Publications

In this study, Fourier Transform Infrared Spectroscopy (FTIR) in Attenuated Total Reflectance mode was employed as main characterization technique to investigate the reaction mechanisms in vitro (SBF) of bioglass and glass-ceramic sputtered coatings. Two bioglass compositional systems are compared in order to gain more information regarding their in vitro bioreactivity. Important correlations between the concentration of non-bridging silicon-oxygen (Si-O-NBO) groups and the content of network modifiers were found. FTIR revealed that the high concentrations of Si-O-NBO groups are promoting the enhancing of coatings' reactivity. This information could be very useful for the development and tailoring of new bioactive glasses with an optimum biological behaviour. By varying the compositional features and the structural state, the sputtered glassy coatings exhibited different in vitro behaviour: inertness, resorbability and bioactivity.

The application area of piezoceramic materials and devices based on such materials is continuously extended. The working conditions for such devices and structures may be sometimes very hard such as low and high temperatures, nuclear radiation, high pressure and so on. Such conditions may affect to some extent the transducer performances due to the changes of the basic properties of piezoceramic materials used as sensors. In this regard we have investigated the changes of the main piezoelectric properties of two typically hard and soft piezoceramics within a large temperature range from 2 to 600 K. All parameters measured showed a rather steady increase or decrease with increasing temperature. The results were discussed in terms of intrinsic and domain wall contribution to the dielectric and piezoelectric response of materials.

Zeolites NaY and ZSM-5 were used as hosts for styrene polymerization after ion-exchange with europium ions. The parent and hybrid, polystyrene coated Eu-NaY (Eu-NaY/PS) and Eu-ZSM-5 (Eu-ZSM-5/PS) zeolites were investigated by using thermal analysis, SEM, PXRD, FT-IR, DR-UV/Vis, steady state and time-resolved photoluminescence spectroscopy. FT-IR spectra evidenced for the interaction between the zeolitic hosts and polystyrene while the PXRD spectra supported for the presence of the polymer inside the channels/pores of Eu-NaY/PS and Eu-ZSM-5/PS materials. The optical properties of Eu-NaY/PS and Eu-ZSM-5/PS were significantly changed relative to those of the parent zeolites, giving further evidence for the presence of polymer inside zeolites. An interesting case is presented by NaY zeolite: following styrene polymerization, the polymer interacted selectively with one of the two main species co-existing inside zeolite while for ZSM-5 a similar effect was not observed.

This paper discusses the quantum confinement effects in nanometric structures that form low dimensional systems. In such systems, each surface/interface acts like a potential barrier, i.e. the wall of a quantum well, generating new energy levels. These levels are computed in a model that uses the approximation of the infinite rectangular quantum wells. The model is adapted for 2D, 1D and 0D systems, respectively. Different applications are discussed. The differences between the model results and the experimental data are proved to be of the same order of magnitude as the differences between the levels computed within the frame of infinite and finite quantum well approximations.

Optical and electrical behavior of Giant Magnetoresistivc (GMR)/Tunneling Magnetoresistive (TMR) multilayer thin films were controlled adjusting thermionic vacuum arc plasma parameters. Smooth, dense and adherent films were prepared using optimized plasma conditions. A new setup for simultaneous depositions of pure materials was made, having inside the vacuum chamber three simultaneous discharges. To obtain the discharge all of the tungsten filaments of the thermionic vacuum arc guns were heated by a 45-55 A current. The emitted electrons were focused on a tungsten coated carbon crucible anode, filled with Cu, and the others crucible anodes filed with MgO, Co and Ag, respectively. The anode applied voltages for Cu, MgO Co and Ag were up to 1500 V, 1700V 1800V and 820V respectively. An optimization of the geometrical parameters as the distance between the cathode and the anode, and of the external parameters as the discharge voltage and the heating current of tungsten current filament was performed. Structural and morphological properties of the prepared films were analyzed by scanning electron microscopy (SEM). The behavior of the obtained films was first analyzed in a Magneto-Optical Kerr Effect (MOKE) experiment. The electrical resistance behavior of the prepared films was determined in a magnetic field which values varied from 0.4 T to 0.4 T. The important changes in the values of the electrical resistance of the films were observed and correlated to the plasma conditions.

The wettability of 18 dental impression materials, commercially available, during their working time was investigated using the contact angle method, as a good wettability is desired to obtain a high fidelity impression. Polyetheric materials, A-silicones with added surfactants and C-silicones were found to have a good wettability. Alginate was found to be the most hydrophilic material, but this quality decreases in time. In the paper an explanation for the time dependence of the contact angle is advanced.

The two crystallographic modifications of AuSe, alpha-AuSe and beta-AuSe, were studied by Au-197 Mossbauer spectroscopy. Despite the different crystal structures, the Mossbauer spectra of the two phases are nearly the same, and reveal the presence of two gold sites with Mossbauer parameters typical for Au-I and Au-III. The Mossbauer-Lamb factor of the Au-I is less than half of that of the Au-III. Calculations using the WIEN2k program reproduce the experimental results quite well and also yield the signs of the electric field gradients.

Carbon nanotubes are attractive materials with numerous possibilities of applications in various domains. Nevertheless, pertinent characterization studies are required in order to insure reproducibility in preparation, handling and incorporation in devices. Several spectroscopic tools have been developed so far, such as transmission electron microscopy and near-field electrical microscopy. Optical techniques have also been improved with the use of Raman Scattering, Surface Enhanced Raman Scattering (SERS) and near-field optical spectroscopy (SNOM). These non-destructive techniques have been used for nanotubes after synthesis and exploited to follow the modifications of their spectroscopic features when they are functionalized or embedded in host matrices. In this paper, we show that, by using SERS conditions, a new effect is observed: a "single-beam pumped'' Coherent anti-Stokes Raman Scattering (CARS). We demonstrate that under a tight-focusing of the excitation light, this emission, resulting from a wave mixing process between the incident laser light (omega(l)) and Stokes Raman light (omega(s)), is generated by a Surface Enhanced Raman Scattering (SERS) mechanism. Since abnormal anti-Stokes/Stokes intensity ratios are also observed for carbon nanotubes in powders, we have investigated in details their behaviour as a function of several parameters which include the excitation wavelengths, the laser power, the sample support, as well as the presence of nanotubes in isolated or in bundled form. It appears that resonance phenomena explain the anti-Stokes/Stokes intensity ratios in the case of powders and that CARS is only observed when SERS conditions are used. In addition, we have investigated other materials in which anomalies are also observed. This is the case of poly(bithiophene) (PBTh) electrochemically polymerized on carbon nanotubes for which its main Raman line at 1450 cm(-1) is enhanced, this enhancement being presumably generated by the plasmon excitation of metallic tubes. In the case of PEDOT, the analysis of the anti-Stokes branch provides additional information on the functionalization of carbon nanotubes with this polymer.

Different phases of boron nitride (BN) nano-structures are synthesized from an hBN ceramic target immersed in acetone, by ablation with a high power pulsed Nd: YAG laser. Transmission electron microscopy (TEM) and electron diffraction (ED) are used to identify the morphology and structure of the prepared colloidal suspensions. It is revealed that by varying solely a single experimental parameter, i.e. the laser pulse fluency, a large variety of BN nanostructures can be produced: nanotubes, very thin graphene-like foils, nano-curls and nanoparticles, all with the hexagonal graphite-like hBN structure, as well as high pressure BN phases: orthorhombic explosion E-BN nano-rods, or cubic diamond-like cBN nano-particles.