NIMP| Carmen BREAZU, Author at NIMP

Expertize

· Nano-imprint lithography;

· Deposition of organic thin layers: oligomers, polymers, bio-organic compounds on diffrent substrates (including flexible) using different methods (vacuum thermal evaporation, spin-coating, Langmuir-Blodgett);

· Preparation and characterization of organic semiconductors structures;

· Optical and morphological characterization (AFM, SEM).

Publications

1. Organic Heterostructures with Dendrimer Based Mixed Layer for Electronic Applications

Authors: Rasoga, O; Yonkeu, ALD; Breazu, C; Socol, M; Preda, N; Stanculescu, F; Stanculescu, A; Iwuoha, E

Published: SEP 2024, MOLECULES, 29, 4155, DOI: 10.3390/molecules29174155

Recently, much research has focused on the search for new mixed donor-acceptor layers for applications in organic electronics. Organic heterostructures with layers based on the generation 1 poly(propylene thiophenoimine) (G1PPT) dendrimer, N,N '-diisopropylnaphthalene diimide (MNDI), and a combination of the two were prepared and their electrical properties were investigated. Single layers of G1PPT and MNDI and a mixed layer (G1PPT:MNDI) were obtained via spin coating on quartz glass, silicon, and glass/ITO substrates, using chloroform as a solvent. The absorption mechanism was investigated, the degree of disorder was estimated, and the emission properties of the layers were highlighted using spectroscopic methods (UV-Vis transmission and photoluminescence). The effects of the concentration and surface topographical particularities on the properties of the layers were analyzed via atomic force microscopy. All of the heterostructures realized with ITO and Au electrodes showed good conduction, with currents of the order of mA. Additionally, the heterostructure with a mixed layer exhibited asymmetry in the current-voltage curve between forward and reverse polarization in the lower range of the applied voltages, which was more significant at increased concentrations and could be correlated with rectifier diode behavior. Consequently, the mixed-layer generation 1 poly(propylene thiophenoimine) dendrimer with N,N '-diisopropylnaphthalene diimide can be considered promising for electronic applications.

2. MAPLE-Deposited Perylene Diimide Derivative Based Layers for Optoelectronic Applications

Authors: Breazu, C; Girtan, M; Stanculescu, A; Preda, N; Rasoga, O; Costas, A; Catargiu, AM; Socol, G; Stochioiu, A; Popescu-Pelin, G; Iftimie, S; Petre, G; Socol, M

Published: NOV 2024, NANOMATERIALS, 14, 1733, DOI: 10.3390/nano14211733

Nowadays, the development of devices based on organic materials is an interesting research challenge. The performance of such devices is strongly influenced by material selection, material properties, design, and the manufacturing process. Usually, buckminsterfullerene (C60) is employed as electron transport material in organic photovoltaic (OPV) devices due to its high mobility. However, considering its low solubility, there have been many attempts to replace it with more soluble non-fullerene compounds. In this study, bulk heterojunction thin films with various compositions of zinc phthalocyanine (ZnPc), a perylene diimide derivative, or C60 were prepared by matrix-assisted pulsed laser evaporation (MAPLE) technique to assess the influence of C60 replacement on fabricated heterostructure properties. The investigations revealed that the optical features and the electrical parameters of the organic heterostructures based on this perylene diimide derivative used as an organic acceptor were improved. An increase in the JSC value (4.3 x 10-4 A/cm2) was obtained for the structures where the perylene diimide derivative acceptor entirely replaced C60 compared to the JSC value (7.5 x 10-8 A/cm2) for the heterostructure fabricated only with fullerene. These results are encouraging, demonstrating the potential of non-fullerene compounds as electron transport material in OPV devices.

3. Macrocyclic Compounds: Metal Oxide Particles Nanocomposite Thin Films Deposited by MAPLE

Authors: Socol, M; Preda, N; Breazu, C; Costas, A; Rasoga, O; Petre, G; Popescu-Pelin, G; Iftimie, S; Stochioiu, A; Socol, G; Stanculescu, A

Published: MAR 2023, MATERIALS, 16, 2480, DOI: 10.3390/ma16062480

Nanocomposite films based on macrocyclic compounds (zinc phthalocyanine (ZnPc) and 5,10,15,20-tetra(4-pyridyl) 21H,23H-porphyrin (TPyP)) and metal oxide nanoparticles (ZnO or CuO) were deposited by matrix-assisted pulsed laser evaporation (MAPLE). 1,4-dioxane was used as a solvent in the preparation of MAPLE targets that favor the deposition of films with a low roughness, which is a key feature for their integration in structures for optoelectronic applications. The influence of the addition of ZnO nanoparticles (similar to 20 nm in size) or CuO nanoparticles (similar to 5 nm in size) in the ZnPc:TPyP mixture and the impact of the added metal oxide amount on the properties of the obtained composite films were evaluated in comparison to a reference layer based only on an organic blend. Thus, in the case of nanocomposite films, the vibrational fingerprints of both organic compounds were identified in the infrared spectra, their specific strong absorption bands were observed in the UV-Vis spectra, and a quenching of the TPyP emission band was visible in the photoluminescence spectra. The morphological analysis evidenced agglomerated particles on the composite film surface, but their presence has no significant impact on the roughness of the MAPLE deposited layers. The current density-voltage (J-V) characteristics of the structures based on the nanocomposite films deposited by MAPLE revealed the critical role played by the layer composition and component ratio, an improvement in the electrical parameters values being achieved only for the films with a certain type and optimum amount of metal oxide nanoparticles.

4. Effects of Solvent Additive and Micro-Patterned Substrate on the Properties of Thin Films Based on P3HT:PC70BM Blends Deposited by MAPLE

Authors: Socol, M; Preda, N; Breazu, C; Petre, G; Stanculescu, A; Stavarache, I; Popescu-Pelin, G; Stochioiu, A; Socol, G; Iftimie, S; Thanner, C; Rasoga, O

Published: JAN 2023, MATERIALS, 16, 144, DOI: 10.3390/ma16010144

Lately, there is a growing interest in organic photovoltaic (OPV) cells due to the organic materials' properties and compatibility with various types of substrates. However, their efficiencies are low relative to the silicon ones; therefore, other ways (i.e., electrode micron/nanostructuring, synthesis of new organic materials, use of additives) to improve their performances are still being sought. In this context, we studied the behavior of the common organic bulk heterojunction (P3HT:PC70BM) deposited by matrix-assisted pulsed laser evaporation (MAPLE) with/without 0.3% of 1,8-diiodooctane (DIO) additive on flat and micro-patterned ITO substrates. The obtained results showed that in the MAPLE process, a small quantity of additive can modify the morphology of the organic films and decrease their roughness. Besides the use of the additive, the micro-patterning of the electrode leads to a greater increase in the absorption of the studied photovoltaic structures. The inferred values of the filling factors for the measured cells in ambient conditions range from 19% for the photovoltaic structures with no additive and without substrate patterning to 27% for the counterpart structures with patterning and a small quantity of additive.

5. Effect of dopants on the optical properties of benzil crystals

Authors: Stanculescu, F; Socol, M; Rasoga, O; Preda, N; Ionita, I; Petre, G; Breazu, C; Stanculescu, A

Published: APR 15 2022, JOURNAL OF CRYSTAL GROWTH, 584, 126577, DOI: 10.1016/j.jcrysgro.2022.126577

Single-doped [Ag, Na, iodine, naphthalene (Naph), meta-dintrobenzene (m-DNB)] and double-doped, organic-inorganic (Naph + iodine; m-DNB + iodine) benzil (Bz) crystals have been grown from melt in a Bridgman-Stockbarger configuration. All crystals have been grown in the same experimental conditions, temperature variation at the growth interface = 30 K and moving speed of the growth ampoule = 1 mm/h. These conditions have been estimated from the theoretical analysis involving the solution of the classical (conventional) Stefan problem for flat solid-liquid interface in the boundary conditions imposed by our growth system. The effect of doping on the disorder degree, photoluminescence and dielectric constant of the Bz matrix has been investigated. The disorder in the crystals increased with the increase of dopant concentration. The highest disorder was induced by the organic dopant m-DNB, whose molecules does not show an adequate geometrical similarity with Bz molecules. The position of the photoluminescence peak, both at excitation with 335 nm and 435 nm, has not been affected by the presence of dopant(s). All doped samples show Second Harmonic Generation, even those with a significant degree of disorder. The effect of the single and double-doping on the second-order ONL co-efficient was analyzed by comparison with the second-order ONL coefficient of pure Bz crystals. In the case of the double-doping, the highest second-order optical nonlinear coefficient has been evidenced in the Bz crystals simultaneously doped with m-DNB and iodine in the same concentration (1%).

6. Arylenevinylene Oligomer-Based Heterostructures on Flexible AZO Electrodes

Authors: Stanculescu, A; Socol, M; Rasoga, O; Breazu, C; Preda, N; Stanculescu, F; Socol, G; Vacareanu, L; Girtan, M; Doroshkevich, AS

Published: DEC 2021, MATERIALS, 14, DOI: 10.3390/ma14247688

We investigated the optical and electrical properties of flexible single and bi-layer organic heterostructures prepared by vacuum evaporation with a p-type layer of arylenevinylene oligomers, based on carbazole, 3,3 ' bis(N hexylcarbazole)vinylbenzene = L13, or triphenylamine, 1,4 bis [4 (N,N' diphenylamino)phenylvinyl] benzene = L78, and an n-type layer of 5,10,15,20-tetra(4-pyrydil)21H,23H-porphyne = TPyP. Transparent conductor films of Al-doped ZnO (AZO) with high transparency, >90% for wavelengths > 400 nm, and low resistivity, between 6.9 x 10(-4) ohm center dot cm and 23 x 10(-4) ohm center dot cm, were deposited by pulsed laser deposition on flexible substrates of polyethylene terephthalate (PET). The properties of the heterostructures based on oligomers and zinc phthalocyanine (ZnPc) were compared, emphasizing the effect of the surface morphology. The measurements revealed a good absorption in the visible range of the PET/AZO/arylenevinylene oligomer/TPyP heterostructures and a typical injection contact behavior with linear (ZnPc, L78) or non-linear (L13) J-V characteristics in the dark, at voltages < 0.4 V. The heterostructure PET/AZO/L78/TPyP/Al showed a current density of ~1 mA/cm(2) at a voltage of 0.3 V. The correlation between the roughness exponent, evaluated from the height-height correlation function, grain shape, and electrical behavior was analyzed. Consequently, the oligomer based on triphenylamine could be a promising replacement of donor ZnPc in flexible electronic applications.

7. The effect of fullerene layer on the aggregates formation in amyloid beta Langmuir-Blodgett films

Authors: Breazu, C; Rasoga, O; Socol, M; Ganea, P; Tite, T; Matei, E; Stanculescu, F; Stanculescu, A

Published: JAN 30 2021, APPLIED SURFACE SCIENCE, 537, DOI: 10.1016/j.apsusc.2020.147800

The investigation of the effect of carbon nanomaterials and lipids on the aggregation particularities of the amyloid beta/A beta(1-42) layers is important for understanding the generation mechanism of neuronal disorder and how it can be inhibited. Additionally, amyloids are nanomaterials with a wide area of potential applications from nanotechnology to biotechnology. This paper presents a study about the preparation of A beta(1-42) layer by two different methods, Langmuir-Blodgett (L-B) and drop cast (DC), on Si and Si covered by a layer of Buckminster fullerene, C-60, and on the effect of fullerene layer or/and cholesterol (Ch) on the generation of A beta(1-42) secondary structure forms, relevant for specific applications. AFM, SEM FTIR and Raman analysis offered details about the layer surface topography, morphology and particularities of the secondary structure generated in the process of A beta(1-42) molecules aggregation. This study showed that the presence of Ch inhibited the formation of fibrils in A beta(1-42) film deposited by L-B on Si covered by C-60 The structures developed during aggregation were correlated with the topography and roughness of the films. The presence of Ch determined a decrease in roughness for L-B film and increase in roughness for DC film deposited on Si covered by C-60 layer.

8. Silicon Metalens Fabrication from Electron Beam to UV-Nanoimprint Lithography

Authors: Baracu, AM; Avram, MA; Breazu, C; Bunea, MC; Socol, M; Stanculescu, A; Matei, E; Thrane, PCV; Dirdal, CA; Dinescu, A; Rasoga, O

Published: SEP 2021, NANOMATERIALS, 11, DOI: 10.3390/nano11092329

This study presents the design and manufacture of metasurface lenses optimized for focusing light with 1.55 mu m wavelength. The lenses are fabricated on silicon substrates using electron beam lithography, ultraviolet-nanoimprint lithography and cryogenic deep reactive-ion etching techniques. The designed metasurface makes use of the geometrical phase principle and consists of rectangular pillars with target dimensions of height h = 1200 nm, width w = 230 nm, length l = 354 nm and periodicity p = 835 nm. The simulated efficiency of the lens is 60%, while the master lenses obtained by using electron beam lithography are found to have an efficiency of 45%. The lenses subsequently fabricated via nanoimprint are characterized by an efficiency of 6%; the low efficiency is mainly attributed to the rounding of the rectangular nanostructures during the pattern transfer processes from the resist to silicon due to the presence of a thicker residual layer.

9. Nucleobases thin films deposited on nanostructured transparent conductive electrodes for optoelectronic applications

Authors: Breazu, C; Socol, M; Preda, N; Rasoga, O; Costas, A; Socol, G; Petre, G; Stanculescu, A

Published: APR 6 2021, SCIENTIFIC REPORTS, 11, DOI: 10.1038/s41598-021-87181-3

Environmentally-friendly bio-organic materials have become the centre of recent developments in organic electronics, while a suitable interfacial modification is a prerequisite for future applications. In the context of researches on low cost and biodegradable resource for optoelectronics applications, the influence of a 2D nanostructured transparent conductive electrode on the morphological, structural, optical and electrical properties of nucleobases (adenine, guanine, cytosine, thymine and uracil) thin films obtained by thermal evaporation was analysed. The 2D array of nanostructures has been developed in a polymeric layer on glass substrate using a high throughput and low cost technique, UV-Nanoimprint Lithography. The indium tin oxide electrode was grown on both nanostructured and flat substrate and the properties of the heterostructures built on these two types of electrodes were analysed by comparison. We report that the organic-electrode interface modification by nano-patterning affects both the optical (transmission and emission) properties by multiple reflections on the walls of nanostructures and the electrical properties by the effect on the organic/electrode contact area and charge carrier pathway through electrodes. These results encourage the potential application of the nucleobases thin films deposited on nanostructured conductive electrode in green optoelectronic devices.

10. Organic Thin Films Based on DPP-DTT:C60 Blends Deposited by MAPLE

Authors: Socol, M; Preda, N; Breazu, C; Costas, A; Petre, G; Stanculescu, A; Popescu-Pelin, G; Mihailescu, A; Socol, G

Published: DEC 2020, NANOMATERIALS, 10, DOI: 10.3390/nano10122366

The matrix-assisted pulsed laser evaporation (MAPLE) technique was used for depositing thin films based on a recently developed conjugated polymer, poly[2,5-(2-octyldodecyl)-3,6-diketopyrrolopyrrole-alt-5,5-(2,5-di(thien-2-yl)thieno [3,2-b]thiophene)] (DPP-DTT) and fullerene C60 blends. The targets used in the MAPLE process were obtained by freezing chloroform solutions with different DPP-DTT:C60 weight ratios, with the MAPLE deposition being carried at a low laser fluence, varying the number of laser pulses. The structural, morphological, optical, and electrical properties of the DPP-DTT:C60 blend layers deposited by MAPLE were investigated in order to emphasize the influence of the DPP-DTT:C60 weight ratio and the number of laser pulses on these features. The preservation of the chemical structure of both DPP-DTT and C60 during the MAPLE deposition process is confirmed by the presence of their vibrational fingerprints in the FTIR spectra of the organic thin films. The UV-VIS and photoluminescence spectra of the obtained organic layers reveal the absorption bands attributed to DPP-DTT and the emission bands associated with C60, respectively. The morphology of the DPP-DTT:C60 blend films consists of aggregates and fibril-like structures. Regardless the DPP-DTT:C60 weight ratio and the number of laser pulses used during the MAPLE process, the current-voltage characteristics recorded, under illumination, of all structures developed on the MAPLE deposited layers evidenced a photovoltaic cell behavior. The results proved that the MAPLE emerges as a viable technique for depositing thin films based on conjugated polymers featured by a complex structure that can be further used to develop devices for applications in the solar cell area.

11. Hybrid organic-inorganic thin films based on zinc phthalocyanine and zinc oxide deposited by MAPLE

Authors: Socol, M; Preda, N; Costas, A; Breazu, C; Stanculescu, A; Rasoga, O; Popescu-Pelin, G; Mihailescu, A; Socol, G

Published: FEB 15 2020, APPLIED SURFACE SCIENCE, 503, DOI: 10.1016/j.apsusc.2019.144317

Hybrid organic-inorganic thin films based on zinc phthalocyanine (ZnPc) and ZnO nanoparticles were deposited by Matrix Assisted Pulsed Laser Evaporation (MAPLE). Synthesized by a simple wet chemical precipitation method, the ZnO nanoparticles were featured by a hexagonal wurtzite structure, a band-gap value of similar to 3.3 eV and emission bands typical for this semiconductor. The hybrid films containing ZnPc and various amounts of ZnO nanoparticles were evaluated from morphological, compositional, structural, optical and electrical point of view. No chemical decomposition of the organic compound was observed in the FTIR spectra of the deposited layers. The transmittance and photoluminescence spectra recorded on hybrid films disclose the optical signature of both organic (ZnPc) and inorganic (ZnO) components. The electrical measurements carried out under illumination emphasized the importance of the quantity of the inorganic component on the performance parameters of the structures prepared with the hybrid films. Our study provides new insight in the MAPLE deposition of the organic-inorganic hybrid films with potential applications in the photovoltaic cells area.

12. Effect of ITO electrode patterning on the properties of organic heterostructures based on non-fullerene acceptor prepared by MAPLE

Authors: Stanculescu, A; Breazu, C; Socol, M; Rasoga, O; Preda, N; Petre, G; Solonaru, AM; Grigoras, M; Stanculescu, F; Socol, G; Popescu-Pelin, G; Girtan, M

Published: APR 15 2020, APPLIED SURFACE SCIENCE, 509, DOI: 10.1016/j.apsusc.2020.145351

This paper presents some studies on the organic heterostructures realized by Matrix Assisted Pulsed Laser Evaporation in both bi-layer and mixed layer configurations on glass substrates covered by flat or nano-patterned ITO. The donor, a star-shaped arylenevinylene compound, 4,4',4 ''-tris[(4'-diphenylamino) styryl] triphenylamine, and acceptor, a non-fullerene compound, N,N'-bis-(1-dodecyl)perylene-3,4,9,10 tetracarboxylic diimide, were blended in three weight ratios: 1:2, 1:3 and 1:4. A grating of cylindrical pillars with a periodicity of 1.1 mu m has been developed by UV-Nanoimprint Lithography in a polymer layer. The shape of the nanostructures changed to cone trunk by the Pulsed Laser Deposition of ITO on this nanostructured surface. The effect of the nanostructures and composition on the optical and electrical properties of the heterostructures was analyzed. The nano-patterning affected both the UV-Vis transmission and photoluminescence through the multiple reflections inside the cavities and at interfaces and the particularities of the molecular arrangement. The patterning was preserved independently of composition, but the roughness increased with increasing acceptor amount. The I-V characteristics drawn at room temperature in dark revealed an ohmic contact behavior for all heterostructures. The nano-patterning had a similar effect on the current in the heterostructures with mixed layer (1:2) and stacked bi-layer.

13. Pulsed Laser Deposition of Indium Tin Oxide Thin Films on Nanopatterned Glass Substrates

Authors: Socol, M; Preda, N; Rasoga, O; Costas, A; Stanculescu, A; Breazu, C; Gherendi, F; Socol, G

Published: JAN 2019, COATINGS, 9, DOI: 10.3390/coatings9010019

Indium tin oxide (ITO) thin films were grown on nanopatterned glass substrates by the pulsed laser deposition (PLD) technique. The deposition was carried out at 1.2 J/cm(2) laser fluence, low oxygen pressure (1.5 Pa) and on unheated substrate. Arrays of periodic pillars with widths of similar to 350 nm, heights of similar to 250 nm, and separation pitches of similar to 1100 nm were fabricated on glass substrates using UV nanoimprint lithography (UV-NIL), a simple, cost-effective, and high throughput technique used to fabricate nanopatterns on large areas. In order to emphasize the influence of the periodic patterns on the properties of the nanostructured ITO films, this transparent conductive oxide (TCO) was also grown on flat glass substrates. Therefore, the structural, compositional, morphological, optical, and electrical properties of both non-patterned and patterned ITO films were investigated in a comparative manner. The energy dispersive X-ray analysis (EDX) confirms that the ITO films preserve the In2O3:SnO2 weight ratio from the solid ITO target. The SEM and atomic force microscopy (AFM) images prove that the deposited ITO films retain the pattern of the glass substrates. The optical investigations reveal that patterned ITO films present a good optical transmittance. The electrical measurements show that both the non-patterned and patterned ITO films are characterized by a low electrical resistivity (<2.8 x 10(-4)). However, an improvement in the Hall mobility was achieved in the case of the nanopatterned ITO films, evidencing the potential applications of such nanopatterned TCO films obtained by PLD in photovoltaic and light emitting devices.

14. ORGANIC HETEROSTRUCTURES DEPOSITED BY MAPLE ON PATTERNED AZO ELECTRODES

Authors: Socol, M; Preda, N; Breazu, C; Rasoga, O; Stanculescu, A; Popescu-Pelin, G; Gherendi, F; Socol, G; Vacareanu, L

Published: OCT-DEC 2018, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 13, 1053, DOI:

The paper is focused on the investigation of the properties of some organic heterostructures deposited on patterned AZO electrodes. In the first step, 2D patterned arrays based on commercially photoresist were fabricated on glass substrates using nanoimprint litography. Next, on these periodic nanostructures, the transparent AZO layers were deposited by pulsed laser deposition. Further, heterostructures consisting in organic thin films such as 4,7 diphenyl-1,10-phenanthroline (BPhen) (electron transport layer), N,N'-di(1-naftalenil)-N,N'-diafenil-(1,1'-bifenil)-4,4'-diamina (alpha-NPD) (hole transport layer) and arylenevinylene oligomers (3,3-bis (N-hexylcarbazole)vinylbenzene (P13) and 1,4-bis [4-(N,N-diphenylamino)phenylvinyl] benzene (P78)) were obtained by matrix assisted pulsed laser evaporation. The fabricated multilayer organic structures have been investigated from optical (UV-VIS spectroscopy), morphological (scanning electron microscopy and atomic force microscopy) and electrical (I-V characteristics) point of view. An improvement in the current value recorded on the samples prepared on nanostructured electrode was recorded. The results evidence the possibility to integrate these heterostructures in organic electronic devices.

15. Flexible organic heterostructures obtained by MAPLE

Authors: Socol, M; Preda, N; Breazu, C; Stanculescu, A; Costas, A; Stanculescu, F; Girtan, M; Gherendi, F; Popescu-Pelin, G; Socol, G

Published: SEP 2018, APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 124, DOI: 10.1007/s00339-018-1960-3

Organic heterostructures based on zinc phthalocyanine (ZnPc) and perylene tetracarboxylic dianhydride (PTCDA) were deposited by matrix-assisted pulsed laser evaporation (MAPLE) technique on conductive flexible substrate (ITO/PET) in three configurations: ZnPc/PTCDA (stacked layers), ZnPc:PTCDA (blend) and ZnPc/ZnPc:PTCDA/PTCDA. The effect of the configuration on the optical and electrical properties of the obtained heterostructures was investigated. For all heterostructures was observed an improved optical absorption in visible domain. The I-V characteristics recorded under illumination, revealed higher short circuit current (I (SC)) values for the ZnPc:PTCDA and ZnPc/ZnPc:PTCDA/PTCDA structures in comparison with that of the ZnPc/PTCDA structure. The results proved that by MAPLE can be obtained flexible organic heterostructures (in different configurations) with properties adequate for applications in flexible electronics and solar cell fields.

16. On the properties of organic heterostructures prepared with nano-patterned metallic electrode

Authors: Breazu, C; Socol, M; Preda, N; Matei, E; Rasoga, O; Girtan, M; Mallet, R; Stanculescu, F; Stanculescu, A

Published: JUN 15 2018, APPLIED SURFACE SCIENCE, 443, 602, DOI: 10.1016/j.apsusc.2018.02.103

This paper presents a comparative study between the properties of the heterostructures realized with single/multi layer organic (zinc phthalocyanine or/and fullerene) prepared on Si substrate between flat or patterned aluminum (Al) layer metallic electrode and multi layer ZnO/Au/ZnO transparent conductor electrode (TCE). The UV-Nanoimprint Lithography was used for the realization of a 2D array of nanostructures (holes/pillars) characterized by a periodicity of 1.1 mu m and cylindrical shape: diameter = 400 nm and depth/height = 300 nm. The effect of the electrode patterning on the properties of the organic heterostructures was analyzed. For the samples with patterned Al electrode was remarked a slight red shift of the peaks in the reflection spectra determined by an increased interaction between the organic molecules in the delimited region of the patterned holes. The shape of the emission spectra at excitation with UV light showed a narrow intense peak around 500 nm associated with the intense resonance phenomena between the energy of the incident light and the surface plasmons in the patterned Al layer. The TCE followed the morphology of the organic film on which it was deposited. The significant differences between the morphology of the top layer in the heterostructures realized on flat and patterned Al are correlated with the total thickness of the successively deposited layers and with the particularities of the molecular arrangement, leading to the preservation or deleting of patterning. An injection contact behavior was evidence for most heterostructures built on flat and patterned Al. The slight increase in current at an applied bias <1 V in the heterostructure Si/Al/ZnPc/TCE is attributed to the larger interfacial area between the patterned Al electrode and ZnPc layer compared to the interface area between flat Al and ZnPc. A buffer layer of 1,4,5,8-naphthalen-tetracarboxylic dianhydride (NTCDA), sandwiched between the flat metallic electrode and organic film in the heterostructure Si/Al/C60/ZnPc/TCE has determined an increase in the current at low applied voltages. (C) 2018 Elsevier B.V. All rights reserved.

17. Organic heterostructures obtained on ZnO/Ag/ZnO electrode

Authors: Socol, M; Preda, N; Breazu, C; Florica, C; Costas, A; Istrate, CM; Stanculescu, A; Girtan, M; Gherendi, F

Published: AUG 2018, VACUUM, 154, 370, DOI: 10.1016/j.vacuum.2018.05.039

This work is focused on the use of multilayer transparent conductive electrode (TCE) based on ZnO/Ag/ZnO in the fabrication of the organic heterostructures. The ZnO/Ag/ZnO obtained combining sputtering/thermal evaporation/sputtering techniques is featured by a good optical transmittance, a low electrical resistivity and a reduced roughness. All these characteristics recommend it as a viable alternative to indium tin oxide (ITO) for different applications. The organic materials, N,N' - diphenyl N,N' - bis (1 - aphthyl) 1,1' - biphenyl 4,4' - diamine (alpha-NPD), 5,12-Dihydro-5-12-dimethylquino [2,3-b]acridine-7,14dione (DMQA) and 4,7 diphenyl-1,10-phenanthroline (BPhen) were deposited by vacuum thermal evaporation (VTE) method, the properties of the obtained layers being investigated by FTIR, UV-VIS and PL) spectroscopy. The I-V characteristic (recorded in dark) of the organic heterostructure fabricated on the ZnO/Ag/ZriO electrode shows diode behavior, revealing its potential applications in the organic light emitting devices (OLED).

18. Fault-tolerant bandstructure of two-dimensional square photonic crystals with different dielectric rod shapes

Authors: Dragoman, D; Breazu, C

Published: MAY 2017, PHOTONICS AND NANOSTRUCTURES-FUNDAMENTALS AND APPLICATIONS, 24, 17, DOI: 10.1016/j.photonics.2017.02.002

Based on simulations using the plane-wave expansion method, we show that the position of the first bandgap for TM polarized electromagnetic radiation in a high-filling ratio two-dimensional square photonic crystal is practically insensitive to the shape of dielectric rods with the same cross-sectional area. The width of this bandgap depends on the rod shape, but the difference between photonic crystals with circular and regular polygonal rod shapes with a number of edges higher than six can be neglected. For higher-order bandgaps the difference is larger. These results suggest that the fabrication tolerances related to the shape of dielectric rods in a PBG are not as strict as previously thought. (C) 2017 Elsevier B.V. All rights reserved.

19. IZO deposited by PLD on flexible substrate for organic heterostructures

Authors: Socol, M; Preda, N; Stanculescu, A; Breazu, C; Florica, C; Rasoga, O; Stanculescu, F; Socol, G

Published: MAY 2017, APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 123, DOI: 10.1007/s00339-017-0992-4

In: ZnO (IZO) thin films were deposited on flexible plastic substrates by pulsed laser deposition (PLD) method. The obtained layers present adequate optical and electrical properties competitive with those based on indium tin oxide (ITO). The figure of merit (9 X 10(-3) Omega(-1)) calculated for IZO layers demonstrates that high quality coatings can be prepared by this deposition technique. A thermal annealing (150 degrees C for 1 h) or an oxygen plasma etching (6 mbar for 10 min.) were applied to the IZO layers to evaluate the influence of these treatments on the properties of the transparent coatings. Using vacuum evaporation, organic heterostructures based on cooper phthalocyanine (CuPc) and 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA) were deposited on the untreated and treated IZO layers. The optical and electrical properties of the heterostructures were investigated by UVVis, FTIR and current-voltage (I-V) measurements. For the heterostructure fabricated on IZO treated in oxygen plasma, an improvement in the current value with at least one order of magnitude was evidenced in the I-V characteristics recorded in dark conditions. Also, an increase in the current value for the heterostructure deposited on untreated IZO layer can be achieved by adding an organic layer such as tris-8-hydroxyquinoline aluminium (Alq(3)).

20. MAPLE prepared heterostructures with oligoazomethine: Fullerene derivative mixed layer for photovoltaic applications

Authors: Stanculescu, A; Rasoga, O; Socol, M; Vacareanu, L; Grigoras, M; Socol, G; Stanculescu, F; Breazu, C; Matei, E; Preda, N; Girtan, M

Published: SEP 30 2017, APPLIED SURFACE SCIENCE, 417, 195, DOI: 10.1016/j.apsusc.2017.03.053

Mixed layers of azomethine oligomers containing 2,5-diamino-3,4-dicyanothiophene as central unit and triphenylamine (LV5) or carbazol (LV4) at both ends as donor and fullerene derivative, [6,6]-phenylC61 butyric acid butyl ester ([C60] PCB-C4) as acceptor, have been prepared by Matrix Assisted Pulsed Laser Evaporation (MAPLE) on glass/ITO and Si substrates. The effect of weight ratio between donor and acceptor (1: 1; 1: 2) and solvent type (chloroform, dimethylsulphoxide) on the optical (UV-vis transmission/absorption, photoluminescence) and morphological properties of LV4 (LV5): [C60] PCB-C4 mixed layers has been evidenced. Dark and under illumination I-V characteristics of the heterostructures realized with these mixed layers sandwiched between ITO and Al electrodes have revealed a solar cell behavior for the heterostructures prepared with both LV4 and LV5 using chloroform as matrix solvent. The solar cell structure realized with oligomer LV5, glass/ITO/LV5: [C60] PCB-C4 (1: 1) has shown the best parameters. (C) 2017 Elsevier B.V. All rights reserved.

21. Organic heterostructures deposited by MAPLE on AZO substrate

Authors: Socol, M; Preda, N; Stanculescu, A; Breazu, C; Florica, C; Stanculescu, F; Iftimie, S; Girtan, M; Popescu-Pelin, G; Socol, G

Published: SEP 30 2017, APPLIED SURFACE SCIENCE, 417, 203, DOI: 10.1016/j.apsusc.2017.02.260

Organic heterostructures based on poly(3-hexylthiophene) (P3HT) and fullerene (C60) as blends or multilayer were deposited on Al:ZnO (AZO) by Matrix-Assisted Pulsed Laser Evaporation (MAPLE) technique. The AZO layers were obtained by Pulsed Laser Deposition (PLD) on glass substrate, the high quality of the films being reflected by the calculated figure of merit. The organic heterostructures were investigated from morphological, optical and electrical point of view by atomic force microscopy (AFM), UV-vis spectroscopy, photoluminescence (PL) and current-voltage (I-V) measurements, respectively. The increase of the C60 content in the blend heterostructure has as result a high roughness. Compared with the multilayer heterostructure, those based on blends present an improvement in the electrical properties. Under illumination, the highest current value was recorded for the heterostructure based on the blend with the higher C60 amount. The obtained results showed that MAPLE is a useful technique for the deposition of the organic heterostructures on AZO as transparent conductor electrode. (C) 2017 Elsevier B.V. All rights reserved.

22. INVESTIGATIONS ON THE PROPERTIES OF A TWO-DIMENSIONAL NANOPATTERNED METALLIC FILM

Authors: Breazu, C; Preda, N; Socol, M; Stanculescu, F; Matei, E; Stavarache, I; Iordache, G; Girtan, M; Rasoga, O; Stanculescu, A

Published: OCT-DEC 2016, Digest Journal of Nanomaterials and Biostructures, 11, 1229, DOI:

This paper presents some investigations of the effect of nanopatterning on the properties of aluminum layer deposited by sputtering. UV-Nanoimprint Lithography technique has been used for the realization of a 2D array of nanostructures (pillars) in aluminum film characterized by cylindrical shape and the following structural parameters: diameter between 400 nm and 490 nm, depth between 320 nm and 420 nm and periodicity of 1.1 mu m, which have been revealed by SEM and AFM measurements. The UV-Vis transmission, reflection and photoluminescence measurements have evidenced the effect of the nanopatterning on the optical properties of the A1 layer.

23. MAPLE preparation and characterization of mixed arylenevinylene based oligomers:C-60 layers

Authors: Stanculescu, A; Socol, G; Vacareanu, L; Socol, M; Rasoga, O; Breazu, C; Girtan, M; Stanculescu, F

Published: JUN 30 2016, APPLIED SURFACE SCIENCE, 374, 289, DOI: 10.1016/j.apsusc.2015.11.250

This paper presents some studies about the preparation by matrix-assisted pulsed laser evaporation (MAPLE) of mixed layers based on two arylenevinylene oligomers, 1,4-bis [4-(N,N'-diphenylamino)phenylvinyl] benzene (L78) and 3,3'-bis(N-hexylcarbazole)vinylbenzene (L13) as donor and buckminsterfullerene (C-60) as acceptor, blended in three different weight ratios: 1:1, 1:2 and 1:3. The optical, morphological, structural and electrical properties of these mixed layers have been investigated emphasizing the effect of the layer composition and of the significant degree of disorder. I-V characteristics have revealed typically solar cell behaviour for the heterostructures prepared with mixed layers containing L78 (L13) and fullerene blended in a weight ratio of 1:2. The solar cell structure glass/ITO/L13:C-60/Al has shown the best parameters. (C) 2015 Elsevier B.V. All rights reserved.

24. Flexible heterostructures based on metal phthalocyanines thin films obtained by MAPLE

Authors: Socol, M; Preda, N; Rasoga, O; Breazu, C; Stavarache, I; Stanculescu, F; Socol, G; Gherendi, F; Grumezescu, V; Popescu-Pelin, G; Girtan, M; Stefan, N

Published: JUN 30 2016, APPLIED SURFACE SCIENCE, 374, 410, DOI: 10.1016/j.apsusc.2015.10.166

Heterostructures based on zinc phthalocyanine (ZnPc), magnesium phthalocyanine (MgPc) and 5,10,15,20-tetra(4-pyrydil)21H,23H-porphine (TPyP) were deposited on ITO flexible substrates by Matrix Assisted Pulsed Laser Evaporation (MAPLE) technique. Organic heterostructures containing (TPyP/ZnPc(MgPc)) stacked or (ZnPc(MgPc):TPyP) mixed layers were characterized by X-ray diffraction-XRD, photoluminescence-PL, UV-vis and FTIR spectroscopy. No chemical decomposition of the initial materials was observed. The investigated structures present a large spectral absorption in the visible range making them suitable for organic photovoltaics applications (OPV). Scanning electron microscopy-SEM and atomic force microscopy-AFM revealed morphologies typical for the films prepared by MAPLE. The current-voltage characteristics of the investigated structures, measured in dark and under light, present an improvement in the current value (similar to 3 order of magnitude larger) for the structure based on the mixed layer (Al/MgPc:TPyP/ITO) in comparison with the stacked layer (Al/MgPc//TPyP/ITO). A photogeneration process was evidenced in the case of structures Al/ZnPc:TPyP/ITO with mixed layers. (C) 2015 Elsevier B.V. All rights reserved.

25. HETEROSTRUCTURES BASED ON SMALL MOLECULES ORGANIC COMPOUNDS

Authors: Socol, M; Rasoga, O; Breazu, C; Socol, G; Preda, N; Pasuk, I; Visan, D; Stavarache, I; Gherendi, F; Girtan, M; Sidwaba, U

Published: OCT-DEC 2015, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 10, 1392, DOI:

Heterostructures with layers from small molecules organic compounds were deposited on ITO/glass substrate by thermal vacuum evaporation (TVE) technique. Structural, optical and morphological investigations were carried out on the realised layers (zinc phthalocyanine-ZnPc, fullerene-C60 and 1,4,5,8-naphthalene-tetracarboxylic dianhydride-NTCDA). The films are polycrystalline keeping the morphological features characteristic to these materials. The prepared heterostructures reveal a large absorption domain in the visible domain. The current-voltage (I-V) characteristics of the investigated structures, recorded in dark, present an improvement in the current value (similar to one order of magnitude) for the standard structure (ITO/PEDOT: PSS/ZnPc/C60/NTCDA/Al) with a supplimentary layer of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS). For the inverted structure (Al/NTCDA/C60/ZnPc/ITO) was also noticed an increased curent value in comparasion with that observed for the standard structure.

26. MAPLE prepared heterostructures with arylene based polymer active layer for photovoltaic applications

Authors: Stanculescu, F; Rasoga, O; Catargiu, AM; Vacareanu, L; Socol, M; Breazu, C; Preda, N; Socol, G; Stanculescu, A

Published: MAY 1 2015, APPLIED SURFACE SCIENCE, 336, 248, DOI: 10.1016/j.apsusc.2014.11.146

This paper presents some studies about the preparation by matrix-assisted pulsed laser evaporation (MAPLE) technique of heterostructures with single layer of arylene based polymer, poly[N-(2-ethylhexy1)2.7-carbazoly1 vinylene]/AMC16 and poly[N-(2-ethylhexy1)2.7-carbazolyl 1.4-phenylene ethynylene]/AMC22, and with layers of these polymers mixed with Buckminsterfullerene/C-60 in the weight ratio of 1:2 (AMC16: C60) and 1:3 (AMC22: C60). The deposited layers have been characterized by spectroscopic (UV-Vis-NIR, PL, FTIR) and microscopic (SEM, AFM) methods. The effect of the polymer particularities on the optical and electrical properties of the structures based on polymer and polymer: C-60 mixed layer has been analyzed. The study of the electrical properties has revealed typical solar cell behavior for the heterostructure prepared by MAPLE on glass/ITO/PEDOT-PSS with AMC16, AMC22 and AMC22: C-60 layer, confirming that this method is adequate for the preparation of polymeric and mixed active layers for solar cells applications. The highest photovoltaic effect was shown by the solar cell structure realized with single layer of AMC16 polymer: g1a55/ITO/PEDOT-PSSIA1VIC16/A1. (C) 2014 Elsevier B.V. All rights reserved.

27. EFFECT OF CHOLESTEROL ON THE DEPOSITION OF BETA-AMYLOID 1-40 AND 1-42 FILMS

Authors: Breazu, C; Stanculescu, A; Socol, M; Rasoga, O

Published: JAN-MAR 2015, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 10, 313, DOI:

We report the pressure vs area isotherms of Langmuir films of pure and doped with cholesterol (Ch) amyloid beta, A beta (1-40) and (1-42) at the air-water interface and, scanning electron microscopy (SEM) and atomic force microscopy (AFM) studies of A beta (1-40) and (1-42) layers deposited from solution by drop cast and/or dipping and/or Langmuir-Blodgett on substrates of quartz and Si. The particularity of the substrate surface morphology determines the adhesion forces and plays an important role in the formation and stability of the multilayer films which are deposited on these substrates. The effect of cholesterol on the morphology of amyloids films and appearance of fibril structures is also analysed. AFM investigations have revealed the particularities of the aggregation process of the strongly hydrophobic A beta (1-42) on cholesterol films deposited by Langmuir-Blodgett on solid support of quartz and Si.

28. Laser prepared organic heterostructures based on star-shaped arylenevinylene compounds

Authors: Stanculescu, A; Socol, G; Grigoras, M; Ivan, T; Vacareanu, L; Socol, M; Rasoga, O; Breazu, C; Mihailescu, IN; Iordache, I; Preda, N; Stanculescu, F

Published: OCT 2014, APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 117, 268, DOI: 10.1007/s00339-014-8521-1

This paper presents some studies about the preparation by matrix-assisted pulsed laser evaporation (MAPLE) technique of organic bulk heterojunctions made from the mixture of a star-shaped arylenevinylene compound, 4,4',4aEuro(3)-tris[(4'-diphenylamino)styryl] triphenylamine as donor and fullerene derivative, [6, 6]-phenyl C61 butyric acid butyl ester, as acceptor, in the weight ratio 1:2. The mixed layer has been characterized by spectroscopic (UV-Vis, Fourier transform infrared) and microscopic (AFM) methods, and the effects of the deposition conditions (number of pulses) and of a buffer layer of poly(aniline-co-aniline propane sulfonic acid) or poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) have been analyzed. The study of the electrical properties has revealed a typical solar cell behavior for the heterostructure glass/ITO/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)/4,4',4aEuro(3)-tris[(4'-diphenylamino)styryl] triphenylamine: [6, 6]-phenyl C61 butyric acid butyl ester/Al, confirming that MAPLE could be an adequate method for the preparation of active layer based on bulk heterojunction for solar cells.

29. Laser prepared organic heterostuctures on glass/AZO substrates

Authors: Stanculescu, A; Socol, M; Rasoga, O; Mihailescu, IN; Socol, G; Preda, N; Breazu, C; Stanculescu, F

Published: MAY 30 2014, APPLIED SURFACE SCIENCE, 302, 176, DOI: 10.1016/j.apsusc.2014.01.181

This paper presents some studies about the bi-layer organic heterostructures realized with zinc phthalocyanine (ZnPc) as donor layer and 1,4,5,8-naphthalene-tetracarboxylic dianhydride (NTCDA) as acceptor layer, on substrate of glass covered by Al doped ZnO (AZO) layer. These heterostructures have been prepared using laser techniques: pulsed laser deposition (PLD) in an atmosphere of oxygen for AZO films deposition and matrix assisted pulsed laser evaporation (MAPLE) for organic films deposition. The influence of the deposition conditions on the transmission of the organic films has been analysed. The effect of the oxygen plasma treatment, with duration of 5 min and 10 min, on the surface topography, structural and optical properties of AZO layers deposited by PLD and, as consequence, on the optical and electrical properties of the single layer (ZnPc) and bi-layer (ZnPc/NTCDA) organic heterostructure, deposited by MAPLE, was investigated. (C) 2014 Elsevier B.V. All rights reserved.

30. Organic Heterostructures with Indium-Free Transparent Conductor Electrode for Optoelectronic Applications

Authors: Petre, G; Stanculescu, A; Girtan, M; Socol, M; Breazu, C; Vacareanu, L; Preda, N; Rasoga, O; Stanculescu, F; Doroshkevich, AS

Published: DEC 2021 , PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, DOI: 10.1002/pssa.202100521

Herein, the properties of the organic heterostructures with triple-layer ZnO/Ag/ZnO as a replacement for ITO and mixed layer containing arylenevinylene oligomer (based on triphenylamine or carbazole) donor and nonfullerene (perylene diimide) acceptor mixed in the ratio 1:2 and the effect of a buffer layer of PEDOT-PSS intercalated between triple layer and mixed organic layer are discussed. The UV-vis transmission and photoluminescence (PL) properties are investigated in correlation with the surface topography and reveal a good match between the absorption and emission domain, which can favor the generation of the charge carriers. The heterostructure with the mixed layer based on triphenylamine oligomer shows the widest absorption domain, and the PL spectra of the heterostructures realized with either triphenylamine or carbazole oligomer show peaks corresponding to the radiative decay of the donor and acceptor. The I-V characteristics in the dark indicate a slightly nonlinear behavior and the current is affected by the charge carriers recombination on the defects present in the thick mixed layer deposited by matrix-assisted pulsed laser evaporation. The effect of the PEDOT-PSS buffer layer on the electrical properties of the organic heterostructure with ZnO/Ag/ZnO electrode is also investigated.

31. Organic Heterostructures with Indium-Free Transparent Conductor Electrode for Optoelectronic Applications