National Institute Of Materials Physics - Romania

Raman investigations on nanocomposites obtained by loading various amounts of vapor grown carbon nanofibers within an isotactic polypropylene matrix, and gamma irradiated in air, at various integral doses ranging between 0 and 27 kGy, are reported. The analysis is focused on the polymer's answers as revealed by Raman spectroscopy and investigate in detail the effect of ionizing radiation on the position of the Raman line originating from the polymer. The as-obtained data are correlated to the elastic features of the nanocomposites. A competition between gamma irradiation and loading by carbon nanofiber, resulting in the stretching of the polymeric matrix and revealed as a displacement of Raman lines towards smaller wavenumber is reported. It is concluded that side groups (CH3) are less affected by the loading with carbon nanofibers,

Ti6Al4V cranial prostheses in the form of patterned meshes were 3D printed by selective laser melting in an argon environment; using a CO2 laser source and micron-sized Ti6Al4V powder as the starting material. The size and shape of prostheses were chosen based on actual computer tomography images of patient skull fractures supplied in the framework of a collaboration with a neurosurgery clinic. After optimizations of scanning speed and laser parameters, the printed material was defect-free (as shown by metallographic analyses) and chemically homogeneous, without elemental segregation or depletion. The prostheses were coated by radio-frequency magnetron sputtering (RF-MS) with a bioactive thin layer of hydroxyapatite using a bioceramic powder derived from biogenic resources (Bio-HA). Initially amorphous, the films were converted to fully-crystalline form by applying a post-deposition thermal-treatment at 500 degrees C/1 h in air. The X-ray diffraction structural investigations indicated the phase purity of the deposited films composed solely of a hexagonal hydroxyapatite-like compound. On the other hand, the Fourier transform infrared spectroscopic investigations revealed that the biological carbonatation of the bone mineral phase was well-replicated in the case of crystallized Bio-HA RF-MS implant coatings. The in vitro acellular assays, performed in both the fully inorganic Kokubo's simulated body fluid and the biomimetic organic-inorganic McCoy's 5A cell culture medium up to 21 days, emphasized both the good resistance to degradation and the biomineralization capacity of the films. Further in vitro tests conducted in SaOs-2 osteoblast-like cells showed a positive proliferation rate on the Bio-HA RF-MS coating along with a good adhesion developed on the biomaterial surface by elongated membrane protrusions.

Iron oxide nanoparticles have been extensively studied for challenges in applicable areas such as medicine, pharmacy, and the environment. The functionalization of iron oxide nanoparticles with dextran opens new prospects for application. Suspension characterization methods such as dynamic light scattering (DLS) and zeta potential (ZP) have allowed us to obtain information regarding the stability and hydrodynamic diameter of these suspended particles. For rigorous characterization of the suspension of dextran-coated iron oxide nanoparticles (D-MNPs), studies have been performed using ultrasound measurements. The results obtained from DLS and ZP studies were compared with those obtained from ultrasound measurements. The obtained results show a good stability of D-MNPs. A comparison between the D-MNP dimension obtained from transmission electron microscopy (TEM), X-ray diffraction (XRD), and DLS studies was also performed. A scanning electron spectroscopy (SEM) image of a surface D-MNP layer obtained from the stable suspension shows that the particles are spherical in shape. The topographies of the elemental maps of the D-MNP layer showed a uniform distribution of the constituent elements. The homogeneity of the layer was also observed. The morphology of the HeLa cells incubated for 24 and 48 h with the D-MNP suspension and D-MNP layers did not change relative to the morphology presented by the control cells. The cytotoxicity studies conducted at different time intervals have shown that a slight decrease in the HeLa cell viability after 48 h of incubation for both samples was observed.

Monolayers of transition metal (from the group VI B) dichalcogenides (MoS2, MoSe2, WS2 and WSe2) show nonvolatile resistance switching: a transition from a high to a low resistance state. Here we propose two explanations for this behaviour. The first one is that the transition metals swaps from a trigonal prismatic to an octahedral coordination (due to a high applied electric field and pressure) and thus the monolayer switches from a semiconducting to a metallic phase. The second one is a two-step process where the high electric field and pressure break the M-X bonds and the transition metal atoms become firstly tetrahedrally coordinated and afterwards square-planar coordinated. Thus, all transition metal and chalcogen atoms are in the same plane, and the transition metal atoms are in contact with the atoms of the top and bottom electrodes.

Indium-doped zinc oxide (IZO) and aluminium-doped zinc oxide (AZO) thin films were grown by radio-frequency (RF) magnetron sputtering onto optical glass substrates and their structural, morphological, and optical properties were discussed in terms of varying the sputtering power as 40 W, 60 W, 80 W, and 100 W. No heating substrate or any post-thermal treatment was performed. The structural features were analyzed by grazing incidence X-ray diffraction and revealed the amorphous phase for IZO samples, while the AZO thin films inherited the Wurtzite structure of zinc oxide. The morphological properties were investigated by atomic force microscopy (AFM), in tapping mode and scanning electronmicroscopy (SEM). The AFM images showed relatively uniform and smooth surfaces for all prepared structures. The optical transmission spectra proved the excellent theoretical values of transparency for metallic oxides in the visible region of the electromagnetic spectrum, i.e. similar to 60% for IZO and similar to 70% for AZO. The obtained results showed that even without any thermal treatment the structural, morphological, and optical properties of IZO and AZO thin films prepared by RF magnetron sputtering are similar with those for samples subjected to medium or high temperatures.

Latest developments in the field of high power ultra-short pulse lasers have led to intensive studies dedicated to the fabrication possibility of new antireflective coatings which exhibit high damage threshold. Therefore, this study is focused on the deposition and characterization of metal oxide heterostructures followed by laser-induced damage threshold tests which evidence their application in high power laser optics. Al2O3, SiO2, and HfO2 layers are combined to obtain different heterostructures, i.e. HfO2/Al2O3/HfO2/Al2O3/HfO2 and HfO2/SiO2/HfO2/SiO2/HfO2. The metal oxide heterostructures are deposited in a controllable oxygen atmosphere, either at room temperature or high temperatures (600 degrees C) by pulsed laser deposition (PLD). The morphological, structural and optical properties of the as-deposited heterostructures are first investigated. Atomic force microscopy and spectroscopic ellipsometry investigations reveal a lower roughness of the heterostructures based on HfO2/Al2O3 layers grown at 600 degrees C as compared to those grown at room temperature. Furthermore, following the laser-induced damage threshold (LIDT) tests carried out with a Ti-Sapphire laser, higher LIDT values are obtained for the HfO2/Al2O3-based heterostructures than for the HfO2/SiO2-based heterostructures. The ability to control the morphological and structural properties of the antireflective coatings by modifying the deposition parameters of the metal oxide heterostructures demonstrates that PLD is a suitable technique for the manufacturing of antireflective coatings for high power ultra-short laser systems.

We present an extension of the dynamic electrical model, which enable us to explain some important features of the perovskite solar cells (PSC), like the shape of the hysteresis and the appearance of the ?bump? in the so called reverse scan, without requiring any additional assumptions. We give analytical expressions in terms of the Lambert?s function W for the open circuit voltage, the stationary current, and the instantaneous current, which can be written also in terms of elementary functions for the most part of the ranges of the physical parameters. The initial polarization of the cell, modeled as the charging of a capacitor with voltage dependent capacitance, is consistently determined in the model, from the initial stationary conditions. This is inline with a previously observed sharp increase of the PSC capacitance beyond the open-circuit voltage. Besides the known features, we obtain characteristics that were not yet analyzed experimentally, like the change of the bump from the reverse scan branch of the J?V characteristic to the forward scan, with the increase of the poling voltage (or the increase of the PSC capacitance).

Single-phase Ce3+-doped BaTiO3 powders described by the nominal formula Ba1-xCexTi1-x/4O3 with x = 0.005 and 0.05 were synthesized by the acetate variant of the sol-gel method. The structural parameters, particle size, and morphology are strongly dependent on the Ce3+ content. From these powders, dense ceramics were prepared by conventional sintering at 1300 degrees C for 2 h, as well as by spark plasma sintering at 1050 degrees C for 2 min. For the conventionally sintered ceramics, the XRD data and the dielectric and hysteresis measurements reveal that at room temperature, the specimen with low cerium content (x = 0.005) was in the ferroelectric state, while the samples with significantly higher Ce3+ concentration (x = 0.05) were found to be in the proximity of the ferroelectric-paraelectric phase transition. The sample with low solute content after spark plasma sintering exhibited insulating behavior, with significantly higher values of relative permittivity and dielectric losses over the entire investigated temperature range relative to the conventionally sintered sample of similar composition. The spark-plasma-sintered Ce-BaTiO3 specimen with high solute content (x = 0.05) showed a fine-grained microstructure and an almost temperature-independent colossal dielectric constant which originated from very high interfacial polarization.

MgB2 green bodies were prepared by magnetic field slip casting in ethyl alcohol with added polyethyleneimine dispersing agent under a high magnetic field, mu H-0(0) = 12 T. Samples were further processed by spark plasma sintering (SPS) and characterized for superconducting properties. Slip casting provides texturing of MgB2 (the degree of c-axis orientation is approximately 3.5%), which is further increased significantly (to about 21%) in the SPSed sample. The critical current density (J(c)) displays anisotropy relative to the orientation of the measuring magnetic field. Specific features of J(c)(H, T) and of the pinning force extracted from magnetic measurements with the field parallel and perpendicular to H-0 are discussed.

Staggered gap radial heterojunctions based on ZnO-CuxO core-shell nanowires are used as water stable photocatalysts to harvest solar energy for pollutants removal. ZnO nanowires with a wurtzite crystalline structure and a band gap of approximately 3.3 eV are obtained by thermal oxidation in air. These are covered with an amorphous CuxO layer having a band gap of 1.74 eV and subsequently form core-shell heterojunctions. The electrical characterization of the ZnO pristine and ZnO-CuxO core-shell nanowires emphasizes the charge transfer phenomena at the junction and at the interface between the nanowires and water based solutions. The methylene blue degradation mechanism is discussed taking into consideration the dissolution of ZnO in water based solutions for ZnO nanowires and ZnO-CuxO core-shell nanowires with different shell thicknesses. An optimum thickness of the CuxO layer is used to obtain water stable photocatalysts, where the ZnO-CuxO radial heterojunction enhances the separation and transport of the photogenerated charge carriers when irradiating with UV-light, leading to swift pollutant degradation.