NIMP| Ionut ENCULESCU, Author at NIMP

Projects

1. Biomimetic sensors based on high performance, nanowire channel field effect transistors

Project Type: IDEI, Start Date: 2017-07-12 End Date: 2019-12-10

2. Spin and charge control in nanowire field effect transistors

Project Type: IDEI, Start Date: 2013-09-01 End Date: 2016-09-01

3. High Efficiency Electrospinning

Project Type: , Start Date: 2012-07-01 End Date: 2015-07-01

Publications

1. Palladium-Coated Submicron Electrospun Polymeric Fibers with Immobilized Uricase for Uric Acid Determination in Body Fluids

Authors: Leote, RJB; Crisan, DN; Matei, E; Enculescu, I; Diculescu, VC

Published: 2024 FEB 12 2024, ACS APPLIED POLYMER MATERIALS, 6, DOI: 10.1021/acsapm.3c02811

This work describes the development of a flexible uric acid (UA) biosensor based on palladium-coated submicrometer electrospun poly(methylmethacrylate) (PMMA) fibers metalized with gold and attached to polyethylene terephthalate substrate (Pd/Au/PMMA/PET). The morphological characterization conducted by scanning electron microscopy revealed nanoscale Pd dendritic structures. Electrochemical investigations in the absence and in the presence of redox probes demonstrated that these Pd nanostructures are responsible for a six-fold increase in the electroactive area and enhanced electron transfer kinetics when compared to the gold-coated electrospun fibers. The UA biosensor obtained by immobilizing the uricase enzyme (UrOx) onto the Pd/Au/PMMA/PET electrode surface, allowed UA detection with a sensitivity of 431 mu A cm(-2) mM(-1) and a limit of detection of 12 mu M. Investigation of the redox reactions of hydrogen peroxide (a product of the enzymatic oxidation of UA by UrOx) at the Pd/Au/PMMA/PET electrode demonstrated that the working principle of the biosensor is based on the reduction of PdO produced at the electrode surface during the spontaneous reduction of hydrogen peroxide on Pd. This allows a biosensor operating potential of -0.05 V (vs Ag/AgCl) with high selectivity. The UrOx/Pd/Au/PMMA/PET biosensor was applied for UA detection in body fluids (sweat, urine, and blood serum) with recovery values between 98 and 105%, which were validated by high-performance liquid chromatography analysis. The stability of the device was evaluated over a period of 3 months, retaining 78% of the initial sensitivity, and reproducibility with RSD = 4.9% was achieved. The analytical performance of the biosensor under harsh mechanical deformations and at physiological temperatures demonstrated the potential applications of the device to wearable sensing platforms.

2. Palladium-Coated Submicron Electrospun Polymeric Fibers with Immobilized Uricase for Uric Acid Determination in Body Fluids

Authors: Leote, RJB; Crisan, DN; Matei, E; Enculescu, I; Diculescu, VC

Published: FEB 12 2024, ACS APPLIED POLYMER MATERIALS, 6, DOI: 10.1021/acsapm.3c02811

3. PEDOT:PSS based electrospun nanofibres used as trigger for fibroblasts differentiation

Authors: Beregoi, M; Enache, TA; Oprea, D; Enculescu, M; Ciobotaru, IC; Busuioc, C; Enculescu, I

Published: JAN 1 2024, SMART MATERIALS AND STRUCTURES, 33, 015009, DOI: 10.1088/1361-665X/ad10bf

Electrospun nanofibres based on poly(styrene sulfonate) doped poly(3,4-ethylenedioxythiophene) (PEDOT:PSS) were fabricated using a straightforward procedure which combines electrospinning, sputtering deposition and electrochemical synthesis. In general, electrospun fibre meshes based on conducting polymers are prepared by mixing the conducting polymer with a carrier polymer or chemically coverage of the fibres. In contrast, freestanding nylon 6/6 nanofibre webs were prepared through electrospinning and were coated by sputtering with gold in order to make them conductive. Further, a PEDOT:PSS layer was electrochemically deposited onto the metalized nanofibre meshes and the synthesis parameters were chosen in such a way to preserve the high active area of the fibres. The prepared material was morphologically characterized and the formation of PEDOT:PSS was also demonstrated. The PEDOT:PSS coated nanofibres revealed remarkable electrical properties (sheet resistance of about 3.5 Omega cm(-2)), similar to those of metalized nanofibres (sheet resistance around 3 Omega cm2). The in vitro studies using L929 fibroblast mouse cells showed that the bioactive material has no cytotoxic effect and allows proliferation. Moreover, after 72 h of incubation, the fibroblasts shrunk their nuclei and spread suggesting that a differentiation in myofibroblast occurs without application of any kind of external stimuli. These results will be helpful for developing efficient materials for wound healing applications that work without energy consumption.

4. GRAPHENE FOR ELECTRONIC DEVICES - SYNTHESIS AND CHARACTERIZATION

Authors: Apostol, M; Enache, A; Diculescu, V; Tite, T; Onea, M; Enculescu, I; Matei, E; Andronescu, E

Published: 2024, UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN SERIES B-CHEMISTRY AND MATERIALS SCIENCE, 86, DOI:

In this paper, graphene was obtained on a copper substrate using the CVD method, and then it was transferred to various substrates such as glass and SiO2/Si patterned with metallic interdigitated electrodes. The graphene thus obtained was characterized using Raman spectroscopy, scanning electron microscopy (SEM), current-voltage measurements, and electrochemical methods, in order to be used for sensing applications.

5. Organic Light-Emitting Diodes with Electrospun Electrodes for Double-Side Emissions

Authors: Ciobotaru, IC; Enculescu, M; Polosan, S; Enculescu, I; Ciobotaru, CC

Published: MAR 2023, MICROMACHINES, 14, 543, DOI: 10.3390/mi14030543

Transparent conductive electrodes (TCE) obtained by the electrospinning method and gold covered were used as cathodes in the organic light-emitting diodes (OLEDs) to create double side-emission. The electro-active nanofibers of poly(methyl methacrylate) (PMMA) with diameters in the range of several hundreds of nanometers, were prepared through the electrospinning method. The nanofibers were coated with gold by sputtering deposition, maintaining optimal transparency and conductivity to increase the electroluminescence on both electrodes. Optical, structural, and electrical measurements of the as-prepared transparent electrodes have shown good transparency and higher electrical conductivity. In this study, two types of OLEDs consisting of indium tin oxide (ITO)/ poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS)/ Ir(III) complex (8-hydroxyquinolinat bis(2-phenylpyridyl) iridium-IrQ(ppy)(2) 20 wt% embedded in N, N '-Dicarbazolyl-4,4 '-biphenyl (CBP) sandwich structure and either gold-covered PMMA electrospun nanoweb (OLED with electrospun cathode) were fabricated together with a similar structure containing thin film gold cathodes (OLED with thin film cathode). The luminance-current-voltage characteristics, the capacitance-voltage, and the electroluminescence properties of these OLEDs were investigated.

6. Integrated architectures of electrodes and flexible porous substrates for point-of-care testing

Authors: Botta, D; Enculescu, I; Balan, C; Diculescu, VC

Published: DEC 2023, CURRENT OPINION IN ELECTROCHEMISTRY, 42, 101418, DOI: 10.1016/j.coelec.2023.101418

Flexible porous materials have gained a high interest due to their impact on the development of electrochemical point-ofcare devices for monitoring the state of health of individuals. Among the porous materials, paper and textiles are most commonly used due to their innate capillary action on fluids. In this article, attention is paid to the retention of analytes in paper and textile porous substrates, and possible procedures to overcome this effect are discussed. The patterning of hydrophilic and hydrophobic regions for sample flow manipulation, and the folding properties of the flexible substrates for 3D architectures capable of transfer of analytes, are considered in relation to current electrode materials and detection methodologies.

7. Silver nanoparticles decorated ZnO-CuO core-shell nanowire arrays with low water adhesion and high antibacterial activity

Authors: Costas, A; Preda, N; Zgura, I; Kuncser, A; Apostol, N; Curutiu, C; Enculescu, I

Published: JUL 3 2023, SCIENTIFIC REPORTS, 13, 10698, DOI: 10.1038/s41598-023-37953-w

Nanostructured surfaces based on silver nanoparticles decorated ZnO-CuO core-shell nanowire arrays, which can assure protection against various environmental factors such as water and bacteria were developed by combining dry preparation techniques namely thermal oxidation in air, radio frequency (RF) magnetron sputtering and thermal vacuum evaporation. Thus, high-aspect-ratio ZnO nanowire arrays were grown directly on zinc foils by thermal oxidation in air. Further ZnO nanowires were coated with a CuO layer by RF magnetron sputtering, the obtained ZnO-CuO core-shell nanowires being decorated with Ag nanoparticles by thermal vacuum evaporation. The prepared samples were comprehensively assessed from morphological, compositional, structural, optical, surface chemistry, wetting and antibacterial activity point of view. The wettability studies show that native Zn foil and ZnO nanowire arrays grown on it are featured by a high water droplet adhesion while ZnO-CuO core-shell nanowire arrays (before and after decoration with Ag nanoparticles) reveal a low water droplet adhesion. The antibacterial tests carried on Escherichia coli (a Gram-negative bacterium) and Staphylococcus aureus (a Gram-positive bacterium) emphasize that the nanostructured surfaces based on nanowire arrays present excellent antibacterial activity against both type of bacteria. This study proves that functional surfaces obtained by relatively simple and highly reproducible preparation techniques that can be easily scaled to large area are very attractive in the field of water repellent coatings with enhanced antibacterial function.

8. Monodispersed nanoplatelets of samarium oxides for biosensing applications in biological fluids

Authors: Leote, RJB; Matei, E; Apostol, NG; Enculescu, M; Enculescu, I; Diculescu, VC

Published: JAN 10 2022, ELECTROCHIMICA ACTA, 402, 139532, DOI: 10.1016/j.electacta.2021.139532

A nanostructured samarium oxide electrode was constructed by electrodeposition onto the surface of a gold electrode on SiO2/Si wafer. The samarium oxides electrode's surface morphology was investigated by scanning electron microcopy showing a quasi-monodispersed nanoplatelets like structure. X-rays diffraction analysis demonstrated a mixture of monoclinic and hexagonal phases while the X-rays photoelectron spectroscopy indicated the co-existence of both Sm2+ and Sm3+ species in a 1:3 proportion. Cyclic voltammetry and electrochemical impedance spectroscopy were used to investigate the charge transfer processes at the surface of the samarium oxide electrode in the absence and in the presence of redox probes. A roughness factor of 2.5 was determined from the samarium oxide electrode while the charge transfer constant was almost double when compared to the planar gold electrode. Then, the samarium oxide electrode was used for the H2O2 detection by fixed potential amperometry at -0.20 V (vs. Ag/AgCl) with a linear region between 0.01 and 1.00 mM, a sensitivity of 153 mu A cm(-2) mM(-1) and a LoD = 2.70 mu M. Glucose oxidase was used as a model enzyme in order to test the capacity of the samarium oxides electrode for biosensing. The enzyme was immobilized by physical adsorption and the optimum conditions for glucose analysis investigated. The biosensor showed a linear range for glucose detection between 0.10 and 1.20 mM with a sensitivity of 8.40 mu A cm(-2) mM(-1) and a LoD = 8.00 mu M. Selectivity was tested toward common interfering species, and the results revealed the lack of biosensor response. The glucose biosensor on samarium oxides was tested for glucose detection in serum samples with a recovery factor of 90%, and the result validated with a commercial glucometer. (C) 2021 Elsevier Ltd. All rights reserved.

9. Metallized electrospun polymeric fibers for electrochemical sensors and actuators

Authors: Leote, RJB; Beregoi, M; Enculescu, I; Diculescu, VC

Published: AUG 2022, CURRENT OPINION IN ELECTROCHEMISTRY, 34, 101024, DOI: 10.1016/j.coelec.2022.101024

Electrospun polymeric fibers present an emerging alternative for the development of flexible electronics, enabling applications in wearable sensors and biosensors for continuous monitoring, and actuators for tissue engineering. The possibility to prepare sub-micrometric polymeric scaffolds, their processing for increasing the conductivity, their modification with different materials, conductive polymers and biomolecules in order to obtain functional flexible electrodes, allows the development of innovative devices for healthcare, and biomedical applications. In this review, the impact of metallized electrospun polymeric fibers in electrochemical (bio)sensors and actuators is discussed. A relation between their structure and functionality is provided, alongside with an overview of the different methods to obtain functional conductive fibers.

10. Self-connected CuO-ZnO radial core-shell heterojunction nanowire arrays grown on interdigitated electrodes for visible-light photodetectors

Authors: Costas, A; Florica, C; Preda, N; Besleaga, C; Kuncser, A; Enculescu, I

Published: APR 27 2022, SCIENTIFIC REPORTS, 12, 6834, DOI: 10.1038/s41598-022-10879-5

An original photodetector system based on self-connected CuO-ZnO radial core-shell heterojunction nanowire arrays grown on metallic interdigitated electrodes, operating as visible-light photodetector was developed by combining simple preparation approaches. Metallic interdigitated electrodes were fabricated on Si/SiO2 substrates using a conventional photolithography process. Subsequently, a Cu layer was electrodeposited on top of the metallic interdigitated electrodes. The CuO nanowire arrays (core) were obtained by thermal oxidation in air of the Cu layer. Afterwards, a ZnO thin film (shell) was deposited by RF magnetron sputtering covering the surface of the CuO nanowires. The morphological, structural, compositional, optical, electrical and photoelectrical properties of the CuO nanowire arrays and CuO-ZnO core-shell nanowire arrays grown on metallic interdigitated electrodes were investigated. The performances of the devices were evaluated by assessing the figures of merit of the photodetectors based on self-connected CuO-ZnO core-shell heterojunction nanowire arrays grown on the metallic interdigitated electrodes. The radial p-n heterojunction formed between CuO and ZnO generates a type II band alignment that favors an efficient charge separation of photogenerated electron-hole pairs at the CuO-ZnO interface, suppressing their recombination and consequently enhancing the photoresponse and the photoresponsivity of the photodetectors. The electrical connections in the fabricated photodetector devices are made without any additional complex and time-consuming lithographic step through a self-connecting approach for CuO-ZnO core-shell heterojunction nanowire arrays grown directly onto the Ti/Pt metallic interdigitated electrodes. Therefore, the present study provides an accessible path for employing low dimensional complex structures in functional optoelectronic devices such as photodetectors.

11. Direct and remote induced actuation in artificial muscles based on electrospun fiber networks

Authors: Bunea, MC; Beregoi, M; Evanghelidis, A; Galatanu, A; Enculescu, I

Published: JUL 29 2022, SCIENTIFIC REPORTS, 12, 13084, DOI: 10.1038/s41598-022-16872-2

The present work reports a new configuration of soft artificial muscle based on a web of metal covered nylon 6/6 micrometric fibers attached to a thin polydimethylsiloxane (PDMS) film. The preparation process is simple and implies the attachment of metalized fiber networks to a PDMS sheet substrate while heating and applying compression. The resulting composite is versatile and can be cut in different shapes as a function of the application sought. When an electric current passes through the metallic web, heat is produced, leading to local dilatation and to subsequent controlled deformation. Because of this, the artificial muscle displays a fast and ample movement (maximum displacement of 0.8 cm) when applying a relatively low voltage (2.2 V), a consequence of the contrast between the thermal expanse coefficients of the PDMS substrate and of the web-like electrode. It was shown that the electrical current producing this effect can originate from both direct electric contacts, and untethered configurations i.e. radio frequency induced. Usually, for thermal activated actuators the heating is produced by using metallic films or conductive carbon-based materials, while here a fast heating/cooling process is obtained by using microfiber-based heaters. This new approach for untethered devices is an interesting path to follow, opening a wide range of applications were autonomous actuation and remote transfer of energy are needed.

12. Charge transport mechanisms in free-standing devices with electrospun electrodes

Authors: Ciobotaru, IC; Polosan, S; Enculescu, M; Nitescu, A; Enculescu, I; Beregoi, M; Ciobotaru, CC

Published: SEP 24 2022, NANOTECHNOLOGY, 33, 395203, DOI: 10.1088/1361-6528/ac7ac1

Embedding electronic and optoelectronic devices in common, daily use objects is a fast developing field of research. New architectures are needed for migrating from the classic wafer- based substrates. Novel types of flexible PMMA/Au/Alq(3)/LiF/Al structures were obtained starting from electrospun polymer fibers. Thus, using an electrospinning process poly (methyl metacrylate) (PMMA) nanofibers were fabricated. A thin Au layer deposition rendered the fiber array conductive, this being further employed as the anode. The next steps consisted of the thermal evaporation of tris(8-hydroxyquinolinato) aluminum (Alq(3)) and aluminum deposition as the cathode. The Au covered PMMA nanofiber layer had a similar behavior with an indium tin oxide film i.e. low sheet resistance 10.6 omega/sq and high transparency. The low electrode resistivities allow an electron drift mobility of about 10(-6) cm(2) V-1 s(-1) at a low applied field, similar to the counterpart structures based on thin films. Concerning the relaxation processes in these structures, the Cole-Cole plots exhibit a slightly deformed semicircle, indicating a more complex equivalent circuit for the processes between metal electrodes and the active layer. This equivalent circuit includes reactance equivalent processes at the anode, cathode, in the active layer and most probably originates from the roughness of the metallic electrodes.

13. Electrochemical Deposition of ZnO Nanowires on CVD-Graphene/Copper Substrates

Authors: Boukhoubza, I; Matei, E; Jorio, A; Enculescu, M; Enculescu, I

Published: AUG 2022, NANOMATERIALS, 12, 2858, DOI: 10.3390/nano12162858

ZnO nanostructures were electrochemically synthesized on Cu and on chemical vapor deposited (CVD)-graphene/Cu electrodes. The deposition was performed at different electrode potentials ranging from -0.8 to -1.2 V, employing a zinc nitrate bath, and using voltametric and chronoamperometric techniques. The effects of the electrode nature and of the working electrode potential on the structural, morphological, and optical properties of the ZnO structures were investigated. It was found that all the samples crystallize in hexagonal wurtzite structure with a preferential orientation along the c-axis. Scanning electron microscopy (SEM) images confirm that the presence of a graphene covered electrode led to the formation of ZnO nanowires with a smaller diameter compared with the deposition directly on copper surface. The photoluminescence (PL) measurements revealed that the ZnO nanowires grown on graphene/Cu exhibit stronger emission compared to the nanowires grown on Cu. The obtained results add another possibility of tailoring the properties of such nanostructured films according to the specific functionality required.

14. Bioinspired polypyrrole based fibrillary artificial muscle with actuation and intrinsic sensing capabilities

Authors: Beregoi, M; Beaumont, S; Evanghelidis, A; Otero, TF; Enculescu, I

Published: SEP 2 2022, SCIENTIFIC REPORTS, 12, 15019, DOI: 10.1038/s41598-022-18955-6

A non-conventional, bioinspired device based on polypyrrole coated electrospun fibrous microstructures, which simultaneously works as artificial muscle and mechanical sensor is reported. Fibrous morphology is preferred due to its high active surface which can improve the actuation/sensing properties, its preparation still being challenging. Thus, a simple fabrication algorithm based on electrospinning, sputtering deposition and electrochemical polymerization produced electroactive aligned ribbon meshes with analogous characteristics as natural muscle fibers. These can simultaneously generate a movement (by applying an electric current/potential) and sense the effort of holding weights (by measuring the potential/current while holding objects up to 21.1 mg). Electroactivity was consisting in a fast bending/curling motion, depending on the fiber strip width. The amplitude of the movement decreases by increasing the load, a behavior similar with natural muscles. Moreover, when different weights were hung on the device, it senses the load modification, demonstrating a sensitivity of about 7 mV/mg for oxidation and - 4 mV/mg for reduction. These results are important since simultaneous actuation and sensitivity are essential for complex activity. Such devices with multiple functionalities can open new possibilities of applications as e.g. smart prosthesis or lifelike robots.

15. Chemical sensing and actuation properties of polypyrrole coated fibers

Authors: Beregoi, M; Beaumont, S; Jinga, SI; Otero, TF; Enculescu, I

Published: OCT 1 2022, SMART MATERIALS AND STRUCTURES, 31, 105012, DOI: 10.1088/1361-665X/ac83ff

Designing complex electrochemical artificial muscles aims towards novel devices which besides excellent actuation capabilities should also present the ability to self-sense the modification of environmental parameters. In order to improve efficiency, mimicking the structure of natural muscles, synthetic actuators should have a similar fibrillary morphology. The importance of using materials based on fiber building blocks in actuators aimed at soft robotics field was demonstrated in the present report by comparing a fibrillary artificial muscle with one based on a classical film structure. Nylon electrospun fiber meshes and films were covered in the same conditions with a thin polypyrrole (PPy) layer. The fibrillary electrospun web morphology mimics that of natural muscles and the structure performs a fast, ample bending movement in liquid electrolyte when switching an applied electric potential between -0.6 and +0.6 V. Using the same actuation conditions, no movement of a film based artificial muscle was observed. In order to check the sensing ability of both fibrillary and film like electroactive architectures, their response i.e. PPy reaction when potential cycles were applied in different concentrations of LiClO4 electrolyte were recorded. The obtained results suggest that the ion exchange of the fibrillary artificial muscle is more efficient due to its higher active surface and such devices could work also as dual device (sensor/artificial muscle).

16. Gold coated electrospun polymeric fibres as new electrode platform for glucose oxidase immobilization

Authors: Aldea, A; Leote, RJB; Matei, E; Evanghelidis, A; Enculescu, I; Diculescu, VC

Published: JUN 2021, MICROCHEMICAL JOURNAL, 165, 106108, DOI: 10.1016/j.microc.2021.106108

Fibres of poly(methyl methacrylate) were obtained by electrospinning, subjected to coating with a gold layer and then attached on a thin polyethylene terephthalate substrate in order to obtain flexible electrodes for biosensing applications. The morphology of these electrodes, investigated by scanning electron microscopy showed multilayers of random oriented fibres of approx. 400 nm diameter. The electrochemical characterization of these flexible electrodes was performed by cyclic voltammetry and electrochemical impedance spectroscopy in acid and neutral media, in the absence and in the presence of redox probes, proving their superior performance (e.g. 5fold current density value) when compared to planar gold electrodes obtained on silicon wafers. The electrodes obtained from conductive electrospun polymeric fibres nets were tested by cyclic voltammetry and amperometry for the detection of hydrogen peroxide with a sensitivity of 0.84 mA cm-2 mM-1 and a detection limit of 20.40 ?M. The immobilization of the model enzyme glucose oxidase at the surface of the gold-coated electrospun polymeric fibres electrode was investigated and the obtained biosensor was applied for glucose determination in aqueous solutions by fixed potential amperometry with a sensitivity of 3.10 ?A cm-2 mM-1, a detection limit of 0.33 mM, and reduced interferences. Also, the practical applicability of the biosensor was tested for the detection of glucose in artificial sweat and serum samples.

17. Fabrication of ZnO and TiO2 Nanotubes via Flexible Electro-Spun Nanofibers for Photocatalytic Applications

Authors: Enculescu, M; Costas, A; Evanghelidis, A; Enculescu, I

Published: MAY 2021, NANOMATERIALS, 11, DOI: 10.3390/nano11051305

Web-like architectures of ZnO and TiO2 nanotubes were fabricated based on a three-step process of templating polymer nanofibers produced by electrospinning (step 1). The electrospun polymer nanofibers were covered by radio-frequency magnetron sputtering with thin layers of semiconducting materials (step 2), with FESEM observations proving uniform deposits over their entire surface. ZnO or TiO2 nanotubes were obtained by subsequent calcination (step 3). XRD measurements proved that the nanotubes were of a single crystalline phase (wurtzite for ZnO and anatase for TiO2) and that no other crystalline phases appeared. No other elements were present in the composition of the nanotubes, confirmed by EDX measurements. Reflectance spectra and Tauc plots of Kubelka-Munk functions revealed that the band gaps of the nanotubes were lower than those of the bulk materials (3.05 eV for ZnO and 3.16 eV for TiO2). Photocatalytic performances for the degradation of Rhodamine B showed a large degradation efficiency, even for small quantities of nanotubes (0.5 mg/10 mL dye solution): similar to 55% for ZnO, and similar to 95% for TiO2.

18. Photodetecting properties of single CuO-ZnO core-shell nanowires with p-n radial heterojunction

Authors: Costas, A; Florica, C; Preda, N; Kuncser, A; Enculescu, I

Published: OCT 29 2020, SCIENTIFIC REPORTS, 10, DOI: 10.1038/s41598-020-74963-4

CuO-ZnO core-shell radial heterojunction nanowire arrays were obtained by a simple route which implies two cost-effective methods: thermal oxidation in air for preparing CuO nanowire arrays, acting as a p-type core and RF magnetron sputtering for coating the surface of the CuO nanowires with a ZnO thin film, acting as a n-type shell. The morphological, structural, optical and compositional properties of the CuO-ZnO core-shell nanowire arrays were investigated. In order to analyse the electrical and photoelectrical properties of the metal oxide nanowires, single CuO and CuO-ZnO core-shell nanowires were contacted by employing electron beam lithography (EBL) and focused ion beam induced deposition (FIBID). The photoelectrical properties emphasize that the p-n radial heterojunction diodes based on single CuO-ZnO core-shell nanowires behave as photodetectors, evidencing a time-depending photoresponse under illumination at 520 nm and 405 nm wavelengths. The performance of the photodetector device was evaluated by assessing its key parameters: responsivity, external quantum efficiency and detectivity. The results highlighted that the obtained CuO-ZnO core-shell nanowires are emerging as potential building blocks for a next generation of photodetector devices.

19. Functionalization of eggshell membranes with CuO-ZnO based p-n junctions for visible light induced antibacterial activity against Escherichia coli

Authors: Preda, N; Costas, A; Beregoi, M; Apostol, N; Kuncser, A; Curutiu, C; Iordache, F; Enculescu, I

Published: DEC 1 2020, SCIENTIFIC REPORTS, 10, DOI: 10.1038/s41598-020-78005-x

Biopolymers provide versatile platforms for designing naturally-derived wound care dressings through eco-friendly pathways. Eggshell membrane (ESM), a widely available, biocompatible biopolymer based structure features a unique 3D porous interwoven fibrous protein network. The ESM was functionalized with inorganic compounds (Ag, ZnO, CuO used either separately or combined) using a straightforward deposition technique namely radio frequency magnetron sputtering. The functionalized ESMs were characterized from morphological, structural, compositional, surface chemistry, optical, cytotoxicity and antibacterial point of view. It was emphasized that functionalization with a combination of metal oxides and exposure to visible light results in a highly efficient antibacterial activity against Escherichia coli when compared to the activity of individual metal oxide components. It is assumed that this is possible due to the fact that an axial p-n junction is created by joining the two metal oxides. This structure separates into components the charge carrier pairs promoted by visible light irradiation that further can influence the generation of reactive oxygen species which ultimately are responsible for the bactericide effect. This study proves that, by employing inexpensive and environmentally friendly materials (ESM and metal oxides) and fabrication techniques (radio frequency magnetron sputtering), affordable antibacterial materials can be developed for potential applications in chronic wound healing device area.

20. Biomorphic 3D fibrous networks based on ZnO, CuO and ZnO-CuO composite nanostructures prepared from eggshell membranes

Authors: Preda, N; Costas, A; Enculescu, M; Enculescu, I

Published: JAN 15 2020, MATERIALS CHEMISTRY AND PHYSICS, 240, DOI: 10.1016/j.matchemphys.2019.122205

Three-dimensional (3D) fibrous networks based on metal oxides were obtained by a bio-inspired approach: the replication of an ecological daily-waste, the eggshell membrane (ESM). The biomorphic process consists in the immersion of the ESM into aqueous solutions containing the metal salt precursors followed by the calcination of the metal ions impregnated ESM. Biomorphic ZnO, CuO and ZnO-CuO composite networks were obtained, their morphological, structural, compositional, optical, photocatalytical and electrical properties being evaluated. The scanning electron microscopy investigations proved that the hierarchical structure of the original organic template is perfectly replicated into inorganic architectures consisting of interconnected fibers containing metal oxide nanoparticles as building blocks. The photocatalytical properties of the metal oxide networks under solar simulator irradiation were tested through the degradation of methylene blue. Using Si/SiO2 patterned with interdigitated metallic electrodes as substrates during the calcination step, the electrical properties of the selfcontacted metal oxide networks were investigated. Thus, by replicating the unique architecture of the ESM, 3D metal oxide interwoven meshwork can be easily developed for various applications in fields such as photocatalysis, sensing, optoelectronic devices, etc.

21. Unidirectional Magnetic Anisotropy in Dense Vertically-Standing Arrays of Passivated Nickel Nanotubes

Authors: Locovei, C; Filipoiu, N; Kuncser, A; Stanciu, AE; Antohe, S; Florica, CF; Costas, A; Enculescu, I; Piraux, L; Kuncser, V; Antohe, VA

Published: DEC 2020, NANOMATERIALS, 10, DOI: 10.3390/nano10122444

We report the facile and low-cost preparation as well as detailed characterization of dense arrays of passivated ferromagnetic nickel (Ni) nanotubes (NTs) vertically-supported onto solid Au-coated Si substrates. The proposed fabrication method relies on electrochemical synthesis within the nanopores of a supported anodic aluminum oxide (AAO) template and allows for fine tuning of the NTs ferromagnetic walls just by changing the cathodic reduction potential during the nanostructures' electrochemical growth. Subsequently, the experimental platform allowed further passivation of the Ni NTs with the formation of ultra-thin antiferromagnetic layers of nickel oxide (NiO). Using adequately adapted magnetic measurements, we afterwards demonstrated that the thickness of the NT walls and of the thin antiferromagneticNiO layer, strongly influences the magnetic behavior of the dense array of exchange-coupled Ni/NiO NTs. The specific magnetic properties of these hybrid ferromagnetic/antiferromagnetic nanosystems were then correlated with the morpho-structural and geometrical parameters of the NTs, as well as ultimately strengthened by additionally-implemented micromagnetic simulations. The effect of the unidirectional anisotropy strongly amplified by the cylindrical geometry of the ferromagnetic/antiferromagnetic interfaces has been investigated with the magnetic field applied both parallel and perpendicular to the NTs axis.

22. Synthesis of Core-Double Shell Nylon-ZnO/Polypyrrole Electrospun Nanofibers

Authors: Beregoi, M; Preda, N; Costas, A; Enculescu, M; Negrea, RF; Iovu, H; Enculescu, I

Published: NOV 2020, NANOMATERIALS, 10, DOI: 10.3390/nano10112241

Core-double shell nylon-ZnO/polypyrrole electrospun nanofibers were fabricated by combining three straightforward methods (electrospinning, sol-gel synthesis and electrodeposition). The hybrid fibrous organic-inorganic nanocomposite was obtained starting from freestanding nylon 6/6 nanofibers obtained through electrospinning. Nylon meshes were functionalized with a very thin, continuous ZnO film by a sol-gel process and thermally treated in order to increase its crystallinity. Further, the ZnO coated networks were used as a working electrode for the electrochemical deposition of a very thin, homogenous polypyrrole layer. X-ray diffraction measurements were employed for characterizing the ZnO structures while spectroscopic techniques such as FTIR and Raman were employed for describing the polypyrrole layer. An elemental analysis was performed through X-ray microanalysis, confirming the expected double shell structure. A detailed micromorphological characterization through FESEM and TEM assays evidenced the deposition of both organic and inorganic layers. Highly transparent, flexible due to the presence of the polymer core and embedding a semiconducting heterojunction, such materials can be easily tailored and integrated in functional platforms with a wide range of applications.

23. Ionophore- Nafion (TM) modified gold-coated electrospun polymeric fibers electrodes for determination of electrolytes

Authors: Aldea, A; Matei, E; Leote, RJB; Rau, I; Enculescu, I; Diculescu, VC

Published: DEC 10 2020, ELECTROCHIMICA ACTA, 363, 137239, DOI: 10.1016/j.electacta.2020.137239

The present work describes the electrochemical properties of ionophores immobilized at the surface of electrodes obtained from electrospun polymeric fibers, in order to develop sensors for the analysis of electrolytes. Poly(methyl methacrylate) submicrometer fibers were prepared by electrospinning, coated with a gold layer by magnetron sputtering and then transferred on polyethylene terephthalate (PET) in order to obtained flexible electrodes. The ionophores were immobilized at the surface of these electrodes by drop-casting a ionophore-Nafion mixed solution. The sensor surface was investigated by scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy in order to understand the morphology and distribution of a model Ca2+ ionophore over the electrode surface. Also, Fourier-transformed infrared spectroscopy was performed and demonstrated that the model Ca2+ ionophore can be immobilized in the nafion matrix maintaining its conformation, while cyclic voltammetry and electrochemical impedance spectroscopy demonstrated that the Ca2+ ionophore allows the diffusion of target ions through this this type of membrane. In order to prove the concept of ionophore-based sensors for the analysis of some electrolytes, Ca2+, NH4+, Cl- and H+ ionophore immobilized in a nafion matrix at the surface of these flexible electrodes were tested and the determination of the target ions performed by potentiometry in different media including artificial sweat. Finally, sensitivities, limits of detection, selectivity coefficients were determined. (C) 2020 Elsevier Ltd. All rights reserved.

24. Electrospun conductive gold covered polycaprolactone fibers as electrochemical sensors for O-2 monitoring in cell culture media

Authors: Serban, A; Evanghelidis, A; Onea, M; Diculescu, V; Enculescu, I; Barsan, MM

Published: FEB 2020, ELECTROCHEMISTRY COMMUNICATIONS, 111, DOI: 10.1016/j.elecom.2020.106662

This work reports the use of electrospun conductive gold covered polycaprolactone fibers for the quantification of dissolved O-2. The morphologies of the electrospun fibers obtained at a static and a dynamic drum collector were investigated by scanning electron microscopy. The reduction process of O-2 at negative potentials is analyzed by cyclic voltammetry and electrochemical impedance spectroscopy (EIS) in sodium phosphate buffer (NaPB) pH 7.0 and in cellular media pH 7.4. The electrochemical sensing performance of Au/PCL towards O-2 quantification in NaPB and cellular media is compared by using three electrochemical techniques: cyclic and linear sweep voltammetry and EIS. Measurements are done in a two electrode configuration, using a silver wire as reference, to show the applicability of the method for O-2 quantification in cellular culture media.

25. Core-shell nanowire arrays based on ZnO and CuxO for water stable photocatalysts

Authors: Florica, C; Costas, A; Preda, N; Beregoi, M; Kuncser, A; Apostol, N; Popa, C; Socol, G; Diculescu, V; Enculescu, I

Published: NOV 21 2019, SCIENTIFIC REPORTS, 9, DOI: 10.1038/s41598-019-53873-0

Staggered gap radial heterojunctions based on ZnO-CuxO core-shell nanowires are used as water stable photocatalysts to harvest solar energy for pollutants removal. ZnO nanowires with a wurtzite crystalline structure and a band gap of approximately 3.3 eV are obtained by thermal oxidation in air. These are covered with an amorphous CuxO layer having a band gap of 1.74 eV and subsequently form core-shell heterojunctions. The electrical characterization of the ZnO pristine and ZnO-CuxO core-shell nanowires emphasizes the charge transfer phenomena at the junction and at the interface between the nanowires and water based solutions. The methylene blue degradation mechanism is discussed taking into consideration the dissolution of ZnO in water based solutions for ZnO nanowires and ZnO-CuxO core-shell nanowires with different shell thicknesses. An optimum thickness of the CuxO layer is used to obtain water stable photocatalysts, where the ZnO-CuxO radial heterojunction enhances the separation and transport of the photogenerated charge carriers when irradiating with UV-light, leading to swift pollutant degradation.

26. Radial heterojunction based on single ZnO-CuxO core-shell nanowire for photodetector applications

Authors: Costas, A; Florica, C; Preda, N; Apostol, N; Kuncser, A; Nitescu, A; Enculescu, I

Published: APR 3 2019, SCIENTIFIC REPORTS, 9, DOI: 10.1038/s41598-019-42060-w

ZnO-CuxO core-shell radial heterojunction nanowire arrays were fabricated by a straightforward approach which combine two simple, cost effective and large-scale preparation methods: (i) thermal oxidation in air of a zinc foil for obtaining ZnO nanowire arrays and (ii) radio frequency magnetron sputtering for covering the surface of the ZnO nanowires with a CuxO thin film. The structural, compositional, morphological and optical properties of the high aspect ratio ZnO-CuxO core-shell nanowire arrays were investigated. Individual ZnO-CuxO core-shell nanowires were contacted with Pt electrodes by means of electron beam lithography technique, diode behaviour being demonstrated. Further it was found that these n-p radial heterojunction diodes based on single ZnO-CuxO nanowires exhibit a change in the current under UV light illumination and therefore behaving as photodetectors.

27. Palladium/palladium oxide coated electrospun fibers for wearable sweat pH-sensors

Authors: Diculescu, VC; Beregoi, M; Evanghelidis, A; Negrea, RF; Apostol, NG; Enculescu, I

Published: JUN 20 2019, SCIENTIFIC REPORTS, 9, DOI: 10.1038/s41598-019-45399-2

The work describes the development of a flexible, hydrogel embedded pH-sensor that can be integrated in inexpensive wearable and non-invasive devices at epidermal level for electrochemical quantification of H+ ions in sweat. Such a device can be useful for swift, real time diagnosis and for monitoring specific conditions. The sensors' working electrodes are flexible poly(methyl methacrylate) electrospun fibers coated with a thin gold layer and electrochemically functionalized with nanostructured palladium/palladium oxide. The response to H+ ions is investigated by cyclic voltammetry and electrochemical impedance spectroscopy while open circuit potential measurements show a sensitivity of aprox. -59 mV per pH unit. The modification of the sensing interface upon basic and acid treatment is characterized by scanning and transmission electron microscopy and the chemical composition by X-ray photoelectron spectroscopy. In order to demonstrate the functionality of the pH-sensor at epidermal level, as a wearable device, the palladium/palladium oxide working electrode and silver/silver chloride reference electrode are embedded within a pad of polyacrylamide hydrogel and measurements in artificial sweat over a broad pH range were performed. Sensitivity up to -28 mV/pH unit, response time below 30 s, temperature dependence of approx. 1 mV/degrees C as well as the minimum volume to which the sensor responses of 250 nanoliters were obtained for this device. The proposed configuration represents a viable alternative making use of low-cost and fast fabrication processes and materials.

28. Nanostructured palladium doped nickel electrodes for immobilization of oxidases through nickel nanoparticles

Authors: Barsan, MM; Matei, E; Enculescu, M; Costescu, R; Preda, N; Enache, TA; Enculescu, I; Diculescu, VC

Published: AUG 20 2019, ELECTROCHIMICA ACTA, 315, 113, DOI: 10.1016/j.electacta.2019.04.143

The present investigation deals with the development, characterization and application of nano-structured Pd doped Ni electrodes (Pd@Ni), which uses the electrochemical properties of Pd in synergy with the magnetic properties of Ni for biosensors development. The Pd@Ni electrodes have been characterized by X-ray diffraction, scanning electron microscopy with energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. It has been shown that palladium presented spherical assemblies ranging 150-200 nm medium diameter size that covers large areas of the electrode surface while metallic nickel, which confers magnetic properties, showed a uniform granular structure with sizes between 20 and 50 nm. Cyclic voltammetry and electrochemical impedance spectroscopy were performed to understand the electrochemical process at the Pd@Ni electrodes in neutral media. The Pd@Ni electrodes were applied for the electrochemical detection of H2O2. Finally, Ni nanoparticles (NiNP) functionalized with the model enzyme glucose oxidase (GOx-NiNP) have been attached to the Pd@Ni electrode solely through magnetic interactions, and the obtained GOx-NiNP/Pd@Ni biosensor applied for glucose determination in aqueous solutions by fixed potential amperometry at -0.05 V (vs Ag/AgCl) with reduced interferences. (C) 2019 Elsevier Ltd. All rights reserved.

29. Hierarchical functionalization of electrospun fibers by electrodeposition of zinc oxide nanostructures

Authors: Matei, E; Busuioc, C; Evanghelidis, A; Zgura, I; Enculescu, M; Beregoi, M; Enculescu, I

Published: NOV 15 2018, APPLIED SURFACE SCIENCE, 458, 563, DOI: 10.1016/j.apsusc.2018.06.143

Electrospun sub-micrometer polymer fiber mats represent an interesting substrate which can be employed as a transparent conducting electrode. Functionalization by using nanostructures represents a convenient way of increasing the range of applications. The present paper describes an electrodeposition process which can be applied for preparing ZnO nanostructures covered fibers in a straightforward manner. Poly(methyl methacrylate) fiber mats were obtained by electrospinning using metal frame collectors. Subsequent metallization by DC sputtering was used, these microstructured electrodes being thermally transferred onto glass substrates and further employed as working electrodes for the electrochemical deposition of ZnO. The transparency of the metal covered webs, a function of fiber density, is comparable to that of conventional transparent conductive oxides electrodes such as ITO. The same enhanced control of the ZnO electrodeposition process was observed for the case of the web electrodes as for the classic case of deposition on transparent conducting oxides or on metallic substrates. Structural, optical, morphological and wetting properties were investigated and correlated with the electrodeposition conditions. The photocatalytic properties of ZnO covered fibers were tested through the decomposition of methylene blue thin films under UV irradiation.

30. Flexible Delivery Patch Systems based on Thermoresponsive Hydrogels and Submicronic Fiber Heaters

Authors: Evanghelidis, A; Beregoi, M; Diculescu, VC; Galatanu, A; Ganea, P; Enculescu, I

Published: DEC 3 2018, SCIENTIFIC REPORTS, 8, DOI: 10.1038/s41598-018-35914-2

This paper proposes a novel, flexible, low cost administration patch which could be used as a non-invasive, controlled transdermal drug delivery system. The fabricated device consists in a flexible microfiber architecture heater covered with a thermoresponsive hydrogel, namely poly(N-isopropylacrylamide), as a matrix for the incorporation of active molecules. The manufacturing process consists of two main steps. First, the electrospun poly(methyl methacrylate) fiber networks are sputter coated with a thin gold layer and attached to flexible poly(ethylene terephthalate) substrates to obtain the heating platforms. Second, the heaters are encapsulated in poly(ethylene terephthalate) foils and covered with poly(N-isopropylacrylamide) hydrogel sheets. In order to illustrate the functionality of the fabricated patch, the hydrogel layer is loaded with methylene blue aqueous solution and is afterwards heated via Joule effect, by applying a voltage on the metalized fibers. The methylene blue releasing profiles of the heated patch are compared with those of the unheated one and the influence of parameters such as hydrogel composition and morphology, as well as the applied voltage values for microheating are investigated. The results indicate that the fabricated patch can be used as a drug administration instrument, while its performance can be tuned depending on the targeted application.

31. White-Light Emission of Dye-Doped Polymer Submicronic Fibers Produced by Electrospinning

Authors: Enculescu, M; Evanghelidis, A; Enculescu, I

Published: JUL 2018, POLYMERS, 10, DOI: 10.3390/polym10070737

Lighting and display technologies are evolving at tremendous rates nowadays; new device architectures based on new, microscopic building blocks are being developed. Besides high light-emission efficiencies, qualities including low cost, low environmental impact, flexibility, or lightweightness are sought for developing new types of devices. Electrospun polymer fibers represent an interesting type of such microscopic structures that can be employed in developing new functionalities. White-light-emitting fiber mats were prepared by the electrospinning of different dye-doped polymer solutions. Two approaches were used in order to obtain white-light emissions: the overlapping of single-dye-doped electrospun fiber mats, and the electrospinning of mixtures of different ratios of single-dye-doped polymer solutions. Scanning electron microscopy (SEM) was used to investigate the morphologies of the electrospun fibers with diameters ranging between 300 nm and 1 mu m. Optical absorption and photoluminescence (PL) were evaluated for single-dye-doped submicronic fiber mats, for overlapping mats, and for fiber mats obtained from different compositions of mixtures. Depending on the ratios of the mixtures of different dyes, the luminance was balanced between blue and red emissions. Commission Internationale de L'Eclairage (CIE) measurements depict this fine-tuning of the colors' intensities, and the right composition for white-light emission of the submicronic fiber mats was found.

32. Magnetism and magnetoresistance of single Ni-Cu alloy nanowires

Authors: Costas, A; Florica, C; Matei, E; Toimil-Molares, ME; Stavarache, I; Kuncser, A; Kuncser, V; Enculescu, I

Published: AUG 30 2018, BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 9, 2355, DOI: 10.3762/bjnano.9.219

Arrays of magnetic Ni-Cu alloy nanowires with different compositions were prepared by a template-replication technique using electrochemical deposition into polycarbonate nanoporous membranes. Photolithography was employed for obtaining interdigitated metallic electrode systems of Ti/Au onto SiO2/Si substrates and subsequent electron beam lithography was used for contacting single nanowires in order to investigate their galvano-magnetic properties. The results of the magnetoresistance measurements made on single Ni-Cu alloy nanowires of different compositions have been reported and discussed in detail. A direct methodology for transforming the magnetoresistance data into the corresponding magnetic hysteresis loops was proposed, opening new possibilities for an easy magnetic investigation of single magnetic nanowires in the peculiar cases of Stoner-Wohlfarth-like magnetization reversal mechanisms. The magnetic parameters of single Ni-Cu nanowires of different Ni content have been estimated and discussed by the interpretation of the as derived magnetic hysteresis loops via micromagnetic modeling. It has been theoretically proven that the proposed methodology can be applied over a large range of nanowire diameters if the measurement geometry is suitably chosen.

33. Versatile Actuators Based on Polypyrrole-Coated Metalized Eggshell Membranes

Authors: Beregoi, M; Preda, N; Evanghelidis, A; Costas, A; Enculescu, I

Published: AUG 2018, ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 6, 10181, DOI: 10.1021/acssuschemeng.8b01489

Eggshell membranes were employed as biological scaffolds for developing soft and versatile actuators. A particular architecture, consisting of eggshell membrane coated with polypyrrole, has been fabricated and has been found to be a green, inexpensive, lightweight, and easy to handle class of actuators. The polypyrrole-coated eggshell membrane devices were tested in liquid, ambient atmosphere and controlled humidity environment, with the recorded movements proving their versatility. In 1 M NaCl aqueous solution, by applying successive potential pulses, the actuator contracts/expands owing to the expulsion/insertion of the electrolyte ions out/into polypyrrole film, producing a displacement of similar to 0.1 cm. In air, upon application of voltages from 2 to 5 V on a V-shaped geometry actuator, it bends due to water desorption from its structure induced by Joule heating, generating a displacement which reaches similar to 0.4 cm at 5 V. In a chamber with controlled humidity, the decrease of humidity stimulates a bending/curling motion of the actuator, achieving a displacement of similar to 2.1 cm at 50% relative humidity. Upon modification of the humidity, these actuators move, hold, and release delicate and lightweight objects. Such polypyrrole-coated eggshell membrane actuators which operate in different environments and respond to multiple stimuli can have potential applications in biomimetic micromanipulators or artificial muscle fields.

34. A straightforward route to obtain organic/inorganic hybrid network from bio-waste: Electroless deposition of ZnO nanostructures on eggshell membranes

Authors: Preda, N; Costas, A; Beregoi, M; Enculescu, I

Published: AUG 16 2018, CHEMICAL PHYSICS LETTERS, 706, 30, DOI: 10.1016/j.cplett.2018.05.073

Bio-waste eggshell membranes (ESM) present a unique micro-architecture consisting in an interwoven fibrous network which can be functionalized with metal oxides resulting in hybrid materials. ESM were covered with ZnO nanostructures by electroless deposition using Au as catalyst. The structural, optical, morphological and wetting properties of the pristine ESM and ESM/ZnO were evaluated. The ESM fibers were uniformly coated by ZnO hexagonal prisms, the hybrid ESM/ZnO preserving the water absorption characteristic of the pristine ESM. Combining an abundant bio-waste with a simple wet chemical synthesis method, flexible organic/inorganic hybrid networks based on ZnO-functionalized ESM can be designed for various applications. (C) 2018 Elsevier B.V. All rights reserved.

35. ONE SIDE POLYANILINE COATED FIBERS BASED ACTUATOR

Authors: Beregoi, M; Evanghelidis, A; Ganea, P; Iovu, H; Matei, E; Enculescu, I

Published: 2017, UNIVERSITY POLITEHNICA OF BUCHAREST SCIENTIFIC BULLETIN SERIES B-CHEMISTRY AND MATERIALS SCIENCE, 79, 130, DOI:

In this study, one side aligned PANI coated micro-fibers were fabricated in order to develop a novel actuator configuration. Thus, electrospun PMMA fibers were coated only on one side with a thin gold layer guiding in this way the deposition of PANI (only on the side with gold considering an adequate PANI deposition time). Further, the half-metalized fibers were employed as working microelectrodes for electrochemical deposition of PANI. The prepared PANI coated fibers present actuation properties when they are in contact with an electrolyte like 1 M H2SO4. By switching the potential between +1.4 and -0.2 V, the fiber strips move due to the swelling/shrinking and anisotropic deposition of PANI film.

36. Polyaniline based microtubes as building-blocks for artificial muscle applications

Authors: Beregoi, M; Evanghelidis, A; Matei, E; Enculescu, I

Published: DEC 2017, SENSORS AND ACTUATORS B-CHEMICAL, 253, 583, DOI: 10.1016/j.snb.2017.06.128

Morphology is a key element in the functionality of low dimensional structures including here electroactive polymers, especially when applications such as muscle like actuators are sought. The reason is that morphology in the context of a high specific surface object strongly influences specific parameters such as ionic diffusion, conductivity and consequently the actuation capability of the system. In the present work a new architecture for microtube-based actuating elements is presented. Free-standing fibrillar microtubes with diameter in the range of micrometers and with a core-shell polyaniline/gold structure are fabricated through a scalable approach. Aligned electrospun poly(methyl methacrylate) fibers are coated with gold and are further employed as microstructured electrodes for the electrochemical deposition of polyaniline. Further the poly(methyl methacrylate) core was dissolved, leading to a tubular structure. The polyaniline/gold microtubes show complex, rapid and reversible movement patterns, with great stability and consistency over repeated actuation cycles. Thus, when the potential is swept between -0.2 and 1 V at different rates, the microtubes move, this movement being associated with the morphological and structural characteristics of the deposited polyaniline layer, a mechanism based on the expansion/contraction and conformational changes of the polymer chains due to the insertion/expulsion of ions. The response time of these electroactive microstructures during one cycle is in the range of seconds, a consequence of their low dimensionality and specific structure. Moreover the actuation takes place in different electrolytes including simulated gastric fluid, which enables a wide range of applications. (C) 2017 Elsevier B.V. All rights reserved.

37. Polypyrrole Actuator Based on Electrospun Microribbons

Authors: Beregoi, M; Evanghelidis, A; Diculescu, VC; Iovu, H; Enculescu, I

Published: NOV 1 2017, ACS APPLIED MATERIALS & INTERFACES, 9, 38075, DOI: 10.1021/acsami.7b13196

The development of soft actuators by using inexpensive raw materials and straightforward fabrication techniques, aiming at creating and developing muscle like micromanipulators, represents an important challenge nowadays. Providing such devices with biomimetic qualities, for example, sensing different external stimuli, adds even more complexity to the task. We developed electroactive polymer coated microribbons that undergo conformational changes in response to external physical and chemical parameters. These were prepared following three simple steps. During the first step nylon-6/6 microribbons were fabricated by electrospinning. In a second step the microribbons were one side coated with a metallic layer. Finally, a conducting layer of polypyrrole was added by means of electrochemical deposition. Strips of polypyrrole-coated aligned microribbon meshes were tested as actuators responding to current, pH, and temperature. The electrochemical activity of the microstructured actuators was investigated by recording cyclic voltammograms. Chronopontentiograms for specific current, pH, and temperature values were obtained in electrolytes with different compositions. It was shown that, upon variation of the external stimulus, the actuator undergoes conformational changes due to the reduction processes of the polypyrrole layer. The ability of the actuator to hold and release thin wires, and to collect polystyrene microspheres from the bottom of the electrochemical cell, was also investigated.

38. ZnO nanowires grown directly on zinc foils by thermal oxidation in air: Wetting and water adhesion properties

Authors: Florica, C; Preda, N; Costas, A; Zgura, I; Enculescu, I

Published: MAY 1 2016, MATERIALS LETTERS, 170, 159, DOI: 10.1016/j.matlet.2016.02.035

Large scale ZnO nanowire arrays were grown directly on zinc foils using the thermal oxidation in air method. The X-ray diffraction and reflectance investigations confirm that the as-grown nanowires properties are typical for ZnO having a hexagonal wurtzite crystalline structure and band-gap values between 3.2 and 3.3 eV. The scanning electron microscopy images prove that the density and the dimensions (diameter and length) of the ZnO nanowires can be tuned by controlling the oxidation temperature. Wettability studies reveal in the case of Zn foils a hydrophilic behavior with high water droplet adhesion which is transformed into a superhydrophobic one with low water droplet adhesion after the foils' surfaces are covered with ZnO nanowires. Obtaining functional surfaces with such interesting wetting properties using a simple, inexpensive and highly reproducible thermal oxidation in air technique is very attractive for anticorrosion coatings and self-cleaning applications. (C) 2016 Elsevier B.V. All rights reserved.

39. Direct and contactless electrical control of temperature of paper and textile foldable substrates using electrospun metallic-web transparent electrodes

Authors: Busuioc, C; Evanghelidis, A; Galatanu, A; Enculescu, I

Published: OCT 10 2016, SCIENTIFIC REPORTS, 6, DOI: 10.1038/srep34584

Multiple and complex functionalities are a demand nowadays for almost all materials, including common day-to-day materials such as paper, textiles, wood, etc. In the present report, the surface temperature control of different types of materials, including paper and textiles, was demonstrated by Joule heating of metallic-web transparent electrodes both by direct current and by RF induced eddy currents. Polymeric submicronic fiber webs were prepared by electrospinning, and metal sputtering was subsequently performed to transform them into flexible transparent electrodes. These electrodes were thermally attached to different substrates, including paper, textiles and glass. Using thermochromic inks, we demonstrated a high degree of control of the substrates' surface temperature by means of the Joule effect. Metallic fiber webs appear to be excellently suited for use as transparent electrodes for controlling the surface temperature of common materials, their highly flexible nature being a major advantage when dealing with rough, bendable substrates. This kind of result could not be achieved on bendable substrates with rough surfaces such as paper or textiles while employing classical transparent electrodes i.e. metal oxides. Moreover, contactless heating with induced currents is a premiere for transparent electrodes and opens up a score of new application fields.

40. Electrochromic properties of polyaniline-coated fiber webs for tissue engineering applications

Authors: Beregoi, M; Busuioc, C; Evanghelidis, A; Matei, E; Iordache, F; Radu, M; Dinischiotu, A; Enculescu, I

Published: AUG 30 2016, INTERNATIONAL JOURNAL OF PHARMACEUTICS, 510, 473, DOI: 10.1016/j.ijpharm.2015.11.055

By combining the electrospinning method advantages (high surface-to-volume ratio, controlled morphology, varied composition and flexibility for the resulting structures) with the electrical activity of polyaniline, a new core-shell-type material with potential applications in the field of artificial muscles was synthesized. Thus, a poly(methylmethacrylate) solution was electrospun in optimized conditions to obtain randomly oriented polymer fiber webs. Further, a gold layer was sputtered on their surface in order to make them conductive and improve the mechanical properties. The metalized fiber webs were then covered with a PANI layer by in situ electrochemical polymerization starting from aniline and using sulphuric acid as oxidizing agent. By applying a small voltage on PANI-coated fiber webs in the presence of an electrolyte, the oxidation state of PANI changes, which is followed by the device color modification. The morphological, electrical and biological properties of the resulting multilayered material were also investigated. (C) 2015 Elsevier B.V. All rights reserved.

41. High performance FETs based on ZnO nanowires synthesized by low cost methods

Authors: Florica, C; Costas, A; Kuncser, A; Preda, N; Enculescu, I

Published: NOV 25 2016, NANOTECHNOLOGY, 27, DOI: 10.1088/0957-4484/27/47/475303

Single ZnO nanowires prepared by wet and dry methods are used as channels in high performance back-gated field effect transistors working in low power operation mode, with on-off ratios up to 10(5) and mobilities up to 167 cm(2) V-1 s(-1). The nanowires' properties, generated by the growth techniques, influence the parameters of the transistors, therefore a throughout comparison is made.

42. Electrical properties of templateless electrodeposited ZnO nanowires

Authors: Matei, E; Costas, A; Florica, C; Enculescu, M; Pintilie, I; Pintilie, L; Enculescu, I

Published: FEB 2016, MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 42, 372, DOI: 10.1016/j.mssp.2015.11.007

Electrochemical deposition allows the preparation of ZnO nanostructures with precisely controlled morphology and properties, by finely tuning the process parameters. ZnO nanowires were deposited onto gold substrates by electrodeposition from a low concentration zinc nitrate bath Photolithography was employed for patterning interdigitated electrode systems onto silicon/silicon dioxide substrates and ZnO electrodeposition lead to wires connected to each other by bridging neighboring interdigits allowing electronic transport characterization. Optical measurements, i.e. reflection and photoluminescence spectroscopy, were performed and the results were correlated to electronic transport data. We found that we deal with a system for which one can apply a model of space charge limited currents with different traps energy distribution as a consequence of electrodeposition rate. Current versus temperature measurements show different behavior for lower and higher range of temperatures. Such nanowires, fabricated and contacted in a straightforward way, allow a wide area of applications ranging from conductometric bio- or chemo-sensors to optoelectronic devices. (C) 2015 Elsevier Ltd. All rights reserved.

43. Electrical properties of single CdTe nanowires

Authors: Matei, E; Florica, C; Costas, A; Toimil-Molares, ME; Enculescu, I

Published: FEB 12 2015, BEILSTEIN JOURNAL OF NANOTECHNOLOGY, 6, 450, DOI: 10.3762/bjnano.6.45

Ion track, nanoporous membranes were employed as templates for the preparation of CdTe nanowires. For this purpose, electrochemical deposition from a bath containing Cd and Te ions was employed. This process leads to high aspect ratio CdTe nanowires, which were harvested and placed on a substrate with lithographically patterned, interdigitated electrodes. Focused ion beam-induced metallization was used to produce individual nanowires with electrical contacts and electrical measurements were performed on these individual nanowires. The influence of a bottom gate was investigated and it was found that surface passivation leads to improved transport properties.

44. ELECTROSPRAYING OF ZnO MICROSTRUCTURES FOR ELECTRICAL CONTACTING

Authors: Costas, A; Florica, C; Evanghelidis, A; Enculescu, M; Preda, N; Enculescu, I

Published: OCT-DEC 2015, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 10, 1188, DOI:

ZnO complex microstructures were deposited onto interdigitated metallic electrodes by electrospraying. Simple methods, such as wet chemical precipitation and optical lithography, were used for the synthesis of flower-like and snowflake-like ZnO structures and for the preparation of interdigitated metallic electrodes, respectively. The electrosprayed ZnO particles preserve the structural, optical and morphological properties of the chemically synthesized ZnO powders. During the electrospraying process, the ZnO microstructures form bridges between the interdigitated metallic electrodes leading to electrical contacting. Changes in the electron transport through the ZnO microstructures are evidenced by their exposure to ammonia or their passivation with poly(methyl methacrylate). Merging such easy-scalable and low-cost techniques, devices based on electrosprayed complex ZnO structures can be designed.

45. Electrical properties of single CuO nanowires for device fabrication: Diodes and field effect transistors

Authors: Florica, C; Costas, A; Boni, AG; Negrea, R; Ion, L; Preda, N; Pintilie, L; Enculescu, I

Published: JUN 1 2015, APPLIED PHYSICS LETTERS, 106, DOI: 10.1063/1.4921914

High aspect ratio CuO nanowires are synthesized by a simple and scalable method, thermal oxidation in air. The structural, morphological, optical, and electrical properties of the semiconducting nanowires were studied. Au-Ti/CuO nanowire and Pt/CuO nanowire electrical contacts were investigated. A dominant Schottky mechanism was evidenced in the Au-Ti/CuO nanowire junction and an ohmic behavior was observed for the Pt/CuO nanowire junction. The Pt/CuO nanowire/Pt structure allows the measurements of the intrinsic transport properties of the single CuO nanowires. It was found that an activation mechanism describes the behavior at higher temperatures, while a nearest neighbor hopping transport mechanism is characteristic at low temperatures. This was also confirmed by four-probe resistivity measurements on the single CuO nanowires. By changing the metal/semiconductor interface, devices such as Schottky diodes and field effect transistors based on single CuO p-type nanowire semiconductor channel are obtained. These devices are suitable for being used in various electronic circuits where their size related properties can be exploited. (c) 2015 AIP Publishing LLC.

46. OPTICAL AND PHOTOCATALYTIC PROPERTIES OF ELECTROSPUN ZnO FIBERS

Authors: Busuioc, C; Evanghelidis, A; Enculescu, M; Enculescu, I

Published: JUL-SEP 2015, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 10, 965, DOI:

ZnO nanofibers were obtained by electrospinning a solution of zinc acetate dihydrate and polyvinylpyrrolidone in N, N-dimethylformamide, followed by calcination at 500, 650 or 800 degrees C for 1 h. X-ray diffraction, selected area electron diffraction, scanning electron microscopy, transmission electron microscopy, reflectance spectroscopy and photoluminescence spectroscopy were used for the characterization of the resulting fibers. The thermally treated samples exhibit ZnO single phase with polycrystalline hexagonal structure. The morphological investigation revealed an accentuated contraction process during calcination, as well as the increase of the crystallite size and the appearance of a breaking tendency with the calcination temperature enhancement. Both UV and Visible emissions under excitation at 350 nm were showed by the optical studies, which also led to band gap values slightly lower than those reported for similar one-dimensional nanostructures. In order to assess the photocatalytic activity of ZnO fibers, the photodegradation of methylene blue in aqueous medium (10(-3) M) under UV irradiation (368 nm) was analyzed.

47. Zinc oxide electroless deposition on electrospun PMMA fiber mats

Authors: Preda, N; Evanghelidis, A; Enculescu, M; Florica, C; Enculescu, I

Published: JAN 1 2015, MATERIALS LETTERS, 138, 242, DOI: 10.1016/j.matlet.2014.10.021

ZnO crystallites were grown by electroless deposition on poly(methyl methacrylate) (PMMA) fiber mats prepared by an electrospinning technique. The electroless deposition involves three steps: sensitization, activation and deposition, which were performed by subsequently dipping the PMMA fiber mats in the appropriate solutions. After the deposition the PMMA fibers are uniformly coated with ZnO prisms which show hexagonal wurtzite structure and optical signatures (band-gap value and emission bands) typical for this semiconductor. By combining electroless deposition and electrospinning, different semiconductor coated polymer fibers can be obtained for a wide range of applications. Both methods are appropriate for large scale production, being scalable, cheap, efficient and suitable for large-area covering techniques. (C) 2014 Elsevier B.V. All rights reserved.

48. Metallic Nanowires and Nanotubes Prepared by Template Replication

Authors: Matei, E; Enculescu, M; Preda, N; Florica, C; Costas, A; Busuioc, C; Molares, MET; Kuncser, V; Enculescu, I

Published: 2014, SIZE EFFECTS IN NANOSTRUCTURES: BASICS AND APPLICATIONS, 205, 165, DOI: 10.1007/978-3-662-44479-5_6

Low dimensional nanostructures represent a hot scientific field nowadays due mainly to the tremendous potential for applications. Low dimensions open the possibilities for both ultra-miniaturization and increase in functionality. Numerous procedures were developed for fabricating such nanostructures. Template replication represents a highly effective method in fabricating metallic nanowires and nanotubes. The approach is characterized by the excellent control in obtaining nano objects with the desired shape and dimensions. A large variety of templates are available ranging from viruses and proteins to nanoporous membranes fabricated by using swift heavy ion accelerators. In the following chapter the main steps involved in employing the method for fabricating metalic nanowires and nanotubes by replicating ion track nanoporous membranes were described. The steps include here membrane fabrication and replication and involve track etching and electrochemical metal deposition. The influence of the process parameters on the properties of the nanoobjects prepared by this approach was reviewed. It was found that simple experimental parameters can be chosen in such a way that the functionality of the nanowires or nanotubes can be finely tuned.

49. Polysaccharide-assisted crystallization of ZnO micro/nanostructures

Authors: Preda, N; Enculescu, M; Enculescu, I

Published: JAN 15 2014, MATERIALS LETTERS, 115, 260, DOI: 10.1016/j.matlet.2013.10.081

ZnO micro/nanostructures with complex morphology were synthesized by a simple chemical reaction between zinc nitrate and hexamethylenetetramine in the presence of polysaccharides. X-ray diffraction analysis showed that all obtained samples are of wurtzite structure. The reflectance and room temperature photoluminescence spectra have been used to investigate the optical properties of the ZnO structures. The scanning electron microscopy images reveal that the ZnO morphology (star, double-jellyfish, double-raspberry and edelweiss-flower) can be easily changed by varying the polysaccharides: sodium alginate, gum arabic and chitosan. The polysaccharide-assisted crystallization method could provide a facile approach to synthesize other desired compounds with controllable morphology. (C) 2013 Elsevier B.V. All rights reserved.

50. Field Effect Transistor with Electrodeposited ZnO Nanowire Channel

Authors: Florica, C; Matei, E; Costas, A; Molares, MET; Enculescu, I

Published: AUG 10 2014, ELECTROCHIMICA ACTA, 137, 297, DOI: 10.1016/j.electacta.2014.05.124

ZnO nanowires were prepared by electrochemical deposition in polycarbonate ion track templates. After the deposition process the polymer templates were dissolved in dichloromethane and the nanowires were harvested by ultrasonication in isopropyl. A droplet of nanowire suspension was placed on a Si/SiO2 substrate patterned with interdigitated electrodes. By means of electron beam lithography single nanowires were selected and provided with electrical contacts. We found that in order to obtain reliable electrical contacts and typical field effect characteristics the electrode deposition process needs to be adapted to the 3 D shape of the wires and that annealing and passivation treatments are necessary. (C) 2014 Elsevier Ltd. All rights reserved.

51. INFLUENCE OF PREPARATION STEPS ON THE PROPERTIES OF ELECTROSPUN ZnO FIBERS

Authors: Busuioc, C; Evanghelidis, A; Florica, C; Enculescu, I

Published: OCT-DEC 2014, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 9, 1578, DOI:

ZnO nanofibers were obtained by calcination of electrospun Zn(Ac)(2)center dot 2H(2)O/PMMA composite fibers and characterized by X-ray diffraction, scanning electron microscopy and photoluminescence spectroscopy. The thermal treatment led to polymer burning and polycrystalline hexagonal ZnO phase formation. The average fiber diameters range between 450 and 600 nm before calcination and 200 - 300 nm after calcination. PL investigation revealed a strong dependence of ZnO fibers emission band on the calcination temperature. Furthermore, electrical contacts were fabricated by photolithography and electric characteristics were measured.

52. Structural characteristics of iridium dual-emitter organometallic compound

Authors: Polosan, S; Ciobotaru, IC; Enculescu, I; Ciobotaru, CC

Published: DEC 14 2014, JOURNAL OF MATERIALS RESEARCH, 29, 2904, DOI: 10.1557/jmr.2014.337

By combining two types of ligands, phenylpyridine and quinoline, a new type of organometallic IrQ(ppy)(2) compound has been synthesized, which exhibits two phosphorescences: green and red. Using an appropriate catalyst, the final IrQ(ppy)(2) compound has a good chemical yield up to 60% and becomes a stable dual emitter at room temperature. This compound is important because it exhibits stable red emission which is limited by the quantum yield due to the low energy band gap. As a result, an overlap between the ground state and the excited state occurs due to the vibrations that increase the nonradiative transitions, destroying the red emissions. Structural characteristics of the IrQ(ppy)(2) powder reveal a triclinic structure confirmed by x-ray diffraction and scanning electron microscopy images. Thermal analysis of the final compound confirms a good stability against decomposition and structural changes up to 350 degrees C. X-ray photoelectron spectroscopy reveals Ir-O chemical bonds and several differences between the intermediate and final compounds, such as Ir-Cl bonds. Cathodoluminescence patterns show a phosphorescent triclinic structure with a higher efficiency for the red color. Backscattering electron images prove that there is a uniform distribution of iridium ions in the IrQ(ppy)(2) nanocrystals.

53. The Influence of the Microstructure and Morphology of CeO2 Buffer Layer on the Properties of YBCO Films PLD Grown on Ni Tape

Authors: Mihalache, V; Stefan, N; Enculescu, I; Mihailescu, IN; Socol, M; Miroi, M

Published: NOV 2014, JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM, 27, 2485, DOI: 10.1007/s10948-014-2679-9

YBa2Cu3O7-delta films were deposited on CeO2-buffered nickel substrates, with different buffer thickness. Full width at half maximum of rocking curve, Delta(omega), of CeO2 and yttrium barium copper oxide (YBCO), as well as the critical temperature, T-c, of YBCO were shown to be strongly dependent on buffer thickness. They behave similarly but not proportional to the buffer thickness increase. This and the fact that Delta(omega) vs. buffer thickness and T-c vs. buffer thickness for YBCO behave similar with RMS roughness vs. thickness of CeO2 indicates that the surface peculiarity of buffers is responsible for YBCO properties. More precisely, the surface of CeO2 films prepared by the chemical solution route based on propionic acid is prone to agglomerate (de-wet) and the degree of agglomeration depends in an intricate way on buffer thickness. We showed that nor RMS roughness neither (00l) texture degree can define alone the surface suitable for c-axis YBCO nucleation. The {111} faceted grains (even in the case of high (00l) texture) and other defects generated by agglomeration supply a low fraction of (00l) flat terminations of buffer that affect the nucleation of c-axis-oriented YBCO phase. Moreover, the thermal instability of the surface morphology of CeO2 buffers (further development of de-wetting process, {111} faceted grains, etc. during superconducting layer deposition) influence the quality of YBCO films.

54. DEPENDENCE ON THE DYE'S TYPE AND CONCENTRATION OF THE EMISSIVE PROPERTIES OF ELECTROSPUN DYE-DOPED BEADED NANOFIBERS

Authors: Enculescu, M; Evanghelidis, A; Busuioc, C; Florica, C; Costas, A; Oancea, M; Preda, N; Matei, E; Enculescu, I

Published: APR-JUN 2014, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 9, 816, DOI:

Luminescent polymer fibers were obtained by electrospinning solutions of 8% (in ethanol) polyvinylpyrrolidone (PVP) doped with three different dyes (coumarin 6, rhodamine 6G and sulforhodamine 101). Using the same parameters for the electrospinning process, nanofibers with diameters between 200 and 800 nm and different sizes and distributions of the beads were obtained as proven by scanning electron microscopy (SEM). We assessed the dependence of their emissive properties (intensity and wavelength) on the type of dye using photoluminescence (PL) spectra for the same concentration of the dopand dye (10(-3)M). Moreover, employing 4 different concentrations for coumarin 6 and rhodamine 6G (from 10(-3) to 10(-6) M) we evaluated the dependence with the concentration of the dye on the emissive properties of the electrospun dye-doped PVP nanofibers.

55. Superhydrophobic ZnO networks with high water adhesion

Authors: Florica, C; Preda, N; Enculescu, M; Zgura, I; Socol, M; Enculescu, I

Published: AUG 8 2014, NANOSCALE RESEARCH LETTERS, 9, DOI: 10.1186/1556-276X-9-385

ZnO structures were deposited using a simple chemical bath deposition technique onto interdigitated electrodes fabricated by a conventional photolithography method on SiO2/Si substrates. The X-ray diffraction studies show that the ZnO samples have a hexagonal wurtzite crystalline structure. The scanning electron microscopy observations prove that the substrates are uniformly covered by ZnO networks formed by monodisperse rods. The ZnO rod average diameter and length were tuned by controlling reactants' concentration and reaction time. Optical spectroscopy measurements demonstrate that all the samples display bandgap values and emission bands typical for ZnO. The electrical measurements reveal percolating networks which are highly sensitive when the samples are exposed to ammonia vapors, a variation in their resistance with the exposure time being evidenced. Other important characteristics are that the ZnO rod networks exhibit superhydrophobicity, with water contact angles exceeding 150 degrees and a high water droplet adhesion. Reproducible, easily scalable, and low-cost chemical bath deposition and photolithography techniques could provide a facile approach to fabricate such ZnO networks and devices based on them for a wide range of applications where multifunctionality, i.e., sensing and superhydrophobicity, properties are required.

56. Zinc Oxide and Polysaccharides: Promising Candidates for Functional Nanomaterials

Authors: Preda, N; Enculescu, M; Zgura, I; Socol, M; Florica, C; Evanghelidis, A; Matei, E; Enculescu, I

Published: 2014, SIZE EFFECTS IN NANOSTRUCTURES: BASICS AND APPLICATIONS, 205, 136, DOI: 10.1007/978-3-662-44479-5_5

Recently, ZnO and natural polysaccharides have received more and more attention as interesting components for designing complex functional nanomaterials, key elements being their high occurrence and low-cost. In this chapter are presented possibilities for tailoring the ZnO properties by using polysaccharides in the synthesis process as well as reports on the functionalization of cellulose-based natural fabrics with ZnO. In both cases, in the preparation step were used only simple and scalable wet chemical methods. The resulting materials with suitable characteristics, e.g. dependence of the ZnO nanostructures optical properties on their morphology or high-UV blocking and superhydrophobicity for ZnO-functionalized fabrics, can find applications in domains where such qualities are required.

57. Cu codoping control over magnetic precipitate formation in ZnCoO nanowires

Authors: Granville, S; Matei, E; Enculescu, I; Toimil-Molares, ME

Published: DEC 22 2014, APPLIED PHYSICS LETTERS, 105, DOI: 10.1063/1.4904987

Using electrodeposition, we have grown nanowires of ZnCoO with Cu codoping concentrations varying from 4-10 at. %, controlled only by the deposition potential. We demonstrate control over magnetic Co oxide nano-precipitate formation in the nanowires via the Cu concentration. The different magnetic behavior of the Co oxide nano-precipitates indicates the potential of ZnCoO for magnetic sensor applications. (C) 2014 AIP Publishing LLC.

58. Micropatterned ZnO rod arrays prepared by Au-catalyzed electroless deposition

Authors: Florica, C; Preda, N; Enculescu, M; Enculescu, I

Published: JUL 2014, PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 8, 652, DOI: 10.1002/pssr.201409089

Micropatterned ZnO was synthesized by an electroless deposition process using Au stripes as catalytic surfaces. The Au-patterned electrodes were prepared on SiO2/Si wafers using photolithography. The site-selective deposition of patterned ZnO hexagonal rod arrays is confirmed by scanning electron microscopy. The ZnO micropatterned surface revealed a conversion of wettability from hydrophilic to super-hydrophobic depending on the deposition reaction parameters. The electrical measurements carried out at room temperature before and after exposure to ammonia vapors of the patterned ZnO arrays show a resistance variation with exposure time. Highly reproducible, easy scalable and low-cost, photolithography and electroless deposition techniques could provide a facile approach to fabricate functionalized micropatterns, for a wide range of applications. (C) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

59. Influence of morphology on the emissive properties of dye-doped PVP nanofibers produced by electrospinning

Authors: Enculescu, M; Evanghelidis, A; Enculescu, I

Published: DEC 2014, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 75, 1371, DOI: 10.1016/j.jpcs.2014.07.008

Dye-doped polymer micro- and nanofibers with tailored light emission properties have great potential for applications in optical, optoelectronic, or photonic devices. In this study, these types of structures were obtained by electrospinning rhodamine 6 G-doped polyvinylpyrrolidone (PVP) using a polymer solution of 10% (mass) concentration in ethanol. Polymer nanofibers with different morphologies (smooth and beaded) and diameters of about 500 nm were obtained using different electrospinning conditions with the same solutions. Fluorescence optical microscopy observations showed that the dye was distributed uniformly in the doped PVP nanofibers. Different shifts were observed when we compared the wavelength of the dye emission band peak of the smooth nanofibers (566 nm) and the wavelength of the dye emission band peak of the beaded fibers (561.5 nm) produced by electrospinning in different conditions with the wavelength of the emission band peak for transparent thin films produced by spin coating (558 nm) using the same polymer solution. This demonstrates that it is possible to tune the optical properties of electrospun dye-doped polymer nanofibers simply by modifying the morphology of the material, i.e., the parameters of the electrospinning process. (C) 2014 Elsevier Ltd. All rights reserved.

60. Self-assembled homojunction In2O3 transparent thin-film transistors

Authors: Gherendi, F; Nistor, M; Antohe, S; Ion, L; Enculescu, I; Mandache, NB

Published: AUG 2013, SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 28, DOI: 10.1088/0268-1242/28/8/085002

Homojunction transparent thin-film In2O3 transistors were fabricated at room temperature. Self-assembled In2O3 source-channel-drain structures were grown by pulsed electron beam deposition using a shadow mask with a 300 mu m diameter wire as an obstacle placed at similar to 100 mu m distance from the substrate for growing the channel region behind it. The film resistivity varies from similar to 7 x 10(8) Omega cm in the channel region to similar to 10(-3) Omega cm in the source-drain regions. We explain this fact by the relative depletion of the indium incorporated in the channel region of the film due to the reduced flux of ablated species arriving on the substrate behind the obstacle, leading to a relative enrichment in oxygen compared to the source and drain regions. The gate insulator is a Y2O3 film grown by RF magnetron sputtering. The transistor operates in enhanced mode. The subthreshold swing is similar to 0.26 V/decade with an on/off current ratio of 1.5 x 10(7), and the saturation channel mobility is greater than 45 cm(2) V-1 s(-1).

61. Magnetic configurations of Ni-Cu alloy nanowires obtained by the template method

Authors: Matei, E; Enculescu, I; Toimil-Molares, ME; Leca, A; Ghica, C; Kuncser, V

Published: AUG 2013, JOURNAL OF NANOPARTICLE RESEARCH, 15, DOI: 10.1007/s11051-013-1863-3

High aspect ratio nanowires of Ni-Cu alloys have been synthesized by potentiostatic electrochemical deposition in etched ion-track membranes. The nickel-to-copper ratio in the nanowires was controlled via the deposition potential and electrochemical bath composition. We present a detailed study of nanowire properties including morphology, composition, and magnetic behavior. We report the magnetic configurations measured as function of the nanowire composition and discuss domain formation, anisotropy aspects, and local easy axis distributions.

62. Single bath electrodeposition of samarium oxide/zinc oxide nanostructured films with intense, broad luminescence

Authors: Matei, E; Enculescu, M; Enculescu, I

Published: APR 15 2013, ELECTROCHIMICA ACTA, 95, 178, DOI: 10.1016/j.electacta.2013.02.044

Electrochemical deposition from a solution containing zinc and samarium ions, leads to a samarium oxide/zinc oxide sandwich-like structure with an intense, visible, broad luminescence peak centered at 550 nm. The successive deposition of the two materials is related to the bath composition and overpotential, taking place for values higher than a certain threshold. The zinc oxide film, first one to be deposited, presents typical hexagonal prism morphology while samaria coating films present a porous, nanowall like structure. The photoluminescence emission is at least 10 times more intense than in the case of typical electrodeposited ZnO films of similar thickness and does not appear in Sm2O3 films electrodeposited from solutions containing only Sm ions. Samples prepared in different conditions were characterized from the point of view of composition, structure, morphology and optical properties. The characteristics of the emission spectra of the films make them interesting for solid state lightning applications. (c) 2013 Elsevier Ltd. All rights reserved.

63. Polymer Sphere Array Assisted ZnO Electroless Deposition

Authors: Preda, N; Enculescu, M; Enculescu, I

Published: JAN 1 2013, SOFT MATERIALS, 11, 464, DOI: 10.1080/1539445X.2012.693147

ZnO uniform films were deposited on polymer sphere arrays by an electroless technique. The low-dimensional ZnO particles were grown from an aqueous solution of zinc nitrate and dimethylamineborane. The X-ray diffraction studies demonstrate that the ZnO crystallites have a hexagonal wurtzite structure. The scanning electron microscopy images prove that ZnO hexagonal prisms are synthesized with a fairly uniform diameter of around 200 nm. From the contact angle measurements it was found that the electroless deposition on polymer sphere arrays of semiconductor hexagonal prisms leads to an improvement of ZnO hydrophobic properties.

64. MORPHOLOGY-CONTROLLED SYNTHESIS OF ZnO STRUCTURES BY A SIMPLE WET CHEMICAL METHOD

Authors: Preda, N; Enculescu, M; Florica, C; Costas, A; Evanghelidis, A; Matei, E; Enculescu, I

Published: OCT-DEC 2013, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 8, 1600, DOI:

Zinc oxide particles were synthesized by a simple wet chemical method. Using zinc nitrate and various precipitating agents, like KOH, NaOH and (CH2)(6)N-4, particles with different morphologies were obtained. Also, the addition of a structure-directing agent, like gum arabic - a highly branched biopolymer, leads to a decrease in the ZnO particles size (for KOH and NaOH) and to a dramatical change of the ZnO particle shape in the case of (CH2)(6)N-4. The X-ray diffraction analysis showed that all obtained samples are of wurtzite structure. The reflectance and photoluminescence spectra have been used to investigate the optical properties of the ZnO structures. The morphologies observed by scanning electron microscopy reveal snowflake-like, flower-like, star-like and double-raspberry-like structures. A possible formation mechanism for ZnO micro/nanostructures with different morphologies was proposed. The biopolymer-assisted crystallization method could provide a facile approach to synthesize other desired compounds with controllable morphology.

65. Superhydrophobic properties of cotton fabrics functionalized with ZnO by electroless deposition

Authors: Preda, N; Enculescu, M; Zgura, I; Socol, M; Matei, E; Vasilache, V; Enculescu, I

Published: FEB 15 2013, MATERIALS CHEMISTRY AND PHYSICS, 138, 261, DOI: 10.1016/j.matchemphys.2012.11.054

Cotton fabrics were coated with arrays of ZnO hexagonal prisms using an electroless (catalytic/auto-catalytic) deposition process. A typical three step method, similar to those used for electroless deposition of metals on insulating substrates, consisting of pre-activation, activation and deposition steps was employed. The low-dimensional ZnO particles were grown from an aqueous solution containing zinc nitrate as source of zinc ions and dimethylamineborane as reducing agent. The as-obtained ZnO-coated cotton fabrics were characterized from the point of view of structure by X-ray diffraction (XRD) and morphology by scanning electron microscopy (SEM). The XRD studies demonstrate that the ZnO particles have a hexagonal wurtzite crystalline structure. The SEM observations prove that the cotton fibers are homogeneously covered by hexagonal prisms which have uniform base size of approximately 500 nm and height of 1 mu m. Optical spectroscopy measurements show that the functionalization with ZnO strongly decreases the transmittance in the UV vis region of the cotton fabrics. An important characteristic is that the ZnO-functionalized cotton fabrics exhibit superhydrophobicity, with water contact angles exceeding 150 degrees. The technique described is highly reproducible, easy scalable and cheap, allowing a wide range of applications. (C) 2012 Elsevier B.V. All rights reserved.

66. SINGLE CRYSTAL ZnO NANOWIRE LUMINESCENCE SHIFTING BY NANOSTRUCTURED ZnO LAYERS

Authors: Marcu, A; Enculescu, I; Vizireanu, S; Birjega, R; Porosnicu, C

Published: APR-JUN 2013, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 8, 605, DOI:

Single crystal ZnO nanowires grown by pulsed laser deposition (PLD) and vapour-liquid-solid (VLS) technique respectively, were in-situ and ex-situ covered with additional ZnO shell layers. Luminescence investigation revealed significant luminescence spectra shift from UV to blue emission band of the obtained structures while changing the deposited shell layer film thickness. But with no monotone variation with the deposited film thicknesses. While the luminescence changes are generally considered as being determined by the ratio between core emission lines intensity and shell 'defects' lines intensity, the strongest changes in the photoluminescence spectra were obtained in our experiments for the nanometer order shell layer thicknesses. The comparison between luminescence results and luminescence studies on 50 nm ZnO nanoparticles clusterization, together with HRTEM investigations of the ZnO shell layer suggest that the nanoparticle-nanowire interface, respectively the coupling between the ZnO single crystal core and ZnO nanostructured shell layer, might play a significant role in the luminescence spectra changes.

67. Luminescent micro- and nanofibers based on novel europium phthalate complex

Authors: Enculescu, M; Preda, N; Matei, E; Enculescu, I

Published: SEP 14 2012, MATERIALS CHEMISTRY AND PHYSICS, 136, 58, DOI: 10.1016/j.matchemphys.2012.06.018

We synthesized by wet chemical route a novel europium-potassium phthalate complex Eu3+K+[(COO)(2)(C6H4)](2). The compound is a white powder insoluble in water. X-ray diffraction evaluation shows that we obtained a new crystalline compound with no traces of the starting materials (potassium hydrogen phthalate and europium chloride). Scanning electron microscopy reveals that the powder consists of fiber-shaped structures with sizes larger than 250 nm in diameter. Energy dispersive X-ray analysis proves that the compound has a 1:1 europium-potassium ratio. Fourier transform infrared spectroscopy confirms the presence of the phthalate in the new compound. Photoluminescence and cathodoluminescence measurements show that the fiber-shaped structures are intensely luminescent with emission bands corresponding to the D-5(0) -> F-7(J) (J = 1-4) Eu (III) ion's transitions in the region between 580 nm and 700 nm, the most intense maximum being observed around 615 nm. Up-converted luminescence with a maximum at 315 nm was recorded. (c) 2012 Elsevier B.V. All rights reserved.

68. ZnO Thin Films Deposited on Textile Material Substrates for Biomedical Applications ZnO Thin Films Deposited on Textiles

Authors: Duta, L; Popescu, AC; Dorcioman, G; Mihailescu, IN; Stan, GE; Zgura, I; Enculescu, I; Dumitrescu, I

Published: 2012, TECHNOLOGICAL INNOVATIONS IN SENSING AND DETECTION OF CHEMICAL, BIOLOGICAL, RADIOLOGICAL, NUCLEAR THREATS AND ECOLOGICAL TERRORISM, 210, DOI: 10.1007/978-94-007-2488-4_20

We report on the coating with ZnO adherent thin films of cotton woven fabrics by Pulsed laser deposition technique in order to obtain innovative textile materials, presenting protective effects against UV radiations and antifungal action.

69. Cathodoluminescence and Raman analysis of the finite-size effects in mer-Alq(3) structure

Authors: Radu, IC; Polosan, S; Enculescu, I; Iovu, H

Published: DEC 2012, OPTICAL MATERIALS, 35, 273, DOI: 10.1016/j.optmat.2012.08.017

As synthesized mer-Alq(3) powder, obtained by wet chemical synthesis, has been subjected to different new characterization techniques such as Energy Dispersive X-ray, Cathodoluminescence and Scanning Electron Microscopy in order to identify their structural and photophysical properties. Other common techniques like X-ray diffraction, Raman and Fourier Transform Infrared spectroscopy have been involved in order to prove the formation of mer-Alq(3) compound. The vibrational spectroscopic properties were interpreted by using the output files from Gaussian software with B3YLP functionals and 6-311(d) basic sets. The growth kinetic of mer-Alq(3) nanocrystals in the alpha-phase has been evaluated by using the finite-size effects based on the Raman position peaks and their linewidths, which confirms the semiconductor character of the mer-Alq(3) compound. The XRD results suggest that the isothermal annealing increases the mer-Alq(3) nanocrystals, which modify the regular shape of typical spectral parameters from Raman peaks. (C) 2012 Elsevier B.V. All rights reserved.

70. ZnO morphological, structural and optical properties control by electrodeposition potential sweep rate

Authors: Matei, E; Enculescu, M; Preda, N; Enculescu, I

Published: JUN 15 2012, MATERIALS CHEMISTRY AND PHYSICS, 134, 993, DOI: 10.1016/j.matchemphys.2012.03.101

ZnO films were electrodeposited from an aqueous nitrate bath on ITO/glass substrates. The process was performed not by the usual potentiostatic approach but by using potential ramps with different sweep rates. We tested these ramps in both directions i.e. either towards electronegative (direct) or electropositive (inverse) potential. As expected, the samples prepared in different deposition conditions show different morphology, different quality of crystalline structure and different optical properties. By employing inverse ramps we prepared films with high quality structural and optical properties. We assume that in these conditions the growth is followed by an etching process which preferentially removes the areas with high defect concentration and leads to the formation of hollow hexagonal prisms. (c) 2012 Elsevier B.V. All rights reserved.

71. Interaction of NaYF4:Er:Yb Nanoparticles with Phospholipid Monolayers as Models of Biological Membranes

Authors: Petrescu, L; Cinteza, O; Voiculescu, AM; Rosu, T; Enculescu, I; Matei, E; Georgescu, S; Birjega, R; Avram, S; Mihailescu, D

Published: SEP 2012, REVISTA DE CHIMIE, 63, 961, DOI:

Given the evolution of imaging techniques in the biomedical field is becoming more necessary to develop sensitive markers, less toxic and not least more economical. Upconverting luminescent nanocrystals doped with rare earth ions, excited in infrared and emitting in visible, are considered real concurrent to classical fluorescent markers, featuring a number of advantages in rapport with them. The aim of this study is to prepare NaYF4 nanoparticles doped with erbium and ytterbium for biological applications in bioimaging techniques. After synthesis, upconverting nano particles were coated with SiO2 for surface sealing and passivation. The nano particles were characterized by X-ray diffraction, luminescence spectroscopy, electronic microscopy and dynamic light scattering. The interaction of the nanoparticles with mimicking cell membrane models was studied. NaYF4 nanoparticles showed a good size distribution and good emission efficiency. The uncoated nanoparticles increase the fluidity of the lipid monolayer, while the effect of the silica coated nanoparticles is substantially reduced.

72. Synthesis of CdS nanostructures using template-assisted ammonia-free chemical bath deposition

Authors: Preda, N; Enculescu, M; Gherendi, F; Matei, E; Toimil-Molares, ME; Enculescu, I

Published: SEP 2012, JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 73, 1089, DOI: 10.1016/j.jpcs.2012.05.003

CdS micro- and nano-structures (micro/nanotubes and nanostructured films) were obtained by ammonia-free chemical bath deposition using polymer templates (ion track-etched polycarbonate membranes and poly(styrene-hydroxyethyl methacrylate) nanosphere arrays). The semiconductor structures were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), optical absorption, photoluminescence and electrical measurements. The diameters of CdS tubes are between 300 nm and few microns and the lengths are up to tens of micrometers. The SEM images prove that the CdS films are nanostructured due to the deposition on the polymer nanosphere arrays. For both CdS structures (tubes and films) the XRD patterns show a hexagonal phase. The optical studies reveal a band gap value of about 2.5 - 2.6 eV and a red luminescence at similar to 1.77 eV. A higher increase of conductivity is observed for illuminating the CdS nanostructured film when compared to the simple semiconductor film. This is a consequence of the periodic patterning induced by the polymer nanosphere array. (C) 2012 Elsevier Ltd. All rights reserved.

73. Post-synthesis Carbon Nanowalls Transformation under Hydrogen, Oxygen, Nitrogen, Tetrafluoroethane and Sulfur Hexafluoride Plasma Treatments

Authors: Vizireanu, S; Ionita, MD; Dinescu, G; Enculescu, I; Baibarac, M; Baltog, I

Published: APR 2012, PLASMA PROCESSES AND POLYMERS, 9, 370, DOI: 10.1002/ppap.201100153

Carbon nanowalls (CNWs) functionalization allows the tailoring of some of their properties after they have been synthesized. Herewith we report on post-synthesis CNWs functionalization by plasma treatments. Radiofrequency plasmas generated in hydrogen, oxygen, nitrogen, tetrafluoroethane, and sulfur hexafluoride admixed to argon, were used. The changes of morphology, structure, chemical composition were determined by SEM, FTIR, Raman Spectroscopy, specifically for each gas mixture. The results point out to the surface erosion, the functional groups attachment, or to thin film coverage of CNWs material. Such processes strongly influence the material properties, as exemplified by the wettability: superhydrophilic or superhydrophobic surfaces are obtained starting from the same base CNWs material.

74. PRODUCTION AND CHARACTERIZATION OF CdTe WIRE ARRAYS FOR HYBRID INORGANIC/ORGANIC PHOTOVOLTAIC CELLS

Authors: Florica, C; Arghir, I; Ion, L; Enculescu, I; Antohe, VA; Radu, A; Radu, M; Chisulescu, G; Dina, N; Antohe, S

Published: JAN-MAR 2011, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 6, 27, DOI:

A new approach for obtaining hybrid inorganic/organic photovoltaic structures, based on CdTe nanowires and organic dye films is reported. The wire arrays of CdTe (10(6) wires/cm(2)) were electrochemically grown using a template method. Ion track polycarbonate foils (30 micrometer thick) were used as templates and the growth conditions for obtaining good quality and stoichiometric CdTe nanowires were identified. After dissolving the polycarbonate template, a CdTe thin film (300 nm) has been deposited by thermal vacuum evaporation onto the wire array before the deposition of ZnPc film as organic absorber. Finally a ZnO thin film was deposited by Electron Pulsed Deposition on ZnPc, working as TCO top electrode. The structural, morphological, electrical and optical properties of each component layer are investigated. Typical parameters of the prepared photovoltaic structures are determined. The external quantum efficiency of the Au/wire array CdTe/CdTe(300 nm)/ZnPc/ZnO structures was significantly increased, with respect to that of Au/wire arrays CdTe/ZnPc/ZnO structures.

75. Electrodeposited ZnO films with high UV emission properties

Authors: Matei, E; Enculescu, I

Published: NOV 2011, MATERIALS RESEARCH BULLETIN, 46, 2154, DOI: 10.1016/j.materresbull.2011.04.025

We report here our results in the preparation of ZnO films with high UV band to band characteristic luminescence emission by potentiostatic electrodeposition. Zinc nitrate aqueous baths with different concentration and additives were employed for the preparation of the films on platinum substrates. We focused our research in determining how the electrodeposition bath composition, i.e. zinc nitrate concentration and addition of KCI or polyvinyl pyrolidone and applied overpotential influence the morphological and optical properties of the oxide films. Scanning electron microscopy was employed for characterizing the films in terms of morphology. Optical reflection, photoluminescence spectroscopy and cathodoluminescence were used for determining the optical characteristics of the samples. The morphology of the deposit varies from hexagonal prisms to platelets as a function of the deposition rate. This experimental parameter also influences the luminescence properties. We found that at low deposition rates high UV luminescent material is obtained. (C) 2011 Elsevier Ltd. All rights reserved.

76. Preparation of graphene and its application in dye-sensitized solar cells

Authors: Sima, M; Enculescu, I; Sima, A

Published: MAR 2011, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 5, 418, DOI:

Graphene sheets were prepared using electrochemical and chemical steps followed graphite electrochemical oxidation, graphite chemical oxidation, ultrasound expholiation and chemical reduction of carbon material. Films of graphene were electrophoretically deposited from aqueous dispersion on FTO electrode. These films were tested as cathode for a dye-sensitized solar cell. The morphology of the prepared products was imaged by scanning electron microscopy; the intermediate compound, graphene oxide was characterized by IR spectroscopy.

77. Effect of aqueous comonomer solubility on the surfactant-free emulsion copolymerization of methyl methacrylate

Authors: Preda, N; Matei, E; Enculescu, M; Rusen, E; Mocanu, A; Marculescu, B; Enculescu, I

Published: JAN 2011, JOURNAL OF POLYMER RESEARCH, 18, 30, DOI: 10.1007/s10965-009-9387-3

Surfactant-free emulsion copolymerization was used to prepare methyl methacrylate-hydroxyethyl methacrylate (MMA-HEA) and methyl methacrylate-hydroxypropyl methacrylate (MMA-HPMA) latex particles. Also, glycidyl methacrylate (GMA) was grafted onto the surface of the preformed MMA-HPMA latex particles by seeded surfactant-free emulsion copolymerization. The copolymerization reactions were conducted at 75 A degrees C using a water-soluble initiator, potassium persulfate (KPS). The morphologies of copolymer latex particles were observed using Scanning electron microscopy (SEM). The influence of different reactions parameters (the MMA saturation concentration (Sr), the KPS concentration and the aqueous solubility of the comonomers (HEA or HPMA)) on the particles average diameter and particles size dispersity was investigated. The experimental results showed that the increase of initiator concentration induces in all investigated cases the increase of particles average diameter, while the presence of HEA or HPMA as comonomers in the copolymerization reaction of MMA (1,000% Sr) lead to a decrease of particles average diameter. At small KPS concentration the latex is monodisperse, the increase of the initiator concentration leading to the formation of polydisperse latex. In the case of grafting reaction of GMA onto the monodisperse preformed MMA-HEA latex particles, although the average diameter of the final particles doubles the latex remains quasi-monodisperse.

78. Electrochemical Growth of Eosin Y/Manganese Doped ZnO as Hybrid Films and Nanowires

Authors: Sima, M; Visan, T; Matei, E; Ungureanu, F; Enculescu, I; Sima, M

Published: 2011, ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 225, 339, DOI: 10.1524/zpch.2011.0042

The electrodeposition process of Eosin Y/ZnO:Mn as films and nanowires performed using a solution containing zinc and manganese nitrates + lactic acid mixture was studied by linear voltammetry. The films and wires grown by polarization at -1.1 V/SCE electrode potential were characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and X-ray photoelectron spectroscopy (XPS). Additionally, the Eosin Y presence was evidenced by optical measurements as absorption and photoluminescence spectroscopy. The manganese content in films depends on the nature of support electrode used. On the other hand, the presence of Eosin Y species in the deposition bath increased significantly the manganese concentration in the ZnO:Mn nanowires electrodeposited at -1.1 V/SCE.

79. Radical modification of the wetting behavior of textiles coated with ZnO thin films and nanoparticles when changing the ambient pressure in the pulsed laser deposition process

Authors: Popescu, AC; Duta, L; Dorcioman, G; Mihailescu, IN; Stan, GE; Pasuk, I; Zgura, I; Beica, T; Enculescu, I; Ianculescu, A; Dumitrescu, I

Published: SEP 15 2011, JOURNAL OF APPLIED PHYSICS, 110, DOI: 10.1063/1.3639297

Cotton/polyester woven fabrics were functionalized with ZnO thin films or nanoparticles by pulsed laser deposition, using a KrF* excimer laser source. Depending on the number of applied laser pulses, well-separated nanoparticles (for 10 pulses) or compact thin films (for 100 pulses) were deposited. The synthesized nanostructures were evaluated morphologically by scanning electron microscopy and atomic force microscopy, physico-chemically by x-ray diffraction and functionally by the contact angle method. By modifying the ambient gas nature and pressure in the deposition chamber, hydrophilic or hydrophobic surfaces were obtained. When using an oxygen flux, both the deposited thin films and nanoparticles were hydrophilic. After deposition in vacuum, the nanoparticles were hydrophobic, but the thin films were super-hydrophobic. This radical modification of wetting behavior was assigned to the differences in microstructure features and surface electrical charging in the two cases. (C) 2011 American Institute of Physics. [doi:10.1063/1.3639297]

80. Upconversion luminescence of Er, Yb - doped nanolanganite powders synthesized by a citrate sol-gel method

Authors: Voiculescu, AM; Georgescu, S; Toma, O; Nastase, S; Birjega, R; Petrescu, L; Enculescu, I; Matei, E

Published: NOV 2011, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 5, 1173, DOI:

Langanite nanopowders doped with erbium and ytterbium were prepared by a citrate sol-gel method and annealed in air at various temperatures between 700 degrees C and 1000 degrees C. For annealing temperatures 900 degrees C and 1000 degrees C, part of the langanite transforms in perovskite (LaGaO(3)), as evidenced in XRD spectra. The reddish color of the powders due to color centers associated to oxygen defects intensifies with increasing annealing temperature. Green and red luminescence was obtained for IR (933 nm) pumping and only green for UV pump. The mechanisms involved in luminescence and energy transfer processes are presented and discussed.

81. Polymer-assisted crystallization of low-dimensional lead sulfide particles

Authors: Preda, N; Rusen, E; Enculescu, M; Matei, E; Marculescu, B; Enculescu, I

Published: AUG 2011, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 43, 1832, DOI: 10.1016/j.physe.2011.06.019

PbS micro- and nanoparticles were synthesized by a simple precipitation reaction of lead nitrate with thioacetamide in hydrosoluble polymer water solutions. The effects of four water soluble polymers: polyacrylamide (PAM), polyvinyl alcohol (PVA), polyethylene glycol (PEG) and poly-N-vinyl pyrrolidone (PVP) on the PbS crystallites morphology and structural properties were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD). It was found that for the PbS particles obtained in the PVA. PEG and PVP, the (2 0 0) diffraction peak of the nanocrystals becomes dominant. The highest texture in the [2 0 0] direction was observed for the crystallites obtained in the presence of PVP. Polydisperse PbS particles with cubic morphology and size ranging from 100 nm to several microns are obtained in the case of PAM and PEG. Monodisperse cubic PbS crystallites with an average size of 200 nm are formed in the presence of PVA and PVP. (C) 2011 Elsevier B.V. All rights reserved.

82. Tailoring immobilization of immunoglobulin by excimer laser for biosensor applications

Authors: Sima, F; Axente, E; Ristoscu, C; Mihailescu, IN; Kononenko, TV; Nagovitsin, IA; Chudinova, G; Konov, VI; Socol, M; Enculescu, I; Sima, LE; Petrescu, SM

Published: FEB 2011, JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 96A, 394, DOI: 10.1002/jbm.a.32991

The sheltered transfer and immobilization of rabbit anti-human antiserum immunoglobulin G (IgG) by matrix-assisted pulsed laser evaporation (MAPLE) are reported. The iced targets submitted to laser irradiation consisted of 0.2-2 mg/mL IgG blended or not with lipid (L-a-phosphatidylcholine dipalmitoyl) dissolved in distilled water-based saline buffer. Thin IgG coatings were obtained at room temperature onto glass, fused silica, or silicon substrates. Ten thousand subsequent laser pulses of 0.33, 0.5, or 0.67 J/cm(2) fluence were applied for the synthesis of each sample. Morphology and composition of the thin films were studied by optical, scanning, and atomic force microscopy and Fourier transformed infrared spectrometry. Optical labeling methods such as spectrofluorimetry and fluorescence microscopy were selected to verify the biosensor transduction principle because of their high sensitivity for detecting low amounts of antigen (IgG). Protein immobilization to the substrate surface was demonstrated for all obtained structures after immersion in the donkey anti-rabbit secondary antibody solution. The IgG transfer and immobilization onto substrates were improved by addition of lipid to MAPLE solutions. (C) 2010 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 96A: 384-394, 2011.

83. Highly adherent bioactive glass thin films synthetized by magnetron sputtering at low temperature

Authors: Stan, GE; Pasuk, I; Husanu, MA; Enculescu, I; Pina, S; Lemos, AF; Tulyaganov, DU; El Mabrouk, K; Ferreira, JMF

Published: DEC 2011, JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 22, 2710, DOI: 10.1007/s10856-011-4441-1

Thin (380-510 nm) films of a low silica content bioglass with MgO, B2O3, and CaF2 as additives were deposited at low-temperature (150A degrees C) by radio-frequency magnetron sputtering onto titanium substrates. The influence of sputtering conditions on morphology, structure, composition, bonding strength and in vitro bioactivity of sputtered bioglass films was investigated. Excellent pull-out adherence (similar to 73 MPa) was obtained when using a 0.3 Pa argon sputtering pressure (BG-a). The adherence declined (similar to 46 MPa) upon increasing the working pressure to 0.4 Pa (BG-b) or when using a reactive gas mixture (similar to 50 MPa). The SBF tests clearly demonstrated strong biomineralization features for all bioglass sputtered films. The biomineralization rate increased from BG-a to BG-b, and yet more for BG-c. A well-crystallized calcium hydrogen phosphate-like phase was observed after 3 and 15 days of immersion in SBF in all bioglass layers, which transformed monotonously into hydroxyapatite under prolonged SBF immersion. Alkali and alkali-earth salts (NaCl, KCl and CaCO3) were also found at the surface of samples soaked in SBF for 30 days. The study indicated that features such as composition, structure, adherence and bioactivity of bioglass films can be tailored simply by altering the magnetron sputtering working conditions, proving that this less explored technique is a promising alternative for preparing implant-type coatings.

84. THE INFLUENCE OF SYNTHESIS PARAMETERS ON SIZE AND MORPHOLOGY OF POLY(STYRENE-HYDROXYETHYL METHACRYLATE) COLLOIDS

Authors: Preda, N; Enculescu, M; Matei, E; Enculescu, I

Published: OCT-DEC 2010, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 5, 1065, DOI:

Poly(styrene-hydroxyethyl methacrylate) [P(ST-HEMA)] latex particles were prepared by surfactant-free emulsion copolymerization. As water-soluble initiator was used potassium persulfate (KPS). The influence of different reactions parameters, such as the reaction temperature, the both monomers (ST and HEMA) concentrations and the KPS concentration on the particles average diameter and particles size dispersion was investigated. Generally monodisperse spherical particles are synthesized, but we also obtained stable large three-dimensional colloidal aggregates. These are formed by the agglomeration of monodispersed spheres in certain polymerization conditions. The P(ST-HEMA) monodispersed spheres with 350 nm average diameter were assembled into colloidal crystals using dip-coating technique. Colloidal crystals with different thickness were obtained by modifying two experimental factors, the colloidal concentration and the substrate lifting speed. The morphologies of copolymer latex particles and colloidal crystals were observed using scanning electron microscopy (SEM). The optical properties of colloidal crystals films were also investigated by transmission spectroscopy.

85. EFFECTS OF PROTON IRRADIATION ON THE SPECTRAL PERFORMANCE OF PHOTOVOLTAIC CELLS BASED ON CdS/CdTe THIN FILMS

Authors: Ion, L; Enculescu, I; Iftimie, S; Ghenescu, V; Tazlaoanu, C; Besleaga, C; Mitran, TL; Antohe, VA; Gugiu, MM; Antohe, S

Published: AUG 2010, CHALCOGENIDE LETTERS, 7, 530, DOI:

Due to their physical and chemical properties (such as suitable band gaps, large absorption coefficients and good chemical stability) CdTe thin films are interesting for electronic and optoelectronic devices, including particularly photovoltaic cells for space technology. For that specific application, it is of prime importance to study in this type of materials the influence of ionizing radiations on their physical (structural, electrical and optical) properties. In this paper, the photovoltaic cells based on CdS/CdTe thin films, produced by thermal vacuum sublimation, were irradiated with 3 MeV protons at room temperature. The effects of irradiation were studied by investigating the changes in the electrical and optical properties of the cells. It was found that proton irradiation in the above mentioned conditions results mainly in the introduction of defects at the CdS/CdTe interface. A discussion about the possible origin of those defects is given.

86. SEQUENTIAL DEPOSITION OF MULTISEGMENT NANOWIRES

Authors: Matei, E; Preda, N; Enculescu, M; Ansermet, JP; Molares, MET; Enculescu, I

Published: OCT-DEC 2010, DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 5, 1076, DOI:

Electrochemical replication of nanoporous membranes represents a facile approach towards the fabrication of nanostructures with tailored properties. By the template method we prepared multisegment nanowires with tailored structure. The first step of the process was the fabrication of the nanoporous template by swift heavy ion irradiation and subsequent selective etching of the ion track. The next step was to fill the pores with the desired combination of materials. In this manner, by sequential electrodeposition steps of metal and semiconductor we prepared Ni - CdTe and Ni - ZnO - Ni nanowires.

87. Optical and morphologic properties of YVO4:Eu phosphor

Authors: Georgescu, S; Voiculescu, AM; Cotoi, E; Toma, O; Gheorghe, L; Achim, A; Matei, C; Enculescu, I; Matei, E; Osiac, M

Published: 2010, ROMOPTO 2009: NINTH CONFERENCE ON OPTICS: MICRO- TO NANOPHOTONICS II, 7469, DOI: 10.1117/12.866769

In this paper we present new results concerning the optical and morphologic properties of YVO4:Eu red nanophosphor prepared by a precipitation method and subsequently annealed in air at various temperatures. We monitored the morphologic changes induced by the thermal treatments using the optical spectroscopy (reflectance and luminescence spectra), XRD and electron microscopy. The annealing leads to an increase of the particle size and improvement of the order of the crystalline lattice of YVO4. The annealing at 800 degrees C produces the sample with the highest luminescence intensity.

88. Polymer-microporous host interactions probed by photoluminescence spectroscopy

Authors: Tiseanu, C; Parvulescu, VI; Cojocaru, B; Lorenz-Fonfria, VA; Kumke, M; Gessner, A; Enculescu, I

Published: 2010, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 12, 3037, DOI: 10.1039/b922591a

Zeolites NaY and ZSM-5 were used as hosts for styrene polymerization after ion-exchange with europium ions. The parent and hybrid, polystyrene coated Eu-NaY (Eu-NaY/PS) and Eu-ZSM-5 (Eu-ZSM-5/PS) zeolites were investigated by using thermal analysis, SEM, PXRD, FT-IR, DR-UV/Vis, steady state and time-resolved photoluminescence spectroscopy. FT-IR spectra evidenced for the interaction between the zeolitic hosts and polystyrene while the PXRD spectra supported for the presence of the polymer inside the channels/pores of Eu-NaY/PS and Eu-ZSM-5/PS materials. The optical properties of Eu-NaY/PS and Eu-ZSM-5/PS were significantly changed relative to those of the parent zeolites, giving further evidence for the presence of polymer inside zeolites. An interesting case is presented by NaY zeolite: following styrene polymerization, the polymer interacted selectively with one of the two main species co-existing inside zeolite while for ZSM-5 a similar effect was not observed.

89. Multisegment CdTe nanowire homojunction photodiode

Authors: Matei, E; Ion, L; Antohe, S; Neumann, R; Enculescu, I

Published: MAR 12 2010, NANOTECHNOLOGY, 21, DOI: 10.1088/0957-4484/21/10/105202

Electrochemical deposition in nanoporous ion track membranes is used for the preparation of multisegment CdTe-homojunction diode nanowires. Our study is based on the fact that the deposition overpotential strongly influences the composition of the compound semiconductor nanowires. Therefore, the transport behavior of the nanowire devices can be tailored by appropriately choosing a certain sequence of electrodeposition potentials. The wires were characterized using scanning electron microscopy, energy dispersive x-ray analysis, optical spectroscopy and x-ray diffraction. The current-voltage characteristics measured prove that, by appropriately choosing the voltage pulse pattern, one can fabricate nanowires with ohmic or rectifying behavior. The semiconducting nanowires are sensitive to light, their spectral sensitivity being characteristic of CdTe. The preparation of functional nanostructures in such a simple approach provides, as a major advantage, an increase in the process reproducibility and opens a wide field of potential optoelectronic applications.

90. Metal oxide nanoparticles synthesized by pulsed laser ablation for proton exchange membrane fuel cells

Authors: Dorcioman, G; Ebrasu, D; Enculescu, I; Serban, N; Axente, E; Sima, F; Ristoscu, C; Mihailescu, IN

Published: DEC 1 2010, JOURNAL OF POWER SOURCES, 195, 7780, DOI: 10.1016/j.jpowsour.2009.09.060

We report on the development of a modified gas diffusion layer for fuel cells consisting of a simple or teflonized carbon cloth pulsed laser deposited with metal oxide nanostructures designed to operate both as co-catalyst, and oxidic support for other electrochemically active catalysts. We selected TiO2, ZnO and Al2O3 doped (2 wt.%) ZnO which were uniformly distributed over the surface of gas diffusion layers in order to improve the catalytic activity, stability and lifetime, and reduce the production costs of proton exchange membrane fuel cells. We evidenced by scanning electron microscopy and energy dispersive spectroscopy that our depositions consisted of TiO2 nanoparticles while in the case of ZnO and Al2O3 doped (2 wt.%) ZnO transparent quasi-continuous films were synthesized. (C) 2009 Elsevier BM. All rights reserved.

91. Growth and Characterization of ZnO:Mn Submicron Wires via Electrodeposition from Nitrate-Lactic Acid Solution

Authors: Sima, M; Grecu, MN; Sima, M; Enculescu, I

Published: 2010, SEMICONDUCTORS, METAL OXIDES, AND COMPOSITES: METALLIZATION AND ELECTRODEPOSITION OF THIN FILMS AND NANOSTRUCTURES, 25, 171, DOI: 10.1149/1.3318515

Electrodeposition of manganese doped ZnO wires into polycarbonate membranes from an aqueous solution containing Zn(NO3)(2), Mn(NO3)(2) and lactic acid was investigated using linear sweep voltammetry and electrochemical impedance spectroscopy (EIS). The equivalent electrical circuits used for fitting experimental results were similar to those for characterization of metal/polymer coating systems. The precipitation of metal oxides in the pores of membrane used as template was observed at potentials between -0.9 and -1.15V/SCE. Morphology of the ZnO: Mn submicron wires arrays was observed by scanning electron microscopy and the Mn content of the obtained samples was measured by X-ray analysis. The submicron wires prepared at a potential of -1.1V/SCE have a composition expressed by the formula Zn0.97Mn0.03.

92. Investigations of the Correlation Between the Preparation Method and the Properties of Anilinic Derivative Functionalised Polymer Thin Films for Non-Linear Optical Applications

Authors: Stanculescu, A; Socol, M; Albu, AM; Rasoga, O; Stanculescu, F; Ionita, I; Enculescu, I

Published: 2010, ADVANCED MATERIALS FORUM V, PT 1 AND 2, 636-637, +, DOI: 10.4028/www.scientific.net/MSF.636-637.798

This paper presents a study of two copolymers, maleic anhydride and methylmethacrilate/maleic anhydride and vinyl benzyl chloride, functionalised with polar chromophoric groups such as 2,4 dinitroaniline. Thin films have been prepared by vacuum evaporation and spin coating methods on silicon and glass substrates. UV-VIS, FTIR, XRD and Photoluminescence Spectroscopy have been used to comparatively investigate the effect of the preparation method on the properties of the thin films obtained with functionalized copolymer. SEM has evidenced differences in the morphologies of the layers suggesting a degradation of the polymeric chain during the evaporation process to fragments that conserve unchanged the chromophoric group. This explains the presence of two types of non-linear phenomena, the second harmonic emission and two-photon luminescence emissions for both vacuum evaporated and spin coated films.

93. Synthesis and properties of poly(methyl methacrylate-2-acrylamido-2methylpropane sulfonic acid)/PbS hybrid composite

Authors: Preda, N; Rusen, E; Musuc, A; Enculescu, M; Matei, E; Marculescu, B; Fruth, V; Enculescu, I

Published: AUG 2010, MATERIALS RESEARCH BULLETIN, 45, 1012, DOI: 10.1016/j.materresbull.2010.04.002

The synthesis of a new hybrid composite based on PUS nanoparticles and poly( methyl methacrylate-2acrylamido-2-methylpropane sulfonic acid) [P(MMA-AMPSA)] copolymer is reported. The chemical synthesis consists in two steps: (i) a surfactant-free emulsion copolymerization between methyl methacrylate and 2-acrylamido-2-methylpropane sulfonic acid and (ii) the generation of PbS particles in the presence of the P( MMA-AMPSA) latex, from the reaction between lead nitrate and thiourea. The composite was studied by scanning electron microscopy (SEM), X-ray diffraction, FTIR spectroscopy, thermogravimetric analysis and differential scanning calorimetry. The microstructure observed using SEM proves that the PbS nanoparticles are well dispersed in the copolymer matrix. The X-ray diffraction measurements demonstrate that the PbS nanoparticles have a cubic rock salt structure. It was also found that the inorganic semiconductor nanoparticles improve the thermal stability of the copolymer matrix. (C) 2010 Elsevier Ltd. All rights reserved.

94. Cobalt-doped ZnO prepared by electrochemistry: Chemistry, morphology, and magnetism

Authors: Matei, E; Enculescu, I; Vasilache, V; Teodorescu, CM

Published: NOV 2010, PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 207, 2522, DOI: 10.1002/pssa.200925378

ZnO:Co thin films are prepared by electrochemical deposition at different overpotentials and investigated by scanning electron microscopy, optical spectroscopy, and cathodoluminescence, X-ray photoelectron spectroscopy and Kerr magnetometry (MOKE). An increase of structural disorder and crystallite reorientation are observed for cobalt-doped samples. MOKE magnetometry revealed room-temperature ferromagnetic behavior only for ZnO: Co deposited at -850 mV. These are the samples with the lower cobalt content and lowest structural perturbation of the ZnO matrix by cobalt. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

95. Optical properties of CdS electrodeposited nanowires

Authors: Matei, E; Preda, N; Enculescu, M; Sima, M; Sima, M; Enculescu, I

Published: OCT 2009, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 3, 1022, DOI:

Electrochemical deposition was performed in order to prepare CdS nanowires. The method employed for preparation of such high aspect ratio nanostructures was template replication. Ion track polycarbonate membranes were used as templates. The nanowires were studied by scanning electron microscopy (morphology characterization), energy dispersive X ray analysis (composition) and optical spectroscopy. Optical reflection spectroscopy was performed in order to determine the band gap value while photoluminescence spectroscopy was used for getting information regarding the point defects in the material.

96. Magnetic properties of NiCu thin films obtained by electrodeposition

Authors: Bazavan, D; Bazavan, R; Enculescu, I; Matei, E; Necula, C; Ion, L; Antohe, S

Published: MAY 2009, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 3, 488, DOI:

Using an electrochemical method have been produced NiCu thin films for magnetic applications. The recent development of first-order reversal curve (FORC) diagrams has allowed the detailed investigation of coercivity spectra, interaction and domain states of magnetic thin films. Their magnetic properties have been investigated by Micro Mag (TM) 3900 Vibrating Sample Magnetometer (VSM) and are discussed.

97. Cobalt doped ZnO prepared by electrochemistry: chemistry, morphology, and magnetism

Authors: Enculescu, I; Matei, E; Vasilache, V; Teodorescu, CM

Published: 2009, NANOTECH CONFERENCE & EXPO 2009, VOL 3, TECHNICAL PROCEEDINGS: NANOTECHNOLOGY 2009: BIOFUELS, RENEWABLE ENERGY, COATINGS FLUIDICS AND COMPACT MODELING, +, DOI:

ZnO:Co thin Films are prepared by electrochemical deposition at different overpotentials and investigated by scanning electron microscopy, X-ray photoelectron spectroscopy and Kerr magnetometry (MOKE). Increse of structural disorder and crystallite re-orientation are observed for cobalt doped samples (especially for those obtained at - 750 and at - 800 mV overpotentials). MOKE magnetometry revealed room temperature ferromagnetic behaviour only for ZnO:Co deposited at - 850 mV. These are the samples with the less cobalt content and lowest structural perturbation of the ZnO matrix by cobalt.

98. Influence of dye concentration on optical properties of rhodamine 6G doped KAP crystals

Authors: Enculescu, M; Matei, E; Preda, N; Enculescu, I

Published: NOV 2009, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 3, 1212, DOI:

Crystals of potassium acid phthalate (KAP) doped with rhodamine 6G (Rh 6G) were grown by slow evaporation method from aqueous solutions. Crystals of good optical quality suitable for optical applications were obtained. Different concentrations of rhodamine 6G (10(-5) M, 2x10(-5) M, 5x10(-5) M and 10(-4) M in the growth solutions) were used in order to tune the optical properties of the crystals. Depending of the dye concentration, the absorption spectra of the dye-doped crystals show several bands in the range between 360 nm and 526 nm. The photoluminescence of the KAP crystals induced by the dye-doping reveals two emission bands peaking at 540 nm and 560 nm.

99. Influence of Ionizing Radiations (Electrons and Gamma) on the Electrical Characteristics of LGS Resonators

Authors: Mateescu, I; Georgescu, S; Iliescu, B; Enculescu, I; Georgescu, R; Oproiu, C; Ghita, G

Published: 2009, FERROELECTRICS, 389, 31, DOI: 10.1080/00150190902987517

In this paper results concerning the changes of the electric characteristics of langasite resonators irradiated with electron and gamma rays are reported. For both electron and gamma irradiations the quality factor increases significantly, presumably due to the re-distribution of the point defects. Preliminary optical investigations in UV-VIS domain confirm the modification of defect structure.

100. Nanostructured Ferrite Formation in Borosilicate Glass

Authors: Sandu, V; Popa, S; Pasuk, I; Enculescu, I; Nicolescu, MS; Radicescu, S

Published: 2009, MULTI-FUNCTIONAL MATERIALS AND STRUCTURES II, PTS 1 AND 2, 79-82, +, DOI: 10.4028/www.scientific.net/AMR.79-82.445

We present the preparation, structural, and magnetic properties of a series of Fe-containing borosilicate glasses as a function of the ratio SiO2/Fe2O3 which is ranging from 1.49 to 2.68. The role of nucleators (Cr2O3 and P2O5) was also investigated. X-Ray diffraction has revealed the formation of magnetite as the major or unique crystalline phase. As SEM micrographs have revealed, the addition of P2O5 give rise to a finer structure as compared with Cr2O3. In addition, the same oxide decreases the temperature of structural transition with almost 100 degrees C. The magnetization data reveal a two step transition at low temperatures: a high temperature transition at T-v = 128 K, which we attribute to the Verwey transition, and a low temperature transition at T-s = 48 K which, most likely, is the result of change in the dynamic of the domain motion.

101. Optical properties of pulsed-laser deposited ZnO thin films

Authors: Bazavan, R; Ion, L; Socol, G; Enculescu, I; Bazavan, D; Tazlaoanu, C; Lorinczi, A; Mihailescu, IN; Popescu, M; Antohe, S

Published: APR 2009, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 11, 428, DOI:

ZnO thin films were deposited by pulsed laser deposition (PLD) technique on optical glass substrate. Structural analysis by X-ray diffraction revealed a wurtzite phase ZnO, highly textured, with (002) planes perpendicular to the growth direction. They were optically characterized by absorption and transmission spectrometry. The wavelength dependence of the refractive index was extracted from transmission data by using a numerical fitting procedure.

102. Transport properties of electrodeposited ZnO nanowires

Authors: Tazlaoanu, C; Ion, L; Enculescu, I; Sima, M; Enculescu, M; Matei, E; Neumann, R; Bazavan, R; Bazavan, D; Antohe, S

Published: MAY 2008, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 40, 2507, DOI: 10.1016/j.physe.2007.07.013

ZnO nanowires were electrodeposited by using a template approach. Ion track polycarbonate foils (30 mu m thick) were used as templates. Current-voltage (I-V) characteristics were recorded in the temperature range 40-300 K. I-V characteristics show a symmetric, non-linear shape, at temperatures greater than 240 K and voltages greater than 15 V. At lower temperatures, linear characteristics were recorded for the voltage range used. The temperature dependence of the electrical resistance is activated, with activation energy of 0.42 eV at temperatures greater than 240 K. (C) 2007 Elsevier B.V. All rights reserved.

103. Influence of polyvinylpyrolidone as an additive in electrochemical preparation of ZnO nanowires and nanostructured thin films

Authors: Enculescu, I; Matei, E; Sima, M; Enculescu, M; Sima, M; Ghica, C

Published: MAR-APR 2008, SURFACE AND INTERFACE ANALYSIS, 40, 560, DOI: 10.1002/sia.2749

Preparation of ZnO in different nano-morphological forms became a hot topic during the last few years. This tendency was motivated by the wide field of potential applications ranging from optics to electronics and spintronics. In the present work, we deal with the preparation of ZnO nanowires and nanostructured thin films using electrochemical deposition. ZnO nanowires were grown using the template approach, namely by replicating the nanopores of polycarbonate ion track membranes. The method yields uniform arrays of nanowires with the morphology controlled by the shape and size of the templates pores. Adding polyvinylpyrolidone as an additive in the growth bath became a necessity due to the fact that polycarbonate ion track membranes are usually hydrophobic and thus filling of the nanopores with the growth electrolyte is rather difficult. In order to better understand the influence of the additive on the electrochemical deposition of such nanostructures, similar experiments were performed for the deposition of ZnO thin films. Scanning electron microscopy, X-ray diffraction and optical spectroscopy measurements were performed for characterization of the deposited structures. Copyright (c) 2008 John Wiley & Sons, Ltd.

104. Effect of additives on nickel nanowires electrochemical deposition

Authors: Matei, E; Enculescu, I; Enculescu, M; Neumann, R

Published: MAR 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 511, DOI:

The paper presents the effect of additives on nickel nanowires preparation by employing a template approach. The nanostructures were obtained by electrochemical deposition in ion track nanoporous membranes. The main goal was to find a wetting agent which increases the pores filling efficiency. Due to the fact that the polycarbonate nanoporous membranes used as templates are strongly hydrophobic problems appear when filling the nanopores with the aqueous electrochemical baths. We found that polyvinylpyrrolidone (PVP) added in the bath improves membrane wetting, thus increasing the deposition efficiency up to 80%. Electrochemical polarization and chronoamperometry were employed for identifying and studying the processes which take place in the case of cathodic deposition of nickel nanowires. Scanning electron microscopy was employed for nanostructure morphology characterization.

105. Structural and photocatalytic properties of iron- and europium-doped TiO2 nanoparticles obtained under hydrothermal conditions

Authors: Diamandescu, L; Vasiliu, F; Tarabasanu-Mihaila, D; Feder, M; Vlaicu, AM; Teodorescu, CM; Macovei, D; Enculescu, I; Parvulescu, V; Vasile, E

Published: NOV 15 2008, MATERIALS CHEMISTRY AND PHYSICS, 112, 153, DOI: 10.1016/j.matchemphys.2008.05.023

Iron- and europium-doped (<= 1 at.%)TiO2 nanoparticles powders have been synthesized by a hydrothermal route at 200 degrees C, starting with TiCl4, FeCl3 center dot 6H(2)O and EuCl3 center dot 6H(2)O. The structure, morphology and optical peculiarities were investigated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), extended X-ray absorption fine structure (EXAFS), Mossbauer spectroscopy and UV-vis measurements. The photocatalytic performance was analysed in the photodegradation reaction of phenol. Rietveld refinements of XRD patterns reveal that the as-prepared samples consist in iron- and europium-doped TiO2 in the tetragonal anatase structural shape, with particle size as low as 15 nm. By means of Mossbauer spectroscopy on both Fe-57 and Eu-151 isotopes as well as by EXAFS analyses, the presence of Fe3+ and/or Eu3+ ions in the nanosized powders has been evidenced. It was found that iron and europium ions can substitute for titanium in the anatase structure. From the UV-vis reflection spectra, by using the transformed Kubelka-Munk functions, the band gap energy (E-g) of the hydrothermal samples has been determined in comparison with that of Degussa P-25 photocatalyst. A decrease of E-g from 2.9eV found for Degussa photocatalyst to 2.8 eV for the titania doped with 1 at.% Fe has been evidenced, indicating a valuable absorption shift (similar to 20 nm) towards visible light region. However, the best photocatalytic activity in the photodegradation reaction of phenol was evidenced for the hydrothermal sample, TiO2: 1 at.% Fe, 0.5 at.% Eu, in both UV and visible light regions. The photocatalytic activities of iron-doped and iron-europium-codoped samples are high and practically the same only in visible light. The photocatalytic properties in Correlation with the structural and optical peculiarities of the hydrothermal samples are discussed. (C) 2008 Elsevier B.V. All rights reserved.

106. Physical properties of CdTe nanowires electrodeposited by a template method, for photovoltaic applications

Authors: Ion, L; Enculescu, I; Antohe, S

Published: DEC 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 3246, DOI:

Nanowires made of CdTe were produced by using a template method. Polymer ion track foils (30 micrometers thick) were used as templates, after a proper chemical etching. Nanowires were electrochemically grown in the resulting pores. A discussion of the observed correlations between the morphological/structural properties of the wires and the growth conditions is given. Electrical properties of the arrays of nanowires were studied in the temperature range of 40 K - 300 K, after contacting them by sputtering a gold layer on top of the membranes. Symmetric, non-linear I-V characteristics were recorded in the voltage range used and an activated electrical resistance was observed in the ohmic regime.

107. PbSe nanowires grown by the template method

Authors: Sima, M; Enculescu, I; Sima, M

Published: 2008, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2, 70, DOI:

PbSe nanowires were prepared using the template method. Polycarbonate ion track membranes with pore sizes ranging between 50 nm and 1.5 mu m were used as templates. The deposition of PbSe in the pores of the template was performed electrochemically. The influence of the deposition potential and membrane porosity on the morphology and composition of the prepared nanowires was studied. The composition of the wires has been determined by EDX measurements for different potentials. Scanning electron microscopy revealed the morphology of the deposited nanowires. X ray diffraction has been used for structural measurements.

108. Preparation and Properties of Cobalt Doped ZnO Nanowires

Authors: Enculescu, I; Matei, E; Sima, M; Neumann, R; Granville, S; Ansermet, JP

Published: NOV 2008, IEEE TRANSACTIONS ON MAGNETICS, 44, 2680, DOI: 10.1109/TMAG.2008.2003242

The template method was used for preparing Zn1-xCoxO nanowires with x ranging from 0.01 to 0.05. Thus, electrochemical deposition was employed for filling up the pores of polycarbonate ion track nanoporous membranes with the desired material. The method allows a good control over the morphology and composition of the deposited nanowires, as evidenced by scanning electron microscopy (SEM) and energy dispersive X ray analysis (EDX). Measurements of the magnetic properties showed a paramagnetic behavior of the nanowire arrays for the whole set of temperatures and Co concentrations.

109. Optical spectroscopy of Yb2+ ions in YbF3-doped CaF2 crystals

Authors: Nicoara, I; Lighezan, L; Enculescu, M; Enculescu, I

Published: APR 2008, JOURNAL OF CRYSTAL GROWTH, 310, 2032, DOI: 10.1016/j.jcrysgro.2007.11.183

Transparent colorless Ca1-xYbxF2+x (X = 0-0007-0.016) crystals were grown using the vertical Bridgman technique. In order to obtain efficient Yb3+-Yb2+ conversion in the as-grown crystals, a special procedure has been developed. Room temperature optical absorption spectra reveal the characteristic UV absorption bands of the Yb2+ ions in the as-grown crystals, with intensities more than 10 times higher than those reported by other authors using various conversion procedures. The influence of YbF3 content and of codoping with Pb2+ ions on the absorption and emission spectra has been studied. Room temperature emission bands in the near UV (not reported before) and in the visible spectral domain have been observed. The emission intensity depends on the dopant concentration. A comparison of our results with those obtained by other authors is also given. (c) 2007 Elsevier B.V. All rights reserved.

110. Electrical properties of electrodeposited CdS nanowires

Authors: Ghenescu, M; Ion, L; Enculescu, I; Tazlaoanu, C; Antohe, VA; Sima, M; Enculescu, M; Matei, E; Neumann, R; Ghenescu, O; Covlea, V; Antohe, S

Published: MAY 2008, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 40, 2488, DOI: 10.1016/j.physe.2007.09.188

A template method was used to obtain cadmium sulfide (CdS) nanowires. Polymer ion tracks foils (30 mu m tick) were used as templates, after etching with solutions containing NaOH and methanol. CdS nanowires were electrochemically grown in the resulting pores. The nanowires were contacted by sputtering a gold layer on top of the membrane, and the electrical properties were recorded in the temperature range 40-300K. An activated electrical resistance was observed, with activation energy of 0.27eV at temperatures larger than 180 K. I-V characteristics show a symmetric, non-linear shape, in the voltage range used in this experiment. (C) 2007 Elsevier B.V. All rights reserved.

111. Luminescence and EPR study of ZnO : Mn : Cu nanowire array

Authors: Sima, M; Enculescu, I; Grecu, MN; Secu, M; Sima, M; Matei, E; Vasile, V

Published: MAY 2008, PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 40, 2498, DOI: 10.1016/j.physe.2007.08.075

We report on photoluminescence studies on manganese and copper-doped ZnO nanowire array prepared by template method. The ZnO:Mn:Cu semiconductor grown using the electrochemical technique was characterized by electron paramagnetic resonance (EPR) and optical reflection measurements. Morphology and the structure were observed by SEM and X-ray diffraction. The photoluminescence of this system was correlated with manganese and copper concentration in the ZnO matrix. (C) 2007 Elsevier B.V. All rights reserved.

112. Luminescence tuning of Si/SiO2 nanoparticles in aqueous solutions

Authors: Marcu, A; Sima, C; Grigoriu, C; Enculescu, I; Iliescu, B

Published: NOV 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 3134, DOI:

We investigated the possibility of tuning luminescent spectra for a given Si/SiO2 nanoparticle size distribution in aqueous solution. The luminescence spectra of Si/SiO2 Suspensions in aqueous solutions of different particle/cluster concentrations were studied. The different Si/SiO2 nanoparticle/cluster concentrations were produced by both centrifugation and dilution. Depending on the centrifugal force we found a reversible shift up to 100 nm toward UV, regardless of the excitation wavelength. The shift could be reverse by sonication of the sample. A-scenario based on particle and cluster size variation is also discussed.

113. Structural and morphological properties of NiCu magnetic thin films

Authors: Bazavan, D; Bazavan, R; Enculescu, I; Matei, E; Ion, L; Antohe, S

Published: NOV 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 3057, DOI:

NiCu thin films for magnetic applications have been produced by using an electrochemical method. Their structural and morphological properties have been investigated by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM and EDX) and are discussed in correlation with the growth conditions.

114. Nickel nanotubes prepared by electroless deposition in ion track templates

Authors: Enculescu, I; Sima, M; Enculescu, M; Matei, E; Molares, MET; Cornelius, T

Published: MAR 2008, OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2, 136, DOI:

Nickel nano- and micro- tubes were prepared by electroless deposition in ion track template membranes. By choosing the appropriate etching conditions membranes with cylindrical or conical pores were obtained allowing the preparation of cylindrical or conical tubules. The activation of the membranes was a two step process. The bath used for deposition was an acidic one. Typically for acidic bath deposition, by energy dispersive X ray analysis, a phosphorous content of up to 10 % was found in the deposit.

115. Electrochemical growth and characterization of nanostructured ZnO thin films

Authors: Ghica, C; Enculescu, I; Nistor, LC; Matei, E; Van Tendeloo, G

Published: DEC 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 3240, DOI:

ZnO is a wide band-gap (ca. 3.4 eV) semiconductor, piezoelectric, pyroelectric, biocompatible, transparent in the visible spectrum and UV light emitting material. The fabrication in 2001 of the first nanobelts of semiconductor oxide materials lead to a rapid expansion of researches concerning one dimensional nanostructures (nanotubes, nanowires, nanobelts), given their possible application in optics, optoelectronics, piezoelectricity, catalysis. Researches carried on up to date evidenced the possibility to obtain an extraordinary variety of ZnO nanostructures, in function of the experimental parameters and the used growth methods. In this work we present morphostructural results on nanostructured ZnO layers obtained by electrochemical deposition. The films have been grown on gold covered glass plates and Si wafers, in various experimental conditions such as: nature of the wetting agents, electrical polarization of the substrate (continuous, pulsed). The influence of the growth conditions on the crystalline structure and morphology of the films is revealed by scanning and transmission electron microscopy studies. The films show a variety of growth morphologies, from entangled-wires-like to honeycomb-like layers. These large-specific-surface layers will be tested as nanostructured substrates for photovoltaic cells with improved efficiency.

116. EIS studies of electrodeposition process of manganese and copper doped ZnO wires

Authors: Sima, M; Enculescu, I; Sima, M; Vasile, E; Visan, T

Published: MAR-APR 2008, SURFACE AND INTERFACE ANALYSIS, 40, 565, DOI: 10.1002/sia.2721

Electrodeposition of manganese- and copper-doped ZnO wires into polycarbonate membranes, from an aqueous solution containing 0.05 mol dm(-3) Zn(NO3)(2)+ 0.01 mol dm(-3) Mn(NO3)(2)+ 0.0005 mol dm(-3) Cu(NO3)(2)+ 0.0075 mol dm(-3) lactic acid, pH = 4.7 was investigated using linear sweep voltammetry and electrochemical impedance spectroscopy (EIS). The equivalent electrical circuits for fitting experimental results were similar to those for characterization of metal/polymer coating systems. impedance data and voltarnmetric curves showed that an increase of local pH due to reduction process of nitrate ions induces the co-precipitations of metal ions in the proximity of electrode as oxides. Copyright (c) 2008 John Wiley & Sons, Ltd.

117. Fractal characteristics of metal clusters self-assembled in alkali halide matrices

Authors: Enculescu, M; Enculescu, I

Published: 2007, PHYSICA STATUS SOLIDI C - CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 4, NO 3, 4, +, DOI: 10.1002/pssc.200673716

Metal nanoclusters of Ag and An were obtained in alkali halide crystals (NaCl, KBr and KCl). The fractal character of the structures is proved by the fractal dimensions calculated using a home made computer program. The self aggregation of the metallic structures is governed in both cases (Ag and Au) by the DLA mechanism. This is proved by the values of the fractal dimension calculated using two methods, sandbox and box-counting, which are between 1.7 and 1.8 for Ag and for Au between 1.7 and 1.9. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

118. Preparation of metallic nanowires with magnetic properties using the template method

Authors: Enculescu, I; Sima, M; Enculescu, M; Ghica, C; Enache, M; Neumann, R

Published: MAY 2007, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 9, 1470, DOI:

Metallic nanowires with magnetic properties were prepared by electrochemical deposition in nanoporous ion track membranes. Thus, we prepared Co-Cu alloy and Co/Cu multilayered nanowires. The technique allows the preparation of uniform arrays of parallel nanowires with desired properties. The process of electrochemical deposition of metals in nanoporous membranes was studied by means of cyclic voltammetry and impedance spectroscopy. The influences of deposition conditions such as bath composition, temperature and deposition potential on the morphological, structural and compositional properties of the nanowires were systematically studied.

119. Influence of geometrical properties on light emission of ZnO nanowires

Authors: Enculescu, I; Sima, M; Enculescu, M; Enache, M; Vasile, V; Neumann, R

Published: SEP 2007, OPTICAL MATERIALS, 30, 75, DOI: 10.1016/j.optmat.2007.01.002

The present paper deals with the preparation and study of optical properties of ZnO nanowires. Nanoporous ion track polycarbonate foils were used as templates for ZnO nanowires growth by electrochemical deposition. The growth was performed using an aqueous electrochemical bath at a temperature of 70 degrees C. SEM and TEM were employed to study the morphological properties of the nanowires. Electron diffraction was employed for structural characterization. Reflection and photoluminescence spectroscopy were used for optical characterization. A comparison between the properties of electrodeposited thin films and nanowires of ZnO was made from the point of view of photoluminescence properties. (c) 2007 Elsevier B.V. All rights reserved.

120. Micro and nanorods of alkali halides grown in polymer templates

Authors: Enculescu, M; Enculescu, I; Sima, M; Neumann, R; Trautmann, C

Published: MAY 2007, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 9, 1563, DOI:

Porous membranes containing cylindrical pores with diameters ranging from a few tens of nanometers to a few tens of micrometers were prepared by using the ion track technique. Swift heavy ions (e.g. Au with 11.4 MeV/nucleon specific energy) were used for creating the ion tracks in polycarbonate foils. Etching was performed using an aqueous solution of NaOH containing methanol. The growth of the alkali-halides micro- and nanorods was performed by evaporation from a saturated solution. The rods were imaged using scanning electron microscopy. The method opens up the possibility of growing nanostructures with applications as nanolaser media or nanoscintillators.

121. Deposition and properties of CdTe nanowires prepared by template replication

Authors: Enculescu, I; Sima, M; Enculescu, M; Enache, M; Ion, L; Antohe, S; Neumann, R

Published: MAY 2007, PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 244, 1611, DOI: 10.1002/pssb.200675109

We used the template method to prepare CdTe wires with diameters ranging from 80 nm to 1 mu m. As templates we used polycarbonate and polyethilene tereplitalate ion track membranes and as the method of filling the pores of such membranes we employed electrochemical deposition. The conditions (i.e. bath composition and deposition potential) necessary to obtain the stoichiometric composition of the semiconductor were found. Scanning and transmission electron microscopy were employed for morphological characterization of the nano and microwires. Energy dispersive X-ray analysis was employed for determining the Cd/Te ratio. Selected area electron diffraction was employed for structural measurements. Reflection spectroscopy measurements were performed on nanowire arrays for determining the band gap of the deposited nanostructures. (C) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

122. ZnO : Mn : Cu nanowires prepared by template method

Authors: Sima, M; Enculescu, I; Sima, M; Enache, M; Vasile, E; Ansermet, JP

Published: MAY 2007, PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 244, 1527, DOI: 10.1002/pssb.200675126

Manganese and copper doped ZnO films and nanowire arrays were prepared by cathodic electrodeposition from aqueous solution. The electrochemical process was examined by linear voltammetry and the morphology and the composition of obtained semiconductor were observed by SEM and EDX measurements. Optical absorption spectra indicated the presence of copper in ZnO: Mn: Cu nanowire arrays as Cu2+ ions. (c) 2007 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

123. Current perpendicular to plane single-nanowire GMR sensor

Authors: Enculescu, I; Toimil-Molares, ME; Zet, C; Daub, M; Westerberg, L; Neumann, R; Spohr, R

Published: JAN 2007, APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 86, 47, DOI: 10.1007/s00339-006-3738-2

By electrochemical deposition in a single nanopore membrane we fabricate Cu/Co layered single nanowires, that exhibit up to 10% magnetoresistance at room temperature. Single nanopore membranes are prepared by irradiating polycarbonate membranes with exactly one swift heavy ion, and by subsequent chemical etching of the single ion track. Both dc and pulsed electrodeposition of single wires consisting of Cu-Co alloy and Cu/Co multilayers respectively, are performed from a bath containing the two metal ions. By sputtering a gold electrode on the upper membrane surface, the single nanowire embedded in the flexible polymer foil is reliably contacted. While alloy wires exhibit anisotropic magnetoresistance (AMR), multilayer wires display current-perpendicular-to-plane giant magnetoresistance (CPP-GMR) behavior. This demonstrates that both the fabrication and contacting methods are very suitable for the investigation of transport properties, without the necessity of lithographic processes and without manipulation of the nanowires. In addition, the method opens up many new possibilities for single nanowire-based sensors.

124. Photosensitization of ZnO nanostructured thin films with organic dyes

Authors: Tazlaoanu, C; Ion, L; Socol, G; Socol, M; Mihailescu, IN; Stanculescu, F; Enculescu, I; Ionescu, F; Magherusan, L; Antohe, S

Published: MAY 2007, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 9, 1346, DOI:

We report in this contribution on the photosensitization effect of ZnO nanostructured thin films with copper-phthalocyanine (CuPc). ZnO films were prepared by pulsed laser deposition (PLD), on optical glass substrates, covered with 300 nm thick ITO films. The structure and morphology of ZnO films were optimized for photovoltaic-cell applications by controlling the growing conditions. ZnO films (wurtzite type) were (001) preferentially oriented in the growth direction. Organic dyes were vacuum sublimated on ZnO films, and subsequently a 300 nm thick copper film was vacuum sublimated on top of the structure, acting as an ohmic contact. Action spectra of ITO/ZnO/CuPc/Cu photovoltaic structures were recorded and a well defined response was observed in the range of absorption bands of organic dyes. The dark IN characteristics were also recorded, and electrical characterizations of the photovoltaic structures are given. The measured fourth quadrant IN characteristics under integral illumination (photoelement regime), allowed us to extract the typical photovoltaic cells parameters.

125. Semiconductor nanowires obtained by template method

Authors: Sima, M; Enculescu, I; Sima, M; Vasile, E

Published: MAY 2007, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 9, 1554, DOI:

One-dimensional structures having uniform diameters were prepared by electrochemical deposition using polycarbonate membranes as templates. Lead chalcogenides and ZnO tubes and rods growth processes were presented comparatively. The tendency of PbTe and PbSe semiconductors to grow as tubes both in membrane micro and nanopores was explained based on the absorption of lead ions on the pore wall.

126. Growth of ZnO micro and nanowires using the template method

Authors: Sima, M; Enculescu, I; Vasile, E

Published: APR 2006, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 8, 828, DOI:

The electrochemical deposition in ion track nanoporous membranes was employed for ZnO micro and nanowires preparation. A ZnNO3 bath was employed for the deposition, performed at -800 mV (vs. SCE) and at temperatures around 90 degrees C. Scanning and transmission electron microscopy were used to characterize the wires from a morphological point of view. Electron and X-ray diffraction were employed for the characterization of materials from the point of view of structure. The technique allowed the fabrication of nanowire arrays with good morphological and structural quality.

127. Magneto-sensitive nickel nanowires fabricated by electrodeposition into multi- and single-ion track templates

Authors: Ohgai, T; Enculescu, I; Zet, C; Westerberg, L; Hjort, K; Spohr, R; Neumann, R

Published: OCT 2006, JOURNAL OF APPLIED ELECTROCHEMISTRY, 36, 1162, DOI: 10.1007/s10800-006-9200-5

Polycarbonate templates of ( 30 +/- 1) mu m thickness containing cylindrical etched-track nanochannels of ( 500 +/- 50) nm diameter were used for electrodeposition of Ni nanowires. Using 10(4) channels per cm(2), the most favourable deposition potential of -1.0 V was determined in a potentiostatic mode by varying the deposition potential with respect to an Ag/AgCl reference electrode over a range between -0.1 V and -1.5 V. The deposition efficiency at -1.0 V was estimated around 10%. The resulting single wires had a resistance around 200 W and showed an anisotropic magnetoresistance (AMR) effect of 1%, applicable to directionally sensitive magnetic field sensors.

128. Fractal structures of gold obtained by diffusion limited aggregation in alkali halide crystals

Authors: Enculescu, M; Enculescu, I; Topa, V

Published: JUN 2006, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 8, 1233, DOI:

Nanostructures of gold embedded in potassium chloride matrices were obtained after the doped crystals growth, by electrolytical colouring, and by thermal treatment. When the TEM images of the nanostructures were analyzed using fractal geometry it means was proved that the self assembling of the metallic structures is governed by the diffusion limited aggregation (DLA) mechanism. The values of the fractal dimension, which were in all cases between 1.7 and 1.9, calculated using two methods, sandbox and box-counting, proved the DLA mechanism.

129. Absorption and photoluminescence properties of Cds : Mn2+: Cu+ nanostructures

Authors: Sima, M; Enculescu, I; Ghiordanescu, V; Mihut, L

Published: AUG 2005, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 7, 1955, DOI:

A layer of doped CdS nanocrystals was deposited on the surfaces of nanopores of polyethyleneterephtalate (PET) membranes. Optical absorption measurements were used to determine the bandgaps of the nanocrystals; CdS:Mn2+ and CdS:Mn2+:Cu+ show a blue and red shift, respectively, relative to the band gap of nanostructurated CdS. Photoluminescence spectra of the doped and undoped CdS samples exhibit wide bands covering the visible spectrum range.

130. Ni nanowires electrodeposited in single ion track templates

Authors: Daub, M; Enculescu, I; Neumann, R; Spohr, R

Published: APR 2005, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 7, 870, DOI:

30-mu m thick polycarbonate foils were irradiated with single swift heavy ions (,e.g. Au 11.4 MeV/nucleon). After etching with solutions containing NaOH and methanol, templates containing single conical pores were obtained. The size and the shape of the nanopores depend on etching conditions such as time of etching, concentration and temperature of the etching solution. By electrochemical deposition of nickel, nanowires were grown in the single pores. The nanowires were contacted by sputtering a gold layer on top of the membrane. The magnetic measurements indicated that the nanowires possess around 1% anisotropic magnetoresistance. The current-voltage characteristic of a Ni nanowire shows a linear behavior for current densities smaller than 10(8) A/cm(2). The maximum current density that a single Ni wire can withstand was found to be 3x 10(8) A/cm(2).

131. Photoluminescence of manganese- and copper-doped CdS nanowires

Authors: Ghiordanescu, V; Sima, M; Enculescu, I; Grecu, MN; Mihut, L; Secu, M; Neumann, R

Published: FEB 2005, PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 202, 454, DOI: 10.1002/pssa.200406927

Arrays of US: Mn2+ : Cu+ micro- and nanowires grown in polycarbonate ion-track templates exhibit photoluminescence in the spectral domain ranging from 500 to 800 mn at room temperature. A comparison with similar US and CdS:Mn2+ wire arrays is presented. The individual contributions to the emission spectra of Cu+ and Mn2+ ions in the US matrix are explained using their energy level schemes. Also SEM, EDX and EPR data are given or these wires. (c) 2005 WILEY-VCH Verlag GmbH A Co. KGaA, Weinheim.

132. Manganese and copper doped CdS nanowire arrays preparation

Authors: Sima, M; Enculescu, I; Ioncea, A; Visan, T; Trautmann, C

Published: DEC 2004, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 6, 1198, DOI:

Manganese and copper doped CdS nanowires were obtained by the template technique in a two step process. In the first step metallic alloy CdMnCu nano and microwires were electrodeposited in ion track membranes with pore diameters in the range 150 nm-2 mum. In the following step the resulted nanowires were anodized in a sodium sulphide alkaline solution. Electron microscopy results show participation of the whole metallic wire in the anodization process; manganese and copper doped CdS wires are obtained The composition of micro and nanowires was determined by energy dispersive X-ray analysis.

133. The electrodeposition of semiconductor nanowires with thermoelectric properties using "template" method

Authors: Sima, M; Enculescu, I; Visan, T

Published: OCT 2004, REVISTA DE CHIMIE, 55, 746, DOI:

A binary telluride (CdTe) as well as a ternary telluride (PbSeTe) were electrodeposited in the pores of a track-etched polycarbonate membrane, resulting nanowires and nanotubes. Either acid or alkaline solutions were used for preparing CdTe compound, whereas the ternary PbSe1-xTex compound was deposited from an acid solution, only. The investigation of electrode mechanisms was performed by cyclic voltammetry. The nanostructures were visualized using scanning electron microscopy (SEM).

134. Copper tubes prepared by electroless deposition in ion track templates

Authors: Bercu, B; Enculescu, I; Spohr, R

Published: OCT 2004, NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 225, 502, DOI: 10.1016/j.nimb.2004.06.011

Polycarbonate porous membranes were prepared by etching the ion tracks contained in foils irradiated in the fluence range of 1 ion/sample to 10(8) ions/cm(2). The membranes were used as templates for the preparation of tubes employing auto-catalytic copper deposition. A three-step process was used: pre-activation, activation and copper deposition. The deposition bath employed formaldehyde as reducing agent and tartrate as complexing agent. Copper nucleation was studied in order to optimize the activation steps thus allowing the preparation of thin tubes. The external diameters of the tubes ranged from 300 to 2000 nm. The inner diameters varied as a function of the time-of-exposure to the electroless bath. The length of the tubes was 30 mum, corresponding to the thickness of the foils. (C) 2004 Elsevier B.V. All rights reserved.

135. Electrochemical deposition of PBSe1-xTex nanorod arrays using ion track etched membranes as template

Authors: Sima, M; Enculescu, I; Visan, T; Spohr, R; Trautmann, C

Published: 2004, MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 418, 755, DOI: 10.1080/15421400490478885

Lead chalcogenides (PbS, PbSe, PbTe) are narrow band gap semiconductors which have been studied in the field of IR detection and thermoelectric devices. The template method is a general approach for synthesizing nanomaterials within the pores of membranes. The membranes employed contain cylindrical pores with monodisperse diameters, and corresponding cylindrical nanostructures are obtained. The aim of the present study was to prepare PbSe1-xTex nanorod arrays using electrodeposition. The process was investigated by cyclic voltammetry and electrochemical impedance spectroscopy. The resulted PbSe1-xTex nanostructures were characterized using scanning electron microscopy (SEM) as well as energy dispersive X-ray analysis (EDAX).

136. Electrodeposition of CdTe nanorods in ion track membranes

Authors: Sima, M; Enculescu, I; Trautmann, C; Neumann, R

Published: MAR 2004, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 6, 125, DOI:

CdTe nanowires were electrodeposited in ion track membranes with pore diameters in the range 100-2000 nm. Acidic and basic baths were tested for obtaining materials with good stoichiometry. The cyclic voltammograms were compared for the case of deposition on a carbon rotating disc and on the porous membrane substrates, the differences being attributed to the additional resistance induced by the pores. For larger pores a tendency of growing hollow structures was observed.

137. Copper nanowires electrodeposited in etched single-ion track templates

Authors: Enculescu, I; Siwy, Z; Dobrev, D; Trautmann, C; Toimil-Molares, ME; Neumann, R; Hjort, K; Westerberg, L; Spohr, R

Published: NOV 2003, APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 77, 755, DOI: 10.1007/s00339-003-2216-3

The replication of single-ion track templates opens up the possibility of accessing electrical properties of nanowires without using lithographic techniques. Polycarbonate foils of 30-mum thickness were irradiated with single swift heavy ions (e.g. An 11.4 or Xe 8.3 MeV/nucleon). By controlled one-sided etching of the damage trail caused by the ion, templates containing a single conical pore were prepared. The narrow pore openings had diameters down to 25 nm and opening angles up to 2degrees. By electrochemical deposition of copper, single conical wires were obtained. The electric current recorded during electrodeposition reflects the geometry of the pore. The wires were provided with electrical contacts. Current-voltage measurements confirmed that their resistance was ohmic. The wires could withstand a maximum current density above 10(8) A/cm(2).

138. A model for structures growth by sodium electrodiffusion in quartz crystals

Authors: Enculescu, I; Iliescu, B; Enculescu, M; Covalcica, I

Published: 2002, CRYSTAL RESEARCH AND TECHNOLOGY, 37, 874, DOI: 10.1002/1521-4079(200208)37:8<868::AID-CRAT868>3.0.CO;2-J

Dendritic structures were grown inside the quartz crystal by electrodiffusion of sodium ions from a NaCl layer at the anode. The electric field was applied along the optical axis Z and the structures were grown in the xy plane. An experimental arrangement using a pointed cathode and a graphite plate anode was employed. X ray diffraction analysis shows that the structures' chemical composition is a mixture of sodium silicates. To explain the structures' growth a model is proposed. The model is a bidimensional one. The transport of the particles along the Z axis structural channels by the electric field was taken into account by introducing a probability of generating the particles in the growth plane as a function of the distance to the cathode. The computer generated results and the experimental ones were compared and a good correlation was found.

139. Fractal patterns formed by thermal treatment in alkali halide crystals

Authors: Enculescu, M; Enculescu, I; Topa, V; Vasile, E

Published: NOV-DEC 2002, PHYSICA B-CONDENSED MATTER, 324, 392, DOI: 10.1016/S0921-4526(02)01451-5

We have succeeded in growing nanocrystals of Ag structured like fractals in several solid matrices (NaG, KBr and KCl). These are shown to be diffusion-limited aggregates when fractal dimensions were evaluated. Depending upon the crystal in which the fractal structures were obtained, the fractal dimensions of the Ag nanoclusters were found to be between 1.73 and 1.81. (C) 2002 Elsevier Science B.V. All rights reserved.

140. Chemical composition of structures obtained inside quartz crystals by sodium electrodiffusion

Authors: Iliescu, B; Enculescu, I; Pera, I; Alexe, G; Polosan, S; Stanculescu, A

Published: 2001, CRYSTAL RESEARCH AND TECHNOLOGY, 36, 410, DOI: 10.1002/1521-4079(200106)36:4/5<403::AID-CRAT403>3.0.CO;2-H

Dendritic structures were grown inside quartz crystals by electrodiffusion of sodium ions from a NaCl layer at the anode. An experimental arrangement using a point cathode and a graphite plate anode was employed. X-ray diffraction experiments were carried out, the structures chemical composition was found to be a mixture of sodium silicates. The chemical composition evolution in time was observed. There were made VIS and UV optical absorption spectroscopy measurements of these structures, a colloidal band being found. Thermoluminescence glow curves were measured. Based on the experimental results and observations a growth model is proposed.

141. Kinetics of silver structures growth by electrodiffusion in quartz crystals

Authors: Enculescu, I; Iliescu, B; Teodorescu, V

Published: JAN 2001, SOLID STATE IONICS, 138, 321, DOI: 10.1016/S0167-2738(00)00794-3

Silver layers were grown in quartz crystals by electrodiffusion from an anodic layer of AgNO3. Different experimental arrangements were employed in order to obtain such layers in a reproducible way. We performed DC ionic conductivity measurements on Z-cut and X-cut samples as a function of temperature in the heating up phase and as a function of time at the electromigration temperature. The metal structures and the quartz samples were analyzed by electron microscopy and electron diffraction. Based on the experimental results and on the observations a model, for the metal structure formation is proposed. (C) 2001 Elsevier Science B.V. All rights reserved.

142. DLA type metal structures in quartz crystals

Authors: Iliescu, B; Enculescu, I; Klapper, H; Stamatin, I

Published: MAY 1999, EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 6, 150, DOI: 10.1051/epjap:1999164

Metal structures of diffusion limited aggregation type were obtained by controlled electrodifussion in quartz crystal without macroscopic damages, Conditions of temperature, applied voltage and the form, shape and dimension of electrodes were found, in order to obtain fractal branches. Similarity with fractal DLA structures are described and discussed.

143. Growth of metal structures in quartz crystals by electrodiffusion

Authors: Iliescu, B; Enculescu, I; Vasiliu, F; Secu, M

Published: MAR 1999, JOURNAL OF CRYSTAL GROWTH, 198, 510, DOI: 10.1016/S0022-0248(98)01039-2

Metal structures in quartz crystals were obtained by electrodiffusion in air with different metal sources at the anode. The dynamics and the properties of these structures, for different conditions of temperature, applied electric field and anode material were studied. Current-voltage characteristics, Arrhenius plot, optical microscopy, electronic microscopy and thermoluminescence glow curve were employed. (C) 1999 Elsevier Science B.V. All rights reserved.

144. Current voltage characteristics of alpha-quartz

Authors: Enculescu, I; Iliescu, B

Published: JUN 1998, EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2, 207, DOI: 10.1051/epjap:1998185

Dc conductivity measurements for Z-cut natural quartz plates, at different temperatures and values of the applied electric field were made. The evolution of I-V characteristics shapes is studied for electrodiffusion times up to 100 h (in interstitial alkali ions transport region). The non-ohmic behavior is discussed and is considered to be due to the space charge produced by the uncompensated Al3+ ions substitutional for Si4+.

145. Ionic space charge limited currents in natural quartz crystal

Authors: Enculescu, I; Iliescu, B

Published: 1998, FIFTH CONFERENCE ON OPTICS (ROMOPTO '97), PTS 1 AND 2, 3405, 266, DOI: 10.1117/12.312762

Arrhenius plots and current-voltage characteristics were studied for natural quartz samples, in different conditions of air-sweeping time, of temperature, of electrodes (with or without any source of positive ions). Some observations about the influence of the ionic space charge limited current are made. Some dependencies of ionic current versus voltage were found.

146. Dynamics of the dauphine twins in quartz crystal up to the transition point

Authors: Iliescu, B; Enculescu, I; Chirila, R

Published: 1997, FERROELECTRICS, 190, 124, DOI: 10.1080/00150199708014103

The paper presents two original methods for obtaining electrical mins up to the transition point in quartz crystal: a) thermal treatment in a temperature gradient of 10-15 degree/cm at about 500 degrees C and b) applying an electric field of 1-4kV/cm at 500 degrees C. The twinning time dependence on the temperature. the dynamic of twin domain formation as a function of directions. thickness, temperature gradient, for +5X resonator plates are discussed. The influence of the Dauphine twins on the performances of piezoelectric resonators: resonant frequency, dynamic inductance and equivalent dynamic capacity was previously reported [1]. This paper presents the influence of twinning area on the frequency spectrum of a resonator plate of +5X-cut and the changing of the frequency-temperature characteristic when the resonator plate becomes twinned.

147. Electrical conductivity of quartz crystals

Authors: Enculescu, I; Iliescu, B

Published: 1997, CRYSTAL RESEARCH AND TECHNOLOGY, 32, 891, DOI: 10.1002/crat.2170320702

Dr. Ionut ENCULESCU

General Director

Projects

1. Biomimetic sensors based on high performance, nanowire channel field effect transistors

2. Spin and charge control in nanowire field effect transistors

3. High Efficiency Electrospinning

Publications

1. Palladium-Coated Submicron Electrospun Polymeric Fibers with Immobilized Uricase for Uric Acid Determination in Body Fluids

2. Palladium-Coated Submicron Electrospun Polymeric Fibers with Immobilized Uricase for Uric Acid Determination in Body Fluids

3. PEDOT:PSS based electrospun nanofibres used as trigger for fibroblasts differentiation

4. GRAPHENE FOR ELECTRONIC DEVICES - SYNTHESIS AND CHARACTERIZATION

5. Organic Light-Emitting Diodes with Electrospun Electrodes for Double-Side Emissions

6. Integrated architectures of electrodes and flexible porous substrates for point-of-care testing

7. Silver nanoparticles decorated ZnO-CuO core-shell nanowire arrays with low water adhesion and high antibacterial activity

8. Monodispersed nanoplatelets of samarium oxides for biosensing applications in biological fluids

9. Metallized electrospun polymeric fibers for electrochemical sensors and actuators

10. Self-connected CuO-ZnO radial core-shell heterojunction nanowire arrays grown on interdigitated electrodes for visible-light photodetectors

11. Direct and remote induced actuation in artificial muscles based on electrospun fiber networks

12. Charge transport mechanisms in free-standing devices with electrospun electrodes

13. Electrochemical Deposition of ZnO Nanowires on CVD-Graphene/Copper Substrates

14. Bioinspired polypyrrole based fibrillary artificial muscle with actuation and intrinsic sensing capabilities

15. Chemical sensing and actuation properties of polypyrrole coated fibers

16. Gold coated electrospun polymeric fibres as new electrode platform for glucose oxidase immobilization

17. Fabrication of ZnO and TiO2 Nanotubes via Flexible Electro-Spun Nanofibers for Photocatalytic Applications

18. Photodetecting properties of single CuO-ZnO core-shell nanowires with p-n radial heterojunction

19. Functionalization of eggshell membranes with CuO-ZnO based p-n junctions for visible light induced antibacterial activity against Escherichia coli

20. Biomorphic 3D fibrous networks based on ZnO, CuO and ZnO-CuO composite nanostructures prepared from eggshell membranes

21. Unidirectional Magnetic Anisotropy in Dense Vertically-Standing Arrays of Passivated Nickel Nanotubes

22. Synthesis of Core-Double Shell Nylon-ZnO/Polypyrrole Electrospun Nanofibers

23. Ionophore- Nafion (TM) modified gold-coated electrospun polymeric fibers electrodes for determination of electrolytes

24. Electrospun conductive gold covered polycaprolactone fibers as electrochemical sensors for O-2 monitoring in cell culture media

25. Core-shell nanowire arrays based on ZnO and CuxO for water stable photocatalysts

26. Radial heterojunction based on single ZnO-CuxO core-shell nanowire for photodetector applications

27. Palladium/palladium oxide coated electrospun fibers for wearable sweat pH-sensors

28. Nanostructured palladium doped nickel electrodes for immobilization of oxidases through nickel nanoparticles

29. Hierarchical functionalization of electrospun fibers by electrodeposition of zinc oxide nanostructures

30. Flexible Delivery Patch Systems based on Thermoresponsive Hydrogels and Submicronic Fiber Heaters

31. White-Light Emission of Dye-Doped Polymer Submicronic Fibers Produced by Electrospinning

32. Magnetism and magnetoresistance of single Ni-Cu alloy nanowires

33. Versatile Actuators Based on Polypyrrole-Coated Metalized Eggshell Membranes

34. A straightforward route to obtain organic/inorganic hybrid network from bio-waste: Electroless deposition of ZnO nanostructures on eggshell membranes

35. ONE SIDE POLYANILINE COATED FIBERS BASED ACTUATOR

36. Polyaniline based microtubes as building-blocks for artificial muscle applications

37. Polypyrrole Actuator Based on Electrospun Microribbons

38. ZnO nanowires grown directly on zinc foils by thermal oxidation in air: Wetting and water adhesion properties

39. Direct and contactless electrical control of temperature of paper and textile foldable substrates using electrospun metallic-web transparent electrodes

40. Electrochromic properties of polyaniline-coated fiber webs for tissue engineering applications

41. High performance FETs based on ZnO nanowires synthesized by low cost methods

42. Electrical properties of templateless electrodeposited ZnO nanowires

43. Electrical properties of single CdTe nanowires

44. ELECTROSPRAYING OF ZnO MICROSTRUCTURES FOR ELECTRICAL CONTACTING

45. Electrical properties of single CuO nanowires for device fabrication: Diodes and field effect transistors

46. OPTICAL AND PHOTOCATALYTIC PROPERTIES OF ELECTROSPUN ZnO FIBERS

47. Zinc oxide electroless deposition on electrospun PMMA fiber mats

48. Metallic Nanowires and Nanotubes Prepared by Template Replication

49. Polysaccharide-assisted crystallization of ZnO micro/nanostructures

50. Field Effect Transistor with Electrodeposited ZnO Nanowire Channel

51. INFLUENCE OF PREPARATION STEPS ON THE PROPERTIES OF ELECTROSPUN ZnO FIBERS

52. Structural characteristics of iridium dual-emitter organometallic compound

53. The Influence of the Microstructure and Morphology of CeO2 Buffer Layer on the Properties of YBCO Films PLD Grown on Ni Tape

54. DEPENDENCE ON THE DYE'S TYPE AND CONCENTRATION OF THE EMISSIVE PROPERTIES OF ELECTROSPUN DYE-DOPED BEADED NANOFIBERS

55. Superhydrophobic ZnO networks with high water adhesion

56. Zinc Oxide and Polysaccharides: Promising Candidates for Functional Nanomaterials

57. Cu codoping control over magnetic precipitate formation in ZnCoO nanowires

58. Micropatterned ZnO rod arrays prepared by Au-catalyzed electroless deposition

59. Influence of morphology on the emissive properties of dye-doped PVP nanofibers produced by electrospinning

60. Self-assembled homojunction In2O3 transparent thin-film transistors

61. Magnetic configurations of Ni-Cu alloy nanowires obtained by the template method

62. Single bath electrodeposition of samarium oxide/zinc oxide nanostructured films with intense, broad luminescence

63. Polymer Sphere Array Assisted ZnO Electroless Deposition

64. MORPHOLOGY-CONTROLLED SYNTHESIS OF ZnO STRUCTURES BY A SIMPLE WET CHEMICAL METHOD

65. Superhydrophobic properties of cotton fabrics functionalized with ZnO by electroless deposition

66. SINGLE CRYSTAL ZnO NANOWIRE LUMINESCENCE SHIFTING BY NANOSTRUCTURED ZnO LAYERS

67. Luminescent micro- and nanofibers based on novel europium phthalate complex

68. ZnO Thin Films Deposited on Textile Material Substrates for Biomedical Applications ZnO Thin Films Deposited on Textiles

69. Cathodoluminescence and Raman analysis of the finite-size effects in mer-Alq(3) structure

70. ZnO morphological, structural and optical properties control by electrodeposition potential sweep rate

71. Interaction of NaYF4:Er:Yb Nanoparticles with Phospholipid Monolayers as Models of Biological Membranes

72. Synthesis of CdS nanostructures using template-assisted ammonia-free chemical bath deposition

73. Post-synthesis Carbon Nanowalls Transformation under Hydrogen, Oxygen, Nitrogen, Tetrafluoroethane and Sulfur Hexafluoride Plasma Treatments