Publications

The modification of the polyester track membranes by treatment in radiofrequency plasma generated by capacitive coupled parallel plate discharge in air and ammonia was studied. The investigation of the surface properties (roughness, pore size distribution, contact angle) before and after the plasma treatments was performed. The treatment resulted in increase of the surface roughness and of the pores effective diameter and change of wettability. Membranes presenting lower or higher contact angles, as compared with the initial one can be obtained by selecting adequate values for the radiofrequency power and treatment time values. (c) 2005 Elsevier B.V. All rights reserved.

The effect of light-induced photodarkening in amorphous As100-xSex (x=40 divided by 98) thin films for different thickness and film composition was investigated. It was established a strong dependence of the red shift of the absorption edge and refractive index under light irradiation on the film composition and thermal treatment. It was established that the more sensitive films to photodarkening and holographic recording correspond to non-stoichiometric compositions of As55Se45 and As60Se40 glasses. The experimental results are interpreted in terms of structural optical polymerization process, which includes the transformation of As4Se4 and Se-2 structural units in homogenius AsSe3/2 network.

Microbiological load of green coffee is a real problem considering that it is extremely sensitive to contamination. Irradiation is a decontamination method for a lot of foodstuffs, being a feasible, very effective and environment friendly one. Beans and ground green coffee were irradiated with electron beams up to 40 kGy. Microbial load, rheological behavior, electron paramagnetic resonance (EPR) and visible spectroscopy were carried out. The results show that electron beam irradiation of green coffee could decontaminate it without severe changes in its properties. (c) 2005 Elsevier B.V. All rights reserved.

X-ray Photoelectron Spectroscopy (XPS) was used to investigate the chemical state of ZrC coatings deposited by cathodic arc method. A chemistry model of the ZrC films has been proposed. It was pointed out that on the films surface a highly oxidized passive layer, containing also carbon and oxygen as contaminants, was formed. The film bulk was composed by a mixture of ZrC (the dominant phase), ZrO2 and free carbon.

The simultaneous discharge of Fe (or Co) and, respectively, CU metal sources via thermionic vacuum arc (TVA) was used as a new processing method to obtain granular magneto-resistive films. The nano-structured films with thicknesses of 120 +/- 1 nm and 250 +/- 1 nm were obtained in definite conditions and subsequently characterized via electrical measurements at room temperature, in applied magnetic field. The paper reveals the importance of different specific factors (from size and dispersion effects to annealing influence) on the magnetoresistance behavior. A special contribution of the Mossbauer Spectroscopy, concerning the local structure and interactions as well as the magnetic phase characterization, was emphasized.

Quantum confinement effects in different kinds of nanocrystalline silicon systems are experimentally and theoretically investigated. Porous silicon structured as a nanowire network and silicon nanodots embedded in amorphous silicon dioxide are studied. The main quantum confinement effect in both cases is represented by the appearance of new energy levels in the silicon band gap. The corresponding energies can be experimentally determined from the current - temperature characteristics, which show an Arrhenius-like behavior. The curves present several activation energies between liquid nitrogen temperature and room temperature. The energy levels can be evaluated from a quantum well model. The fundamental level is located at the top of the valence band. The change of the activation energy is then related with the filling of the levels. The ratios of the consecutive activation energies in the current - temperature characteristics prove that the excitation undergoes the angular momentum conservation law imposed by the applied electric field. The estimation of the mean size of the nanocrystals from the values of the activation energies is in good agreement with the microstructure investigations performed on the samples. The confinement levels are also in good agreement with the photoluminescence measurements..

Zero-field-cooling magnetization relaxation measurements performed on Bi2Sr2CaCu2O8+delta single crystals in the low-temperature domain, with the external magnetic field oriented parallel to the c axis, reveal the ordering of the creeping vortex system due to the macroscopic currents induced in the sample. This explains many apparently conflicting results concerning the vortex phase diagram of disordered high-temperature superconductors, which have led to the dichotomy elastic vortex glass-plastic vortex assembly for the vortex phase at high magnetic fields.

TEM-SAED investigations were performed on PZT films, to elucidate the role of pyrolysis conditions on orientation selection. For short pyrolysis, occurrence of the metastable fluorite and the interfacial PtxPb template layer are the factors inducing the (111) PZT orientation. For advanced pyrolysis, the TiO2 interfacial layer could be responsible for (100) PZT strong orientation. To further investigate the stoichiometry of PZT and interfacial layers, we performed heavy ion RBS and NRBS measurements. Only a substoichiometric TiO2-x layer is found for the short pyrolized film whereas two Ti and O rich layers were observed for advanced pyrolysis. The thicker oxygen rich TiO2-x bottom layer, observed by TEM and NRBS analysis, could lead to (100) texture, observed for oxidizing conditions at the interface during pyrolysis. (c) 2005 Elsevier B.V. All rights reserved.

Indium-tin oxide (ITO) sol-gel films have been obtained with the void concentration up to 50%. The films are nanostructured with nanocrystals of In2O3:Sn and nanovoids. The information obtained from derivative thermo-gravimetry was used to design the annealing program for ITO film formation with a high void concentration. Multilayer films were obtained by successive deposition. The thickness of one layer was about 9 nm. By successive depositions, the void density of the film is reduced. Quantitative analysis of the void density has been performed by spectroscopic ellipsometry. The conductivity of the films can be varied in a large range by annealing in vacuum or in air, at temperature higher than 200 degrees C.

Aluminophosphate glasses doped with Fe, Mn, and Cr have been obtained by a wet non-conventional method. Structural information was provided by IR absorption spectra in the range 2000-500 cm(-1). The optical behaviour (transmission and refractive index) of the samples has been studied by UV-VIS-NIR spectroscopy. The Fe valence state and the local coordination were also analysed via Fe-57 Mossbauer spectroscopy, whose data revealed the redox equilibrium in the Fe-doped glasses according to the redox potentials of the transition ions.