Elsevier B.V. All rights reserved.

35. Magnetoresistiviiy and upper critical field in superconductor Mo3Sb7

Authors: Tran, VH; Bauer, E; Galatanu, A; Bukowski, Z

Published: JUL 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 1632, DOI:

Magnetotransport data on a single crystal of the superconducting Mo3Sb7 are reported for temperatures down to 0.4 K and in magnetic fields up to 12 T. The magnetoresistance data are analyzed in terms of the Ginzburg-Landau fluctuation theory. From the experimental data the upper critical field H-c2(0) and Ginzburg-Landau coherent length xi(O) are determined to be similar to 2.3 T and 12 nm, respectively. The H,2(0) value agrees with that inferred from the Werthamer, Helfand, Hohenberg, and Maki theories for conventional type-II superconductors.

36. Low temperature magnetic and transport properties in Ce(Ag, Ni)Sb-2 compounds

Authors: Popescu, B; Royanian, E; Michor, H; Hilscher, G; Bauer, E; Galatanu, A

Published: APR 1 2008, PHYSICA B-CONDENSED MATTER, 403, 939, DOI: 10.1016/j.physb.2007.10.287

Structural, thermodynamic and,transport, properties of CeAg1-xNixSb2 compounds are investigated. The Ni substitution of Ag decreases the magnetic ordering temperature from approximate to 9.5 to approximate to 6 K, while the characteristic temperatures, considered as the temperature of the resistivity maximum, increase from 26 to 65 K. (c) 2007 Elsevier B.V. All rights reserved.

37. Shape memory and associated properties in Fe-Mn-Si-based ribbons produced by melt-spinning

Authors: Valeanu, M; Filoti, G; Kuncser, V; Tolea, F; Popescu, B; Galatanu, A; Schinteie, G; Jianu, AD; Mitelea, I; Schinle, D; Craciunescu, CM

Published: JUL 2008, JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 320, E167, DOI: 10.1016/j.jmmm.2008.02.105

Four Fe-Mn-Si alloys, Fe(62)Mn(32)Si(6), Fe(62)Mn(20)Si(5)Cr(8)Ni(5), Fe(62)Mn(16)Si(5)Cr(12)Ni(5) and Fe(65)Mn(9)Si(7)Cr(10)Ni(9), were obtained by the melt-spinning method. The samples were structurally, magnetic and shape memory effect (SME) investigated, both ''as quenched'' and thermally treated. The Mn-rich compositions show different phase, magnetic behavior and SME in comparison with Mn-poor compositions. The thermal treatments generate transformation between the two existing majority phases (alpha and gamma), related magnetization and SME behavior. The features are derived from the corroboration of structural, magnetic interaction and magnitude of SME data. (c) 2008 Elsevier B.V. All rights reserved.

38. Physical properties of the new ferromagnetic Kondo system CeAg1-xNixSb2

Authors: Popescu, B; Birsan, A; Galatanu, A; Royanian, E; Hilscher, G; Bauer, E

Published: JUL 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 1629, DOI:

Structural, magnetic and transport properties of CeAg1-xNixSb2 compounds are investigated on polycrystalline samples. The experimental results show the formation of ferromagnetic compounds with sharp transitions decreasing from 9.5 K in the 100% Ag compound to 8.1 K for 33% Ni substitution, 7 K for 67% Ni substitution to 6 K for the 100% Ni compound. The characteristic temperatures, considered as the temperature of the resistivity maximum To increases from 26 K to 44 K, 54 K and 65 K, respectively. These results indicate Ce(AgNi)Sb2 compounds as a ferromagnetic Kondo system.

39. Pressure response of Ce(Ag, Ni)Sb(2) compounds

Authors: Khan, RT; Galos, R; Bauer, E; Popescu, B; Galatanu, A

Published: JUL 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 1615, DOI:

The pressure response of CeAg(1-x)Ni(x)Sb(2) is Studied by means of electrical resistivity measurements. The ferromagnetic ordering temperatures T(c) of this series decrease as pressure is applied, except CeNiSb(2), showing a pressure driven continuous increase of T(c). This refers to crystalline electric field effects originating distinct different magnetic ground states. Concomitantly, the pressure response of various material dependent parameters also behave in the opposite direction.

40. Superconductivity in the complex metallic alloy beta-Al3Mg2

Authors: Bauer, E; Kaldarar, H; Lackner, R; Michor, H; Steiner, W; Scheidt, EW; Galatanu, A; Marabelli, F; Wazumi, T; Kumagai, K; Feuerbacher, M

Published: JUL 2007, PHYSICAL REVIEW B, 76, DOI: 10.1103/PhysRevB.76.014528

Transport and thermodynamic properties were studied for the complex metallic compound beta-Al3Mg2, composed of 925 atoms per unit cell. beta-Al3Mg2 exhibits bulk superconductivity below T-c=0.87 K. An exponential temperature dependence of the specific heat well below T-c indicates BCS-like behavior with a nodeless gap of width Delta(BCS)(0)approximate to 1.5 K. The coherence length is derived as xi(0)=4.85x10(-8) m and the Ginzburg Landau parameter kappa(GL)approximate to 13, characterizing beta-Al3Mg2 as a type II superconductor. Superconductivity in beta-Al3Mg2 occurs in the absence of inversion symmetry of the crystal. Surprisingly, in spite of the rather complex crystal structure of beta-Al3Mg2, physical properties turn out to be quite simple.

41. Magnetic behaviour of UB4 at high temperatures

Authors: Galatanu, A; Yamamoto, E; Haga, Y; Onuki, Y

Published: MAY 1 2006, PHYSICA B-CONDENSED MATTER, 378-80, 1000, DOI: 10.1016/j.physb.2006.01.383

UB4 is a moderate heavy fermion compound which does not exhibit my magnetic order down to 0.3 K. In this work, the magnetic properties of UB4 are investigated in an extended temperature range, 2-800 K. on high-quality single crystals. A cross-over from a low temperature 5f itinerant behaviour to a high temperature 5f localized behaviour is observed, marked by broad peaks in the magnetic susceptibility measured along the main crystallographic axes. (c) 2006 Elsevier B.V. All rights reserved.

42. Detailed study of the CePd2-xNixAl3 magnetic phase diagram around its critical concentration

Authors: Sereni, JG; Pedrazzini, P; Bauer, E; Galatanu, A; Aoki, Y; Sato, H

Published: APR 19 2006, JOURNAL OF PHYSICS-CONDENSED MATTER, 18, 3802, DOI: 10.1088/0953-8984/18/15/022

Thermal, magnetic and transport measurements on CePd2-xNixAl3 alloys within the 0 <= x <= 1 range are reported, including applied pressure (p) and magnetic field on some selected samples. The low temperature results indicate that long range antiferromagnetic order is robust up to x = 0.2, whereas between 0.25 and 0.5 magnetic fluctuations give rise to non-Fermiliquid (NFL) behaviour. In this critical region, the low temperature specific heat can be described as due to two components, the major showing a NFL C-p/T = gamma(0) - gamma(1) root T dependence, while the minor one includes a decreasing fraction of short range order degrees of freedom. The latter is only observed close to the critical point, x(cr) approximate to 0.35. Electrical resistivity (rho) studies performed under pressure for x = 0.5 allow us to investigate the evolution of the NFL state around and beyond x(cr), where the exponent of rho proportional to T-n increases from n = 1 (for p = 0) up to n = 2 (for p = 12 kbar). This exponent is also observed at normal pressure on the x = 1.0 sample. indicating the onset of the Fermi liquid behaviour. Doping and pressure effects are compared by fitting high temperature resistivity data employing a unique function which allows us to describe the evolution of the characteristic energy of this series along a large range of concentration and pressure.

43. Magnetic and Mossbauer spectral studies of R3Fe29-x,MOx compounds (R = Y, Nd, Sm, Gd, Tb, and Dy)

Authors: Lazar, DP; Valeanu, M; Galatanu, A; Leonovici, MR; Dafinei, A; Ion, L

Published: APR 19 2005, JOURNAL OF ALLOYS AND COMPOUNDS, 392, 39, DOI: 10.1016/j.jallcom.2004.09.012

The investigation of the structure, magnetic and Mossbauer properties for the series of R-3(Fe,MO)(29) compounds has been performed, where R = Y, Nd, Sm, Gd, Tb, and Dy. The crystallographic structure of the ternary phase compounds has been investigated by Rietveld refinement of the X-ray diffraction patterns obtained at room temperature. The quality of the single-phase compounds was also checked by thermomagnetic measurements, from room temperature to above the Curie temperatures. From the magnetic isotherms for the free powder samples, measured at 4.2 K, the saturation magnetizations and the iron average magnetic moments have been derived. Fe-57 Mossbauer spectra of the R3 (Fe,MO)29 compounds have been measured at 15 K. The analysis of spectra, in a model which takes into account both the Fe atom nearest neighbor numbers and the Fe-Fe nearest neighbor bond lengths, indicates that the transferred contribution to the hyperfine field at the iron sites, due to rare earth moments, can be correlated with the rare earth effective spin. (c) 2004 Elsevier B.V. All rights reserved.

44. Physical properties of skutterudites YbxM4Sb12, M = Fe, Co, Rh, Ir

Authors: Bauer, E; Galatanu, A; Michor, H; Hilscher, G; Rogl, P; Boulet, P; Noel, H

Published: APR 2000, EUROPEAN PHYSICAL JOURNAL B, 14, 493, DOI: 10.1007/s100510051057

A series of compounds YbxM4Sb12, M = Fe, Co, FeCo, Rh,Ir, were synthesised by reaction sintering. From Rietveld refinements isotypism was determined in all cases with the LaFe4P12-(skutterudite)-type, space group Im (3) over bar - No. 204. These refinements also served to derive the Yb-content in the samples. There is a systematic trend for the Yb-occupancy in the parent lattice M4Sb12; revealing a gradual decrease of the Yb-content from x = 0.8 (M = Fe), x = 0.5 (FeCo), x = 0.2 (Co); x = 0.1 (Rh) to x approximate to 0.02 (Ir). This dependency seems to correlate with the thermal stability of the ternary compounds: a true ternary compound forms for M = Fe, whilst for M = Co, Rh, Ir stable binary skutterudite compounds MSb3 already exist. Measurements of various bulk properties revealed the absence of any long range magnetic order in this series of compounds. While the samples rich in Yb behave metallic like, the Rh and Ir based skutterudites show a semiconducting-like resistivity which at lower temperatures is characterised by variable range hopping in the presence of strong Coulomb interaction. Although Yb0.1Rh4Sb12 exhibits a Seebeck coefficient up to about 150 mu V/K, figures of merit ZT generally are below 0.1 near room temperature, primarily due to the large resistivities of the sintered material.

45. Structural and magnetic investigation of nonstoichiometric YFe10V2 and its interstitial carbide prepared by arc-melting

Authors: Plugaru, N; Lazar, DP; Galatanu, A; Morariu, M; Wiesinger, G; Kottar, A; Vasile, E

Published: MAR 14 2000, JOURNAL OF ALLOYS AND COMPOUNDS, 299, 54, DOI: 10.1016/S0925-8388(99)00791-4

A far-from-equilibrium preparation route and using a particular combination of starting materials led us to obtain nonstoichiometric Y(Fe,V)(12) and its interstitial carbide. Structural analysis and EDAX results reveal the formation of the main 1:12 phase with the ThMn12-type structure, with 13-15% vacancies at the 3d metal sites. Insertion of interstitial carbon increases the T-C and magnetization of the 1:12 phase, whereas the unit cell volume remains unchanged. The effects of vacancies and interstitial carbon on the Mossbauer hyperfine fields and isomer shifts are discussed with reference to the calculated quantities. (C) 2000 Elsevier Science S.A. All rights reserved.

46. Field-induced phase transitions and giant magnetoresistance in Dy3Co single crystals

Authors: Baranov, NV; Bauer, E; Hauser, R; Galatanu, A; Aoki, Y; Sato, H

Published: JUL 2000, EUROPEAN PHYSICAL JOURNAL B, 16, 72, DOI: 10.1007/s100510070250

Electrical resistivity and calorimetric measurements on Dy3Co show that below the Neel temperature (T-N = 44 K) the non-collinear antiferromagnetic structure exhibits: field-induced magnetic phase transitions of a first-order type along all principal axes, accompanied by a strongly anisotropic giant magnetoresistance and by a change of the Sommerfeld coefficient of the specific heat. Quantum tunnelling of the magnetization appears to be possible for T < 0.6 K.

47. Fe-57 Mossbauer study of Pr-m(Fe, MO)(n) compounds with m : n=2 : 17 and 1 : 12

Authors: Morariu, M; Lazar, DP; Galatanu, A; Plugaru, N; Kuncser, V; Filoti, G; Hilscher, G; Kottar, A

Published: MAR 30 1999, JOURNAL OF ALLOYS AND COMPOUNDS, 285, 47, DOI: 10.1016/S0925-8388(98)01055-X

The effects of Mo substitution in Pr2Fe17-xMox and PrFe12-xMox compounds were investigated by X-ray diffraction, magnetic measurements and Mossbauer spectroscopy. Different fitting procedures, using magnetic sextets at low temperature, magnetic sextets and quadrupole doublets at room temperature and paramagnetic doublets well above the Curie points, had to be considered in order to analyze the Mossbauer spectra. The Mossbauer data obtained on the Mo-containing compounds stand for distributions of the hyperfine fields due to the random distributions of Mo over the 6c sites in the 2:17 and 8i sites in the 1:12 compounds. The variations in the isomer shifts and hyperfine fields with composition are discussed in relationship to the local environment details at the different iron sites. Site-specific information on the electronic effects due to Fe(Sd)-Mo(4d) states hybridization are derived. (C) 1999 Elsevier Science S.A. All rights reserved.

48. Effect of aluminium on phase stability in the Gd3Co11(B,Al)(4) system

Authors: Galatanu, A; Kottar, A; Artigas, M; Plugaru, N; Lazar, DP

Published: NOV 14 1997, JOURNAL OF ALLOYS AND COMPOUNDS, 262, 362, DOI: 10.1016/S0925-8388(97)00408-8

In the Gd3Co11B4-xAlx alloys the ternary 3:11:4 phase with Ce3Co11B4 structure is formed with an Al content x approximate to 0.5 substituting for boron. The fraction of this phase decreases as the boron content decreases in the samples. The Al, Co and Gd in excess form Gd(Co,Al)(5) with CaCu5-type structure, and the fraction of this phase increases with increasing x. X-ray diffraction results show that these phases are not at equilibrium. A strong preference of aluminium for the 3g site in the CaCu5-type structure is determined by Rietveld refinement of the X-ray diffraction pattern of the end-series compound (x = 4). (C) 1997 Elsevier Science S.A.

49. Structural properties of conducting and semiconducting polymers

Authors: Galatanu, A; Chipara, MI; Chipara, MD; Toacsen, M

Published: JUN 1997, PHYSICA B, 234, 244, DOI: 10.1016/S0921-4526(96)00925-8

Electron spin resonance investigations on polyethylene-polyaniline blends are reported. The temperature dependence of resonance line parameters, in the temperature range 270-400 K is investigated in detail.

50. Local effects of interstitial versus substitutional atoms in Y(2)Fe(17-x)M(x)A(y) compounds, with M=Al or Si and A=C or N

Authors: Plugaru, N; Morariu, M; Galatanu, A; Lazar, DP; Barb, D

Published: DEC 15 1997, JOURNAL OF APPLIED PHYSICS, 82, 6202, DOI: 10.1063/1.366504

Interstitial Y(2)Fe(17-x)M(x)C(y) compounds, with M=A1 or Si and x less than or equal to 2, y less than or equal to 1, were investigated by (57)Fe Mossbauer spectroscopy at room temperature. In the analysis of the spectra, the preferential occupation by Al or Si of the Fe (12k) sites in the hexagonal R(2)Fe(17) phase was taken into account. The hyperfine parameters variations are discussed on the grounds of local crystallographic details at the inequivalent iron sites, altered by the composition modifications. The low values of the isomer shifts and quadrupole interactions suggest small electronic charge redistribution in Y(2)Fe(17-x)M(x)A(y) as compared to Y(2)Fe(17). However, the isomer shift variations upon Wigner-Seitz cell volume changes evidence for screening and electron transfer effects. In order to provide a more consistent picture of the local effects of interstitial versus substitutional atoms in R(2)(Fe,M)(17)A(y) compounds, the discussion of the present results is extended to (57)Fe Mossbauer data obtained on the parent compounds and their nitrides. (C) 1997 American Institute of Physics.

Dr. Andrei GALATANU

Scientific Researcher I