National Institute Of Materials Physics - Romania

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5781 articles found

3211. Nanoblast Synthesis and Consolidation of (La0.8Sr0.2) (Ga0.9Mg0.1)O3-delta Under Spark Plasma Sintering Conditions

Authors: Vasylkiv, O; Borodianska, H; Badica, P; Zhen, Y; Tok, A

Published: JAN 2009, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 9, 149, DOI: 10.1166/jnn.2009.J008

Four-cation nanograined strontium and magnesium doped lanthanum gallate (La0.8Sr0.2) (Ga0.9Mg0.1)O3-delta (LSGM) and its composite with 2 wt% of ceria (LSGM-Ce) were prepared. Morphologcally homogeneous nanoreactors, i.e., complex intermediate metastable aggregates of desired composition were assembled by spray atomization technique, and subsequently loaded with nanoparticles of highly energetic C3H6N6O6. Rapid nanoblast calcination technique was applied and the final composition was synthesized within the preliminary localized volumes of each single nanoreactor on the first step of spark plasma treatment. Subsequent SPS consolidations of nanostructured extremely active LSGM and LSGM-Ce powders were achieved by rapid treatment under pressures of 90-110 MPa. This technique provided the heredity of the final structure of nanosize multimetal oxide, allowed the prevention of the uncontrolled agglomeration during multicomponent aggregates assembling, subsequent nanoblast calcination, and final ultra-rapid low-temperature SPS consolidation of nanostructured ceramics. LaSrGaMgCeO3-delta nanocrystalline powder consisting of similar to 11 nm crystallites was consolidated to LSGM-Ce nanoceramic with average grain size of similar to 14 nm by low-temperature SPS at 1250 degrees C. Our preliminary results indicate that nanostructured samples of (La0.8Sr0.2)(Ga0.9Mg0.1)O3-delta with 2 wt% of ceria composed of similar to 14 nm grains can exhibit giant magnetoresistive effect in contrast to the usual paramagnetic properties measured on the samples with larger grain size.

3212. Films and crystalline powder of PbI2 intercalated with ammonia and pyridine

Authors: Preda, N; Mihut, L; Baibarac, M; Baltog, I; Ramer, R; Pandele, J; Andronescu, C; Fruth, V

Published: JAN 2009, JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 20, 470, DOI: 10.1007/s10854-008-9681-6

Thin films and crystalline powder of PbI2 intercalated with ammonia or pyridine have been studied by optical absorption, Raman scattering, photoluminescence, FTIR spectroscopy and thermo-gravimetric analysis. Ammonia intercalated PbI2 shows an increased optical band gap, of about 0.6 eV, with an intense broad emission band peaking at about 2.3 eV as signature in the photoluminescence spectrum. The intercalation of PbI2 with ammonia is noticed in the Raman spectrum by the appearance of new lines situated in low frequency range. The D-3d coordination geometry of Pb2+ in the PbI2 crystal is reduced by compression to orthorhombic one, the distribution of the electronic states in valence band is also changed. Thus, the top of the valence band undergo a deformation inducing a weakness of the interaction between the lead and iodine ions within a layer. Also the PbI2 intercalated with pyridine is featured by optical and vibration properties different that of pure crystalline powder. Finally, the intercalation of PbI2 with different molecules changes the basic semiconducting properties of the crystal. Thermal analyses and infrared absorption spectra have been used to study the desorption of guests species from PbI2 in order to evaluate the stability range and morphological changes with temperature.

3213. Synthesis, structural characterization, and photocatalytic properties of iron-doped TiO2 aerogels

Authors: Popa, M; Diamandescu, L; Vasiliu, F; Teodorescu, CM; Cosoveanu, V; Baia, M; Feder, M; Baia, L; Danciu, V

Published: JAN 2009, JOURNAL OF MATERIALS SCIENCE, 44, 364, DOI: 10.1007/s10853-008-3147-3

Fe(III)-doped TiO2 aerogels are prepared by acid catalyzed sol-gel method followed by supercritical drying, and then heat treatment. Raman spectra together with X-ray diffraction (XRD) and selected area electron diffraction (SAED) patterns of the iron-doped TiO2 aerogel samples revealed the existence of both anatase and brookite crystalline phases. It was found that the brookite phase formation is favored by the increase of the iron content in the dried samples. XRD measurements show that the lattice constant c of anatase phase decreases with the dopant addition, while the value of a remains essentially unchanged. The microstructure of the investigated samples is relatively compact with small mesopores as revealed from transmission electron microscopy (TEM). The most enhanced photocatalytic activity was exhibited by the TiO2 aerogel sample with 1.8 at.% Fe(III) whose apparent rate constant of the salicylic acid photodegradation was found to be of almost six times higher than that of Degussa P25.

3214. Characterization of Superconducting Wires By Cone-Beam Micro-Tomography

Authors: Tiseanu, I; Craciunescu, T; Badica, P; Aldica, GV; Rindfleisch, M

Published: 2009, 2008 IEEE NUCLEAR SCIENCE SYMPOSIUM AND MEDICAL IMAGING CONFERENCE (2008 NSS/MIC), VOLS 1-9, +, DOI:

Commercial wires of Nb3Sn and NIgB2 were inspected through X-ray cone-beam micro-tomography (mu CT). Details of the architecture of the wires of different topologies were visualized. In the case of MgB2 wires this allowed to compare the geometrical perfection of the component elements between the wires with 18 and 7 superconducting sub-elements heat treated for different conditions. Defects such as 3D voids and interruption of the diffusion barriers were also visualized. High resolution 3D-mu CT observations of the Nb3Sn wire architecture allowed also direct and non-invasive determination of the twist-pitch parameter. 3D tomography shows important advantages over 2D traditional microscopy methods.

3215. Study of the Radiation Hardness of Silicon Sensors for the XFEL

Authors: Fretwurst, E; Januschek, F; Klanner, R; Perrey, H; Pintilie, I; Renn, F

Published: 2009, 2008 IEEE NUCLEAR SCIENCE SYMPOSIUM AND MEDICAL IMAGING CONFERENCE (2008 NSS/MIC), VOLS 1-9, +, DOI:

Imaging experiments at the XFEL pose unprecedented requirements to the detectors in terms of radiation tolerance: Fluxes of up to 10(16) (12 keVphotons/cm(2)) corresponding to approximately 10(9) Gy in silicon, are expected. An irradiation station has been set up in the DORIS beam line F4, MOS test structures have been irradiated, and first results on the dose dependence of the CN-characteristics, surface current density, and interface trap density have been obtained.

3216. INVESTIGATION OF ELECTRICAL PROPERTIES OF CARBON NANOTUBES

Authors: Ciurea, ML; Stavarache, I; Lepadatu, AM; Iancu, V; Dragoman, M; Konstantinidis, G; Buiculescu, R

Published: 2009, CAS: 2009 INTERNATIONAL SEMICONDUCTOR CONFERENCE, VOLS 1 AND 2, PROCEEDINGS, +, DOI: 10.1109/SMICND.2009.5336593

This paper presents the investigation of electrical properties of carbon nanotubes (CNT). A sandwich configuration, quartz substrate/Cr/Al/CNT (partially immersed in SiN)/Cr/Al was investigated. The CNT are mainly oriented parallel with the electrodes. Current - voltage characteristics were taken at 20 K and room temperature and a current - temperature characteristic was taken at constant voltage (20 mV). The I - V characteristics are almost linear, while the G - V characteristics present some peaks and dips, interpreted as voltage percolation thresholds. The I - T and R - T characteristics are also linear (except at low temperatures). The investigated structures have a high electrical polarizability.

3217. Microstrip Bandpass Filters with a Maximum Number of Attenuation Poles

Authors: Lojewski, G; Militaru, N; Banciu, MG

Published: 2009, 2009 32ND INTERNATIONAL SPRING SEMINAR ON ELECTRONICS TECHNOLOGY, +, DOI:

In this paper a novel configuration of microwave planar filters, with multiple cross-couplings and with a number of attenuation poles equal to the order of the filter, is investigated. The location of the poles on the frequency axis can be controlled, allowing the design of band-pass filters with improved selectivity with respect to the adjacent channels. A microstrip bandpass filter with the novel configuration was designed, verified by em-field simulation, fabricated and tested. The response of the designed filter are in good agreement with the specification, confirming the possibilities of realizing microwave band-pass filters of a relatively low order with moderate losses and with improved selectivity performances.

3218. A versatile gas-flow proportional counter for Mossbauer spectroscopy

Authors: Bibicu, I; Nicolescu, G; Cretu, C

Published: 2009, ISIAME 2008, +, DOI: 10.1007/978-3-642-01369-0_77

This article presents a versatile gas-flow proportional counter for surface and transmission Mossbauer spectroscopy, suitable for studies with Fe-57, Sn-119 and Eu-151 isotopes. The main advantages obtained by new design are: (1) the height of the detection volume can be changed in large limits from 0 to 38 mm, (2) the detection volume can be choose symmetrical or not in respect with anode plan, (3) the anode replacement is easily (4) and different anode configuration can be used. The characteristics of the detector, operating at room temperature, are reported.

3219. Synthesis and characterization of Mn2+ doped ZnS nanocrystals self-assembled in a tight mesoporous structure

Authors: Nistor, SV; Nistor, LC; Stefan, M; Mateescu, CD; Birjega, R; Solovieva, N; Nikl, M

Published: JUL-AUG 2009, SUPERLATTICES AND MICROSTRUCTURES, 46, 311, DOI: 10.1016/j.spmi.2008.10.001

We report the synthesis, by a surfactant-assisted liquid-liquid reaction, of nanocrystalline ZnS doped with 0.2 mol% Mn2+ ions self-assembled in a mesoporous structure. The XRD measurements demonstrate the formation of a sponge-like mesoporous material with a tight distribution of pores of 1.8 nm mean diameter built from cubic ZnS nanocrystals of 1.8 nm average size. TEM investigation confirms the formation of the mesoporous structure with walls of 3.1 nm mean thickness built from nanocrystallites of cubic ZnS. The ordering effect of self-assembling, which is reflected in the tight size distribution of crystallites and pores, might be also responsible for the well resolved EPR spectra, attributed to the presence of three types of isolated Mn2+ paramagnetic centers. (C) 2008 Elsevier Ltd. All rights reserved.

3220. Magnetism and Structural Phase Transformation in Fe/Fe oxide Nanopowders

Authors: Crisan, O; Crisan, AD; Skorvanek, I; Kovac, J

Published: 2009, 13TH INTERNATIONAL CONFERENCE ON RAPIDLY QUENCHED AND METASTABLE MATERIALS, 144, DOI: 10.1088/1742-6596/144/1/012027

Fe / Fe3O4 (magnetite) powders obtained by ball milling at room temperature, undergo an incomplete redox reaction with formation of FeO. This reaction is favoured due to the high energy developed during the milling and alloying. Concurrent effects of the milling, such as grain refinement down to the nanometric scale lead at the end of the milling processes to a mixed multiphased nanopowder, with a homogeneous dispersion of Fe and Fe oxide grains. Such ferromagnetic - antiferromagnetic systems are extensively studied due to their exchange bias properties, extremely useful in technological applications. We study the phase transformation that leads to a multiphased metal / oxide microstructure with an energy-dispersive in-situ X-ray diffraction experiment using the synchrotron radiation. This study allows direct collection of X-ray spectra after few minutes exposure, at selected temperatures, ranging between 20 degrees C and 1000 degrees C. Magnetic behavior has been studied for as-milled and annealed samples and the obtained magnetic parameters are correlated to the microstructure and phase composition at each stage of annealing. A significant exchange bias effect, related to FeO content, is observed for as-milled sample, the effect being less pronounced upon annealing the nanogranular powder.