National Institute Of Materials Physics - Romania

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21. Glutathione-capped gold nanoclusters as near-infrared-emitting efficient contrast agents for confocal fluorescence imaging of tissue-mimicking phantoms
Authors: Hada, AM; Craciun, AM; Focsan, M; Vulpoi, A; Borcan, EL; Astilean, S

Published: SEP 2022, MICROCHIMICA ACTA, 189, 337, DOI: 10.1007/s00604-022-05440-0

An innovative research has been conducted focused on demonstrating the ability of novel dual-emissive glutathione-stabilized gold nanoclusters (GSH-AuNCs) to perform bright near-infrared (NIR)-emitting contrast agents inside tissue-mimicking agarose-phantoms via two complementary confocal fluorescence imaging techniques. First, using a new and fast microwave-assisted approach, we synthesized photostable dual-emitting GSH-AuNCs with an average size of 3.2 +/- 0.4 nm and NIR emission quantum yield of 9.9%. Steady-state fluorescence measurements coupled with fluorescence lifetime imaging microscopy (FLIM) assays performed on lyophilized GSH-AuNCs revealed that the obtained GSH-AuNCs exhibit PL emissions at 610 nm (red PL) and, respectively, 800 nm (NIR PL) in both solution and powder solid-state. Time-resolved fluorescence measurements showed that the two PL components are characterized by average lifetimes of 407 ns (red PL) and 1821 ns (NIR PL), respectively. Additionally, due to a partial overlap between the red PL and the absorption of the NIR PL, an energy transfer between the two coexisting emissive centers was discovered and confirmed via steady-state and time-resolved fluorescence measurements. Furthermore, the FLIM analysis performed on powder GSH-AuNCs under 640 nm, an excitation more suitable for bioimaging applications, revealed a homogeneous and photostable NIR PL signal from GSH-AuNCs. Finally, the ability of GSH-AuNCs to operate as reliable NIR-emitting contrast agents inside tissue-mimicking agarose-phantoms was demonstrated here for the first time via complementary FLIM and re-scan confocal fluorescence imaging techniques. In consequence, GSH-AuNCs show great promise for future in vivo imaging applications via confocal fluorescence microscopy.
22. Magnetic Nanoparticles: Current Advances in Nanomedicine, Drug Delivery and MRI
Authors: Comanescu, C

Published: SEP 2022, CHEMISTRY-SWITZERLAND, 4, DOI: 10.3390/chemistry4030063

Magnetic nanoparticles (MNPs) have evolved tremendously during recent years, in part due to the rapid expansion of nanotechnology and to their active magnetic core with a high surface-to-volume ratio, while their surface functionalization opened the door to a plethora of drug, gene and bioactive molecule immobilization. Taming the high reactivity of the magnetic core was achieved by various functionalization techniques, producing MNPs tailored for the diagnosis and treatment of cardiovascular or neurological disease, tumors and cancer. Superparamagnetic iron oxide nanoparticles (SPIONs) are established at the core of drug-delivery systems and could act as efficient agents for MFH (magnetic fluid hyperthermia). Depending on the functionalization molecule and intrinsic morphological features, MNPs now cover a broad scope which the current review aims to overview. Considering the exponential expansion of the field, the current review will be limited to roughly the past three years.
23. Pseudo-dielectric function spectra of the near surface layer of GaAs implanted with various fluence of Xe+ ions
Authors: Tuan, PL; Kulik, M; Phuc, TV; Madadzada, AI; Zelenyak, TY; Turek, M; Zuk, J; Mita, C; Stanculescu, A; Doroshkevich, AS; Jasinska, B; Khiem, LH; Anh, NN; My, NTB

Published: AUG 31 2022, THIN SOLID FILMS, 756, 139376, DOI: 10.1016/j.tsf.2022.139376

Monocrystalline (100) semi-insulating gallium arsenide (GaAs) samples were irradiated with a 250-keV Xe+ ion beam at room temperature. To investigate the effect of ion irradiation on GaAs samples, the ion fluence was varied from 1 x 1012 to 3 x 1016 ions/cm2. The spectroscopic ellipsometry (SE) method and the Rutherford backscattering spectrometry (RBS) with nuclear reaction (NR) method were used to determine the properties of the virgin and implanted samples. The SE approach reveals that the pseudo-dielectric function of implanted GaAs samples varies with ion fluence. The RBS approach, which exposes the depth-profile of As, Ga, and Xe in the implanted samples, allows us to correlate changes in the pseudo-dielectric function with structural modifications caused by the ion irradiation. The NR approach points out the existence of an oxygen-enriched layer on the surface of implanted GaAs samples. Lastly, the optical study involving the Cauchy and Urbach dispersion model measures the refractive index n and extinction coefficient k of the native oxide layer on the surface of GaAs samples.
24. Ferroelectricity modulates polaronic coupling at multiferroic interfaces
Authors: Husanu, MA; Popescu, DG; Bisti, F; Hrib, LM; Filip, LD; Pasuk, I; Negrea, R; Istrate, MC; Lev, L; Schmitt, T; Pintilie, L; Mishchenko, A; Teodorescu, CM; Strocov, VN

Published: AUG 15 2022, COMMUNICATIONS PHYSICS, 5, 209, DOI: 10.1038/s42005-022-00983-3

A deeper understanding of the coupling at the interface of multiferroics heterostructures is being achieved by the use of synchrotron radiation techniques. Here, the authors use k-resolved soft X-ray photoemission spectroscopy and first principles calculations to investigate the band structure of several multiferroic heterostructures, isolating the distinct signature of the interface. Physics of the multiferroic interfaces is currently understood mostly within a phenomenological framework based on screening of the polarization field and depolarizing charges. Additional effects still unexplored are the band dependence of the interfacial charge modulation and the associated changes of the electron-phonon interaction, coupling the charge and lattice degrees of freedom. Here, multiferroic heterostructures of the colossal-magnetoresistance manganite La1-xSrxMnO3 buried under ferroelectric BaTiO3 and PbZrxTi1-xO3 are investigated using soft-X-ray angle-resolved photoemission. The experimental band dispersions from the buried La1-xSrxMnO3 identify coexisting two-dimensional hole and three-dimensional electron charge carriers. The ferroelectric polarization modulates their charge density, affecting the coupling of the 2D holes and 3D electrons with the lattice which forms large Frohlich polarons inherently reducing mobility of the charge carriers. Our k-resolved results on the orbital occupancy, band filling and electron-lattice interaction in multiferroic oxide heterostructures modulated by the ferroelectric polarization disclose most fundamental physics of these systems needed for further progress of beyond-CMOS ferro-functional electronics.
25. Investigating the effect of N-doping on carbon quantum dots structure, optical properties and metal ion screening
Authors: Nguyen, KG; Baragau, IA; Gromicova, R; Nicolaev, A; Thomson, SAJ; Rennie, A; Power, NP; Sajjad, MT; Kellici, S

Published: AUG 15 2022, SCIENTIFIC REPORTS, 12, 13806, DOI: 10.1038/s41598-022-16893-x

Carbon quantum dots (CQDs) derived from biomass, a suggested green approach for nanomaterial synthesis, often possess poor optical properties and have low photoluminescence quantum yield (PLQY). This study employed an environmentally friendly, cost-effective, continuous hydrothermal flow synthesis (CHFS) process to synthesise efficient nitrogen-doped carbon quantum dots (N-CQDs) from biomass precursors (glucose in the presence of ammonia). The concentrations of ammonia, as nitrogen dopant precursor, were varied to optimise the optical properties of CQDs. Optimised N-CQDs showed significant enhancement in fluorescence emission properties with a PLQY of 9.6% compared to pure glucose derived-CQDs (g-CQDs) without nitrogen doping which have PLQY of less than 1%. With stability over a pH range of pH 2 to pH 11, the N-CQDs showed excellent sensitivity as a nano-sensor for the highly toxic highly-pollutant chromium (VI), where efficient photoluminescence (PL) quenching was observed. The optimised nitrogen-doping process demonstrated effective and efficient tuning of the overall electronic structure of the N-CQDs resulting in enhanced optical properties and performance as a nano-sensor.
26. Effect of disubstitution pattern of the terminal alkyl chains on the mesophase of liquid crystals based on lanthanide(III) complexes: A study of the thermal, emission and dielectric behavior
Authors: Ilinca, TA; Chiriac, LF; Ilis, M; Manaila-Maximean, D; Ganea, PC; Pasuk, I; Circu, V

Published: AUG 15 2022, JOURNAL OF MOLECULAR LIQUIDS, 360, 119425, DOI: 10.1016/j.molliq.2022.119425

In the present work, new luminescent lanthanide complexes with extended mesomorphic range were prepared by coordination to lanthanide ions (Eu3+, Sm3+ and Tb3+) of the new 4-pyridone based organic ligands (L) with 3,4-(7-n) and 3,5-di(alkyloxy)benzyl (8-n) mesogenic groups and variable length (n = 12 or 14 carbon atoms) onto the benzyl unit. The cumulative results of the elemental analyses as well as the H-1, C-13 NMR and IR spectroscopies support the structure of the organic derivatives and their lanthanide complexes [LnL(3)(NO3)(3)] (9-n/Ln and 10-n/Ln) described in this work. These complexes show characteristic lanthanide solid state emission, both at room and elevated temperatures corresponding to crystalline, glassy or liquid crystal states. The long range SmA phases displayed by all complexes were supported by a combination of characterization methods, including: differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and variable-temperature powder X-ray diffraction (XRD). This work shows that the number, substitution pattern and length of flexible alkoxy chains are important parameters to control the phase-transition characteristics of the lanthanide complexes. Complexes with 3,4-disubstituted pattern (9-n/Ln) show higher clearing temperatures (nearly 60 degrees C for Eu3+, 70 degrees C for Sm3+ and 85 degrees C for Tb3+ complexes) compared to their counterparts with 3,5-disubstituted pattern (10-n/Ln). Moreover, complexes 9-n/Ln crystallize when cooling their LC phase while complexes 10-n/Ln are stable in glassy state at room temperature as a consequence of the different close interdigitated molecular packing evidenced by XRD measurements. Dielectric spectroscopy was employed to detect the changes of order degree specific to each phases (crystalline, LC or isotropic). The variation of dielectric constant and the electrical conductivity versus temperature shows three transition intervals for selected complexes 10-14/Sm and 10-14/Tb, which delimit the main intervals: 45-60 degrees C, 90-110 degrees C; 140-160 degrees C corresponding to the Cr-1-Cr-2, Cr-2 - SmA and SmA-Iso transitions, and agree very well with the DSC results. The change of characteristic time, obtained by Havriliak-Negami fit function, with temperature also provides a very good correlation with the DSC and POM results. (C) 2022 Elsevier B.V. All rights reserved.
27. Molecular dynamics of alkyl benzoate liquid crystals in the bulk state and in the surface layer of their composites with oxide nanopowders
Authors: Frunza, L; Zgura, I; Ganea, CP; Schonhals, A

Published: AUG 1 2022, JOURNAL OF MOLECULAR LIQUIDS, 359, 119374, DOI: 10.1016/j.molliq.2022.119374

This paper presents the results concerning monotropic nematic liquid crystals 4-pentylphenyl 40-alkyl benzoate (5PnB) (n = 3 or 5 carbon atoms in the alkyl chain). Their mesophase properties were supported by images of the polarized optical microscopy. Molecular dynamics in the bulk samples or in the composites prepared with aerosil A380 was investigated by broadband dielectric spectroscopy in a large temperature range, appropriately chosen. Thermo gravimetric and infrared investigations were additionally performed. The data were compared with those of structurally related nematics like cyanophenyl pentyl benzoates, which have a cyan group instead of the pentyl chain. The dielectric spectra of the bulk 3P5B and 5P5B demonstrate a dielectric behavior with several relaxation processes as expected for nematic liquid crystals. The temperature dependence of the relaxation rates (and of the dielectric strength) seems to have two distinguished regimes. Thus, in the isotropic state, at higher temperatures the data obey the Vogel-Fulcher-Tammann law, whereas an Arrhenius law is fitted at lower temperature, in a close similarity to the behavior of a constrained dynamic glass transition. Samples with a high density of silica (larger than 7 g aerosil/1 g of 5PnB) were prepared to observe a thin layer adsorbed on the particle surface; it was estimated that almost each guest 5PnB molecule interacts with the aerosil surface. For the composites only one main relaxation process is observed at frequencies much lower than those for the corresponding bulk, which was assigned to the dynamics of the molecules in the surface layer. Infrared spectroscopy shows that these molecules interact with the surface by the ester carbonyl group leading to the monolayer self-assembly at liquid-solid interface. We note once more the importance of the functional unit(s) for the interaction with the hydroxyl groups on the aerosil surface. (c) 2022 Elsevier B.V. All rights reserved.
28. Raman Spectroscopy as Spectral Tool for Assessing the Degree of Conversion after Curing of Two Resin-Based Materials Used in Restorative Dentistry
Authors: Gatin, E; Iordache, SM; Matei, E; Luculescu, CR; Iordache, AM; Grigorescu, CEA; Ilici, RR

Published: AUG 2022, DIAGNOSTICS, 12, 1993, DOI: 10.3390/diagnostics12081993

(1) Background: The treatment of dental cavities and restoration of tooth shape requires specialized materials with specific clinical properties, including being easy to model, light-cured, having a natural color, reduced shrinkage, a hardness similar to hydroxyapatite, and no leakage. The dimensional stability of resin composite materials is affected by polymerization shrinkage, degree of conversion (number of pi carbon bonds converted into sigma ones), thermal contraction and expansion, and interactions with an aqueous environment. (2) Methods: The materials used in our investigation were two composite resins with similar polymer matrices, but different filler (micro/nano filler). To evaluate the properties of samples, we employed the pycnometer technique (pycnometer from Paul Marienfeld Gmbh, Lauda-Konigshofen, Germany), RAMAN spectroscopy technique (MiniRam Equipment from B&W Tek Inc., Plainsboro Township, NJ, USA; 785 nm laser source), SEM and EDX (FEI Inspect S.). (3) Results: The size of the filler plays an important role in the polymerization: for the pycnometric results, the larger particle filler (Sample 1) seems to undergo a rapid polymerization during the 45 s curing, while the nanoparticle filer (Sample 2) needs additional curing time to fully polymerize. This is related to a much larger porosity, as proved by SEM images. The lower degree of conversion, as obtained by Raman spectroscopy, in the same geometry means that the same volume is probed for both samples, but Sample 1 is more porous, which means less amount of polymer is probed for Sample 1. (4) Conclusions: For the two composites, we obtained a degree of conversion of 59% for Sample 1 and 93% for Sample 2, after 45 s of curing.
29. Dielectric, piezoelectric and magnetic behavior of CoFe2O4/BNT-BT0.08 monolayer thin films composites
Authors: Cernea, M; Radu, R; Craciun, F; Gavrila, R; Surdu, VA; Trusca, R; Mihalache, V

Published: AUG 2022, MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 282, 115770, DOI: 10.1016/j.mseb.2022.115770

We report in this paper on the monolayer composites thin films that have the magnetic spinel CoFe2O4 and the piezoelectric perovskite BNT-BT0.08 as constituent phases. Composite thin films of CoFe2O4 and BNT-BT0.08, with molar ratios of 0.5:1, 1:1 and 1.5:1, have been deposited by spin coating method from a sol precursor, mixture type, of CoFe2O4 and BNT-BT0.08. The monolayer thin films, deposited on Si/SiO2/TiO2/Pt substrate, were characterized using selected methods, such as: X-ray diffraction, scanning electron microscopy, atomic force microscopy/piezoelectric force microscopy, dielectric spectroscopy, and vibrating sample magnetometer. X-ray diffraction demonstrated the two phases: cubic CoFe2O4 and rhombohedral BNT-BT0.08. Furthermore, the Si/ SiO2/TiO2/Pt/BNT-BT0.08/CoFe2O4 monolayers show a simultaneous enhancement of both the magnetization and coercivity with the increase of the magnetic phase, accompanied by a decrease of the dielectric constant. The obtained results reveal that the investigated monolayer structures present superior properties compared to those of bilayer composites.
30. Effect of the Cadmium Telluride Deposition Method on the Covering Degree of Electrodes Based on Copper Nanowire Arrays
Authors: Panaitescu, AM; Antohe, I; Locovei, C; Iftimie, S; Antohe, S; Piraux, L; Suchea, MP; Antohe, VA

Published: AUG 2022, APPLIED SCIENCES-BASEL, 12, 7808, DOI: 10.3390/app12157808

In this work, we report the preparation of nanostructured electrodes based on dense arrays of vertically-aligned copper (Cu) nanowires (NWs) to be subsequently covered by cadmium telluride (CdTe) thin films, with great potential to be used within "substrate"-type photovoltaic cells based on A(II)-BVI heterojunctions. In particular, the multi-step preparation protocol presented here involves an electrochemical synthesis procedure within a supported anodic aluminum oxide (AAO) nanoporous template for first generating a homogeneous array of vertically-aligned Cu NWs, which are then further embedded within a compact CdTe thin film. In a second stage, we tested three deposition methods (vacuum thermal evaporation, VTE; radio-frequency magnetron sputtering, RF-MS; and electrochemical deposition, ECD) for use in obtaining CdTe layers potentially able to consistently penetrate the previously prepared Cu NWs array. A comparative analysis was performed to critically evaluate the morphological, optical, and structural properties of the deposited CdTe films. The presented results demonstrate that under optimized processing conditions, the ECD approach could potentially allow the cost-effective fabrication of absorber layer/collecting electrode CdTe/Cu nanostructured interfaces that could improve charge collection mechanisms, which in turn could allow the fabrication of more efficient solar cells based on A(II)-BVI semiconducting compounds.

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