Publications

Several iron complexes containing a tri-iron-oxo-cation linked to short chain fatty acids have been used in the preparation of films by self-assembling from solution on glass slides via two procedures: direct evaporation and dragging out. The ordered lamellar structure thus obtained has been investigated by X-ray diffraction. A relation between the lamellar spacing and the disorder in the film has been obtained from the X-ray diffraction data.

The Hall effect and magnetoresistance of a mesoscopic system having a four-probe ring geometry are calculated in a tight-binding model, either ordered or disordered, as function of magnetic flux and Fermi energy. The changes induced in the spectrum by the magnetic field affect differently the Aharonov-Bohm (AB) oscillating pattern of the two resistances: after the gap reaches the Fermi energy, the Hall effect remains bounded while the magnetoresistance increases exponentially with the sample size. The results are shown to depend significantly on the number and geometry of the probes.

Temperature induced surface transitions in liquid crystal tilted homogeneous cells are experimentally studied. The results are theoretically explained by an elastic theory of surface transitions and the resulting values for the effective splay-bend elastic constant (k) over bar(13) for each liquid crystal material are compared with the results from experience with other types of surface anchoring.

Spin probe investigations on the molecular motions in the glass transition range are reported. Within the free volume approximation, a Fox-Flory dependence of the narrowing temperature on the molecular masses is derived. The experimental results support this theoretical prediction. The glass transition temperature is estimated from the spin probe data, within various approaches, and compared to the results obtained by differential scanning calorimetry.

The gradual substitution of Cu by Ag in the Al62Cu25.5-xAgxFe12.5 icosahedral phase (x less than or equal to 10) is investigated by X-ray diffraction from the viewpoint of the induced structural changes. The phonon and random phason disorders, estimated from diffraction linewidths, increase with x, the latter showing, however, an induction range of Ag concentrations. EXAFS results at the CuK and FeK edges show. for low Ag contents, and enhanced disorder in the first coordination sphere, partly relaxed for higher x values. The 6D hypercubic lattice parameter is found to be independent of the Ag content, despite the large diameter of monovalent Ag. The latter facts suggest a d-sp hybridization of the Ag bonds to the surrounding Al, taking place above a certain x value.

SnO2 sensors were prepared by precipitating Sn(OH)(4) from an aqueous solution of SnCl4 or by evaporating SnO2 in the UHV. Subsequent X-ray and TEM measurements show grain sizes in the nanometer range after annealing at different temperatures or annealing times. The effect of Pt and Pd doping upon the response to CO is studied. Parameters, which we focused on, are sensor signal dependent on the operating temperature and dependent on the gas concentration. The results for ceramic sensors are compared with those for thin film sensors.

First searches for the coherent dissociation of relativistic oxygen nuclei into four alpha particles are reported. It is shown that reactions of this type are characterized by a significantly lower decay temperature than the conventional multifragmentation of residual projectile nuclei. The momentum spectra and correlations of alpha particles are not reproduced by the simple statistical model of direct fragmentation. The possibility that the oxygen nucleus undergoing fragmentation acquires a nonzero angular momentum in the collision process is discussed.