National Institute Of Materials Physics - Romania

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41. Animal Origin Bioactive Hydroxyapatite Thin Films Synthesized by RF-Magnetron Sputtering on 3D Printed Cranial Implants
Authors: Chioibasu, D; Duta, L; Popescu-Pelin, G; Popa, N; Milodin, N; Iosub, S; Balescu, LM; Galca, AC; Popa, AC; Oktar, FN; Stan, GE; Popescu, AC

Published: DEC 2019, DOI: 10.3390/met9121332

Abstract: Ti6Al4V cranial prostheses in the form of patterned meshes were 3D printed by selective laser melting in an argon environment; using a CO2 laser source and micron-sized Ti6Al4V powder as the starting material. The size and shape of prostheses were chosen based on actual computer tomography images of patient skull fractures supplied in the framework of a collaboration with a neurosurgery clinic. After optimizations of scanning speed and laser parameters, the printed material was defect-free (as shown by metallographic analyses) and chemically homogeneous, without elemental segregation or depletion. The prostheses were coated by radio-frequency magnetron sputtering (RF-MS) with a bioactive thin layer of hydroxyapatite using a bioceramic powder derived from biogenic resources (Bio-HA). Initially amorphous, the films were converted to fully-crystalline form by applying a post-deposition thermal-treatment at 500 degrees C/1 h in air. The X-ray diffraction structural investigations indicated the phase purity of the deposited films composed solely of a hexagonal hydroxyapatite-like compound. On the other hand, the Fourier transform infrared spectroscopic investigations revealed that the biological carbonatation of the bone mineral phase was well-replicated in the case of crystallized Bio-HA RF-MS implant coatings. The in vitro acellular assays, performed in both the fully inorganic Kokubo's simulated body fluid and the biomimetic organic-inorganic McCoy's 5A cell culture medium up to 21 days, emphasized both the good resistance to degradation and the biomineralization capacity of the films. Further in vitro tests conducted in SaOs-2 osteoblast-like cells showed a positive proliferation rate on the Bio-HA RF-MS coating along with a good adhesion developed on the biomaterial surface by elongated membrane protrusions.
42. Superconducting MgB2 textured bulk obtained by ex situ spark plasma sintering from green compacts processed by slip casting under a 12T magnetic field
Authors: Grigoroscuta, MA; Sandu, V; Kuncser, A; Pasuk, I; Aldica, G; Suzuki, TS; Vasylkiv, O; Badica, P

Published: DEC 2019, DOI: 10.1088/1361-6668/ab4620

Abstract: MgB2 green bodies were prepared by magnetic field slip casting in ethyl alcohol with added polyethyleneimine dispersing agent under a high magnetic field, mu H-0(0) = 12 T. Samples were further processed by spark plasma sintering (SPS) and characterized for superconducting properties. Slip casting provides texturing of MgB2 (the degree of c-axis orientation is approximately 3.5%), which is further increased significantly (to about 21%) in the SPSed sample. The critical current density (J(c)) displays anisotropy relative to the orientation of the measuring magnetic field. Specific features of J(c)(H, T) and of the pinning force extracted from magnetic measurements with the field parallel and perpendicular to H-0 are discussed.
43. Modelling J?V hysteresis in perovskite solar cells induced by voltage poling
Authors: Anghel, DV; Nemnes, GA; Pintilie, I; Manolescu, A

Published: DEC 2019, DOI: 10.1088/1402-4896/ab347d

Abstract: We present an extension of the dynamic electrical model, which enable us to explain some important features of the perovskite solar cells (PSC), like the shape of the hysteresis and the appearance of the ?bump? in the so called reverse scan, without requiring any additional assumptions. We give analytical expressions in terms of the Lambert?s function W for the open circuit voltage, the stationary current, and the instantaneous current, which can be written also in terms of elementary functions for the most part of the ranges of the physical parameters. The initial polarization of the cell, modeled as the charging of a capacitor with voltage dependent capacitance, is consistently determined in the model, from the initial stationary conditions. This is inline with a previously observed sharp increase of the PSC capacitance beyond the open-circuit voltage. Besides the known features, we obtain characteristics that were not yet analyzed experimentally, like the change of the bump from the reverse scan branch of the J?V characteristic to the forward scan, with the increase of the poling voltage (or the increase of the PSC capacitance).
44. Raman investigations on gamma irradiated iPP-VGCNF nanocomposites: The polymer's tale
Authors: Chipara, DM; Secu, C; Lozano, K; Secu, M; Chipara, M

Published: DEC 2019, DOI: 10.1016/j.surfin.2019.100351

Abstract: Raman investigations on nanocomposites obtained by loading various amounts of vapor grown carbon nanofibers within an isotactic polypropylene matrix, and gamma irradiated in air, at various integral doses ranging between 0 and 27 kGy, are reported. The analysis is focused on the polymer's answers as revealed by Raman spectroscopy and investigate in detail the effect of ionizing radiation on the position of the Raman line originating from the polymer. The as-obtained data are correlated to the elastic features of the nanocomposites. A competition between gamma irradiation and loading by carbon nanofiber, resulting in the stretching of the polymeric matrix and revealed as a displacement of Raman lines towards smaller wavenumber is reported. It is concluded that side groups (CH3) are less affected by the loading with carbon nanofibers,
45. Antireflective coatings with high damage threshold prepared by laser ablation
Authors: Filipescu, M; Palla-Papavlu, A; Bercea, A; Rusen, L; Cernaianu, MO; Ion, V; Calugar, A; Nistor, LC; Dinescu, M

Published: DEC 2019, DOI: 10.1007/s00339-019-3110-y

Abstract: Latest developments in the field of high power ultra-short pulse lasers have led to intensive studies dedicated to the fabrication possibility of new antireflective coatings which exhibit high damage threshold. Therefore, this study is focused on the deposition and characterization of metal oxide heterostructures followed by laser-induced damage threshold tests which evidence their application in high power laser optics. Al2O3, SiO2, and HfO2 layers are combined to obtain different heterostructures, i.e. HfO2/Al2O3/HfO2/Al2O3/HfO2 and HfO2/SiO2/HfO2/SiO2/HfO2. The metal oxide heterostructures are deposited in a controllable oxygen atmosphere, either at room temperature or high temperatures (600 degrees C) by pulsed laser deposition (PLD). The morphological, structural and optical properties of the as-deposited heterostructures are first investigated. Atomic force microscopy and spectroscopic ellipsometry investigations reveal a lower roughness of the heterostructures based on HfO2/Al2O3 layers grown at 600 degrees C as compared to those grown at room temperature. Furthermore, following the laser-induced damage threshold (LIDT) tests carried out with a Ti-Sapphire laser, higher LIDT values are obtained for the HfO2/Al2O3-based heterostructures than for the HfO2/SiO2-based heterostructures. The ability to control the morphological and structural properties of the antireflective coatings by modifying the deposition parameters of the metal oxide heterostructures demonstrates that PLD is a suitable technique for the manufacturing of antireflective coatings for high power ultra-short laser systems.
46. Nonvolatile resistance switching in monolayer transition metal dichalcogenides: an explanation
Authors: Mihai, C; Velea, A; Sava, F

Published: DEC 2019, DOI: 10.1088/1361-6641/ab4b85

Abstract: Monolayers of transition metal (from the group VI B) dichalcogenides (MoS2, MoSe2, WS2 and WSe2) show nonvolatile resistance switching: a transition from a high to a low resistance state. Here we propose two explanations for this behaviour. The first one is that the transition metals swaps from a trigonal prismatic to an octahedral coordination (due to a high applied electric field and pressure) and thus the monolayer switches from a semiconducting to a metallic phase. The second one is a two-step process where the high electric field and pressure break the M-X bonds and the transition metal atoms become firstly tetrahedrally coordinated and afterwards square-planar coordinated. Thus, all transition metal and chalcogen atoms are in the same plane, and the transition metal atoms are in contact with the atoms of the top and bottom electrodes.
47. Core-shell nanowire arrays based on ZnO and CuxO for water stable photocatalysts
Authors: Florica, C; Costas, A; Preda, N; Beregoi, M; Kuncser, A; Apostol, N; Popa, C; Socol, G; Diculescu, V; Enculescu, I

Published: NOV 21 2019, DOI: 10.1038/s41598-019-53873-0

Abstract: Staggered gap radial heterojunctions based on ZnO-CuxO core-shell nanowires are used as water stable photocatalysts to harvest solar energy for pollutants removal. ZnO nanowires with a wurtzite crystalline structure and a band gap of approximately 3.3 eV are obtained by thermal oxidation in air. These are covered with an amorphous CuxO layer having a band gap of 1.74 eV and subsequently form core-shell heterojunctions. The electrical characterization of the ZnO pristine and ZnO-CuxO core-shell nanowires emphasizes the charge transfer phenomena at the junction and at the interface between the nanowires and water based solutions. The methylene blue degradation mechanism is discussed taking into consideration the dissolution of ZnO in water based solutions for ZnO nanowires and ZnO-CuxO core-shell nanowires with different shell thicknesses. An optimum thickness of the CuxO layer is used to obtain water stable photocatalysts, where the ZnO-CuxO radial heterojunction enhances the separation and transport of the photogenerated charge carriers when irradiating with UV-light, leading to swift pollutant degradation.
48. Molecular dynamics in bulk and surface species of cyanophenyl alkyl benzoates with 2, 3 and 7 carbon atoms in the alkyl chain: comparison in the whole homologous series
Authors: Frunza, S; Ganea, CP; Zgura, I; Frunza, L; Schonhals, A

Published: , DOI: 10.1080/02678292.2019.1687768

Abstract: Molecular mobility of cyanophenyl alkylbenzoates (CPnBs) (n = 2, 3, 7 - number of carbon atoms in the alkyl chain) in the bulk and in composites with aerosil A380 is investigated by broadband dielectric spectroscopy, while thermal analysis and infrared spectroscopy were applied to characterise the molecular species. The work completes preliminary results obtained for the members with n = 4 ... 6. An interaction by hydrogen bonding, between aerosil surface - OH groups and - CN or ester groups of the CPnB molecules takes place. It slows down the relaxation process as observed for related composites in comparison to the pure materials. The existence of two types of bonding might be the reason that Vogel temperature for the relaxation process in the surface layer does not show the odd-even effect. Temperature dependence of the relaxation rates for composites shows a crossover behaviour from a high to a low temperature regime. Moreover, the temperature dependence of the dielectric strength is unusual. As the loading degree is similar, comparison of the dielectric, spectroscopic and thermal data obtained here and with the results obtained for the composites with n = 4 ... 6 can be directly done. Increasing the number of the members of the homologous series confirms and hardens the preliminary conclusions.
49. Structure and low field magnetic properties in phosphate-tellurite glasses
Authors: Polosan, S

Published: NOV 15 2019, DOI: 10.1016/j.jnoncryso1.2019.119651

Abstract: Phosphate-tellurite glasses exhibit magnetic properties, due to the presence of the small metallic Te colloids which were revealed in low field magnetic circular dichroism. These metallic colloids induce the red coloring of these glasses together with the absorbance in the visible region. The temperature dependence of the absorption spectrurn and the A-term in magnetic circular dichroism are specific for Te metallic nanoparticles, which results during the melting procedure over 1000 degrees C due to the conversion of Te4+ in Te-0 atoms. The X-ray photoelectron spectroscopy supports this fact due to the presence of small peaks as satellites in the region of Te 3d core-level spectrum. Quantification of these satellites compared with Te 3d(3/2) and 3d(5/2) peaks suggests a 14% concentration of Te metallic nanoparticles in these phosphate-tellurite glasses. The presence of metallic particles induces the crystallization effects of Te micrograins upon thermal treatments at higher temperatures.
50. Synthesis and characterization of biocompatible polymer-ceramic film structures as favorable interface in guided bone regeneration
Authors: Dascalu, CA; Maidaniuc, A; Pandele, AM; Voicu, SI; Machedon-Pisu, T; Stan, GE; Cimpean, A; Mitran, V; Antoniac, IV; Miculescu, F

Published: NOV 15 2019, DOI: 10.1016/j.apsusc.2019.07.098

Abstract: The bone regeneration field targeted lately the development of new products based on precursors of natural origin. This study aimed to obtain the optimal design of polymer-ceramic composites for guided bone regeneration application from cellulose acetate (CA) and hydroxyapatite (HA) by varying three relevant parameters: the amount of HA powder added to the CA matrix (in the 20-40 wt% range), the HA particles size (max. 20 mu m vs. max. 40 mu m) and the homogenization time required for HA powder dispersion in the CA matrix (1 min vs. 4 min). For polymer-ceramic film structures preparation, the phase inversion by immersion in water method was used. This involved the deposition of composite solution (i.e. CA with 20-40 wt% HA) on a glass support, followed by sizing it at a thickness of 0.2 mm. The obtained film structures were investigated in terms of morphocompositional and structural properties. The surface features evaluation was achieved by surface wettability, roughness, water permeation, protein retention and in vitro evaluation of MC3T3-E1 morphology and viability. Further, ceramic particle distribution throughout samples volume was provided by computed tomography methods. These investigations targeted the validation of the prepared composite film structures as viable solutions for guided bone regeneration.

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