National Institute Of Materials Physics - Romania

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11. Hybrid organic-inorganic thin films based on zinc phthalocyanine and zinc oxide deposited by MAPLE
Authors: Socol, M; Preda, N; Costas, A; Breazu, C; Stanculescu, A; Rasoga, O; Popescu-Pelin, G; Mihailescu, A; Socol, G

Published: FEB 15 2020, DOI: 10.1016/j.apsusc.2019.144317

Abstract: Hybrid organic-inorganic thin films based on zinc phthalocyanine (ZnPc) and ZnO nanoparticles were deposited by Matrix Assisted Pulsed Laser Evaporation (MAPLE). Synthesized by a simple wet chemical precipitation method, the ZnO nanoparticles were featured by a hexagonal wurtzite structure, a band-gap value of similar to 3.3 eV and emission bands typical for this semiconductor. The hybrid films containing ZnPc and various amounts of ZnO nanoparticles were evaluated from morphological, compositional, structural, optical and electrical point of view. No chemical decomposition of the organic compound was observed in the FTIR spectra of the deposited layers. The transmittance and photoluminescence spectra recorded on hybrid films disclose the optical signature of both organic (ZnPc) and inorganic (ZnO) components. The electrical measurements carried out under illumination emphasized the importance of the quantity of the inorganic component on the performance parameters of the structures prepared with the hybrid films. Our study provides new insight in the MAPLE deposition of the organic-inorganic hybrid films with potential applications in the photovoltaic cells area.
12. Aminopropyl-silica functionalized with halogen-reactive compounds for antimicrobial applications
Authors: Zarafu, I; Al Taweel, AAJ; Limban, C; Popa, M; Marutescu, L; Chifiriuc, MC; Pircalabioru, GG; Culita, D; Ghica, C; Ionita, P

Published: FEB 1 2020, DOI: 10.1016/j.matchemphys.2019.122353

Abstract: Aminopropyl-silica nanoparticles S0 were obtained and further functionalized with eight halogen-reactive organic compounds 1-8, leading to the S1-S8 hybrid organic-inorganic materials, with spherical morphology and having a 50-200 nm size, as showed TEM analysis. These were further characterized by IR and DLS. Biological assays were performed using five microbial strains, belonging to species frequently encountered in the aetiology of human infections (Enterococcus faecalis, Staphylococcus aureus, Pseudomonas aeruginosa, Escherichia toll and Candida albicans). The obtained materials exhibited promising antimicrobial properties, being active against planktonic, but particularly on biofilm-embedded cells. Among the tested hybrid nanomaterials, S6 seemed to exhibit the most promising antimicrobial profile.
13. Electrospun conductive gold covered polycaprolactone fibers as electrochemical sensors for O-2 monitoring in cell culture media
Authors: Serban, A; Evanghelidis, A; Onea, M; Diculescu, V; Enculescu, I; Barsan, MM

Published: FEB 2020, DOI: 10.1016/j.elecom.2020.106662

Abstract: This work reports the use of electrospun conductive gold covered polycaprolactone fibers for the quantification of dissolved O-2. The morphologies of the electrospun fibers obtained at a static and a dynamic drum collector were investigated by scanning electron microscopy. The reduction process of O-2 at negative potentials is analyzed by cyclic voltammetry and electrochemical impedance spectroscopy (EIS) in sodium phosphate buffer (NaPB) pH 7.0 and in cellular media pH 7.4. The electrochemical sensing performance of Au/PCL towards O-2 quantification in NaPB and cellular media is compared by using three electrochemical techniques: cyclic and linear sweep voltammetry and EIS. Measurements are done in a two electrode configuration, using a silver wire as reference, to show the applicability of the method for O-2 quantification in cellular culture media.
14. Crown-ether functionalized graphene oxide for metal ions sequestration
Authors: Petrescu, S; Avramescu, S; Musuc, AM; Neatu, F; Florea, M; Ionita, P

Published: FEB 2020, DOI: 10.1016/j.materresbull.2019.110643

Abstract: Graphene oxide has been synthesized, additionally derivatized with chloroacetic acid for increase the number of available carboxylic groups and further functionalized with crown-ether moieties. The thus obtained material was characterized by IR, thermal analysis, SEM, Raman, and XPS. Tests on adsorption of several metal cations showed that cooper and iron are more retained than potassium.
15. Texture and interface characterization of iridium thin films grown on MgO substrates with different orientations
Authors: Trupina, L; Nedelcu, L; Banciu, MG; Crunteanu, A; Huitema, L; Constantinescu, C; Boulle, A

Published: FEB 2020, DOI: 10.1007/s10853-019-04004-7

Abstract: Iridium thin films are grown by direct-current plasma magnetron sputtering, on MgO single-crystal substrates with various surface orientations, i.e. (100), (111), and (110). The surface morphology, the crystalline properties of the films, and the substrate-thin-film interface are investigated by atomic force microscopy, X-ray diffraction (XRD), focused ion beam scanning electron microscopy, and high-resolution transmission electron microscopy, respectively. The results reveal that hetero-epitaxial thin films with different crystallographic orientation and notable atomic scale smooth surface are obtained. From the XRD analysis, the following epitaxial relations are obtained: (1) (100)(Ir)||(100)(MgO) out-of-plane and [001](Ir)||[001](MgO) in-plane for Ir grown on MgO(100), (2) (110)(Ir)||(110)(MgO) out-of-plane and [1-10](Ir)||[1-10](MgO) in-plane for Ir grown on MgO(110), and (3) (111)(Ir)||(111)(MgO) out-of-plane and two variants for in-plane orientation [1-10](Ir)||[1-10](MgO) and [1-10](Ir)||[10-1](MgO), respectively, for Ir grown on MgO(111). Because of the large misfit strain (9.7%), the thin films are found to grow in a strain-relaxed state with the formation of geometrical misfit dislocations with a similar to 2.8-nm spacing, whereas thermal strain is stored upon cooling down from the growth temperature (600 degrees C). The best structural characteristics are obtained for the (111)-oriented films with a mosaicity of 0.3 degrees and vanishingly small lattice distortions. The (100)- and (110)-oriented films exhibit mosaicities of similar to 1.2 degrees and lattice distortions of similar to 1% which can be explained by the larger surface energy of these planes as compared to (111).
16. The interplay of work function and polarization state at the Schottky barriers height for Cu/BaTiO3 interface
Authors: Popescu, DG; Husanu, MA; Chirila, C; Pintilie, L; Teodorescu, CM

Published: FEB 1 2020, DOI: 10.1016/j.apsusc.2019.144101

Abstract: The emerging field of electronics based on ferro-functional materials relies on driving effectively and predictably a ferroelectric system between different polarization states through bias applied to metallic contacts. This requires detailed understanding of the growth mechanisms and electronic properties of the interface, including ferroelectric and material - dependent band alignment and Schottky barrier heights. Whether the major contribution at the interface band alignment comes from the work function difference or from the ferroelectric state is still under debate. Here, using X-ray photoemsion and ab-initio calculations, we derive the complex microscopic picture of metal/ferroelectric interface formation, including growth mechanism, valence alteration, ferroelectric-dependent electrostatic potential and thickness - dependent compensation mechanisms of ferroelectricity, starting from the ultrathin growth of Cu up to 100 angstrom on BaTiO3. One establishes the evolution of the band bending and of the build-in potential from the initial probed thickness of the ferroelectric in the range of 3 lambda (lambda - the inelastic mean free path) while gradually approaching the contact region with the metal at higher thickness of the top layer. We find that the well-defined orientation of the ferroelectric polarization lead to a band bending at the interface, which add at the bending expected from the work function difference of the two joining materials.
17. Investigations of BaCl2:Eu2+ nanophosphor using electron paramagnetic resonance, structural analysis and thermoluminescence
Authors: Secu, CE; Rostas, AM

Published: JAN 30 2020, DOI: 10.1016/j.jallcom.2019.152400

Abstract: Structural analysis of the Eu2+-doped BaCl2 nanocrystals and the doping process was monitored and characterized via electron paramagnetic resonance spectroscopy. Structural analysis has shown a slight distortion of the cell which is reflected in the low value of microstrain and the Eu2+-doping effect is limited to the first order chlorine ions neighbors of Ba2+. Electron paramagnetic resonance measurements have indicated the presence of the Eu2+-dopant ions in the BaCl2 host matrix with a solubility limit of about 2%. From the spectra simulation, the isotropic g-value g(iso) = 1.9951(7), the isotropic hyperfine coupling constant A(iso)= 42.4 MHz and the high-order zero-field splitting parameters from the crystal field B-2(0) = 21 MHz and B-2(2)= -493 MHz were obtained. During X-ray irradiation, defects are produced and stabilized by the Eu2+ dopant ions. The single dominant thermoluminescence peak at 132 degrees C (activation energy E = 1.1 eV) was assigned to the recombination of the F(Cl)-center with Eu2+ related hole centers. (C) 2019 Elsevier B.V. All rights reserved.
18. Magnetic properties and thermal stability of polyvinylidene fluoride-Fe2O3 nanocomposites
Authors: Kuncser, V; Chipara, D; Martirosyan, KS; Schinteie, GA; Ibrahim, E; Chipara, M

Published: JAN 28 2020, DOI: 10.1557/jmr.2019.375

Abstract: Nanocomposites of polyvinylidene fluoride loaded with various amounts of gamma-Fe2O nanoparticles, with an average size ranging between 20 and 40 nm, have been obtained by melt mixing and investigated using various experimental techniques [Superconducting Quantum Interference Device, Mossbauer, and Thermogravimetric Analysis]. Magnetic and Mossbauer measurements confirmed the presence of maghemite and a trace of a paramagnetic iron compound. Magnetic data are consistent with a blocking temperature close to room temperature (RT), showing a decrease in the coercive field as the temperature is increased. A weak exchange bias was noticed in all nanocomposites investigated at all temperatures and tentatively ascribed to surface spin disorder. The temperature dependence of the coercive field obeys the Kneller law. The nanocomposites exhibit superparamagnetic behavior near RT. Most magnetic measurements have been performed below the blocking temperature, revealing thus a complex behavior. The dependence of the mass loss derivative versus temperature, as obtained by thermogravimetric analysis, exhibits a single peak due to the thermal degradation of the polymeric matrix. A weak increase in the thermal stability of the polymeric matrix upon loading with maghemite is reported.
19. HRTEM analysis of the high-temperature phases of the newly developed high-temperature Ni-base superalloy VDM 780 Premium
Authors: Ghica, C; Solis, C; Munke, J; Stark, A; Gehrmann, B; Bergner, M; Rosler, J; Gilles, R

Published: JAN 25 2020, DOI: 10.1016/j.jallcom.2019.152157

Abstract: VDM 780 Premium is a recently developed Ni-based superalloy designed for working at high service temperatures (above 650 degrees C) while keeping the good workability of alloy 718. VDM 780 Premium is based on the austenitic matrix (gamma phase) strengthened by intermetallic Ni3Al-like precipitates (gamma' phase, fcc L1(2) structure). Other co-precipitates may be formed in function of the applied heat treatment, such as Ni3Nb-based (delta phase, orthorhombic DOa structure) or Ni3Ti-based (eta phase, hexagonal DO24 structure) precipitates. The amount as well as the size and morphology of the different precipitates depend on the heat treatments performed on the alloy, playing an important role in improving the creep properties or the behavior during forging and recrystallization. This work contains a complex study using various techniques of analytical electron microscopy and synchrotron diffraction intended to clarify the structure of the high-temperature phase formed in the newly developed VDM 780 Premium alloy. The atomic structure of the high-temperature plate-like precipitates formed in VDM 780 Premium after two different thermal treatments has been investigated in relation with the surrounding matrix lattice, proving the stacked delta/eta structure of the precipitates. (C) 2019 Published by Elsevier B.V.
20. Synthesis and characterization of antibacterial drug loaded beta-tricalcium phosphate powders for bone engineering applications
Authors: Topsakal, A; Ekren, N; Kilic, O; Oktar, FN; Mahirogullari, M; Ozkan, O; Sasmazel, HT; Turk, M; Bogdan, IM; Stan, GE; Gunduz, O

Published: JAN 21 2020, DOI: 10.1007/s10856-019-6356-1

Abstract: Powders of beta-tricalcium phosphate [beta-TCP, beta-Ca-3(PO4)(2)] and composite powders of beta-TCP and polyvinyl alcohol (PVA) were synthesized by using wet precipitation methods. First, the conditions for the preparation of single phase beta-TCP have been delineated. In the co-precipitation procedure, calcium nitrate and diammonium hydrogen phosphate were used as calcium and phosphorous precursors, respectively. The pH of the system was varied in the range 7-11 by adding designed amounts of ammonia solution. The filtered cakes were desiccated at 80 degrees C and subsequently calcined at different temperatures in the range between 700-1100 degrees C. Later on, rifampicin form II was used to produce drug-loaded beta-TCP and PVA/beta-TCP powders. All the synthesized materials have been characterized from morphological (by scanning electron microscopy) and structural-chemical (by X-ray diffraction and Fourier transform infrared spectroscopy) point of view. The drug loading capacity of the selected pure beta-TCP powder has been assessed. The biological performance (cytocompatibility in fibroblast cell culture and antibacterial efficacy against Escherichia coli and Staphylococcus aureus) has been tested with promising results. Application perspectives of the designed drug-bioceramic-polymer blends are advanced and discussed. [GRAPHICS] .

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