Publications

We propose a new laser configuration in which the pump radiation is coupled into the laser crystal through a prism. The laser medium is square shaped and the prism is attached on one of its lateral sides, near one of the crystal extremities. The diode-laser fiber end is placed close to the prism hypotenuse, the pump radiation is coupled into the laser crystal through the opposite surface of the prism and propagates into the crystal through total internal reflections. This laser geometry is simple to align and permits the realization of compact diode-pumped laser systems, as well as power scaling. A diode-pumped Nd:YAG laser yielding pulses of 2.1 mJ energy under a pump with pulses of 9.9 mJ is demonstrated. The laser slope efficiency is 0.22. Furthermore, this geometry enables one to obtain passively Q-switched lasers with the saturable absorber crystal placed between the resonator high-reflectivity mirror and the laser crystal. A Nd: YAG laser, passively Q-switched by a Cr4+:YAG crystal with initial transmission T-0 = 0.90, delivering laser output with a pulsed energy of 93 mu J, a duration of 26 ns and a pump threshold of 1.9 mJ, is realized in order to prove the concept.

The recent revolution in modern optical techniques revealed that light interaction with matter generates a force, known as optical force, which produces material properties known in physics as optical matter. The basic technique of the domain uses forces exerted by a strongly focused beam of light to trap small objects and subsequently to manipulate their local structures. The purpose of this paper is to develop an alternative approach, using irradiations with high-density-green-photons, which induce electric dipoles by polarization effects. The materials used for the experiments were long carbon chains which represent the framework of biological macromolecules. The physical techniques used to reveal the locally induced molecular arrangements were: dynamic viscosity, zeta potential, chemiluminescence, liquid chromatography; mass spectrometry, and Raman and infrared spectroscopy. The principal result of our experiments was the detection of different molecular arrangements within the mixture of alkane chains, generated by our optical manipulations. This induced "optical matter" displayed two material properties: antioxidant effects and large molecular aggregation effects. In order to bring the experimental results in relation with theory, we developed a physical model and the interacting force between polarizable bodies was computed. By numerical calculations stable structures for N = 6 and N = 8 particles were obtained.

Bi2O3 and Bi-metal powders were mixed with MgB2 powder. Starting compositions were (MgB2)(Bi2O3) x, x = 0.0025, 0.005, 0.015, and (MgB2)(Bi)(y), y = 0.01. Mixtures were processed by Spark Plasma Sintering (SPS) technique. As obtained composite samples show high density, above 94 % of the theoretical density. Samples with Bi2O3 for x = 0.0025 and 0.005 show higher critical current densities, J(c), at high fields and at 20 K than for the pristine sample. Their irreversibility field, H-irr, is also higher. On the other hand, sample added with Bi-metal has lower J(c) and H-irr at any temperature than for the pristine sample.

Monitoring the silver photodiffusion in thin amorphous As2S3 film is addressed with a new experimental setup. A possible photo-diffusion mechanism of silver into the a-As2S3 thin film under green laser diode light (=532nm) irradiation is proposed. The proposed mechanism is based on a gradual filling of the structural voids existing in the network of the thin chalcogenide layer. This mechanism is supported by XRD measurements, optical absorption, and modeling data.

Postsynthetic modification of [Cu2(mand)2(hmt)] (mand=mandelic acid, hmt=hexamethylenetetramine) with a chiral, dimeric chromium(III)salen complex led to a robust structure. Characterization of this new material showed that it perfectly preserved the textural and structural properties of the parent metalorganic framework (MOF). Although epoxidation of trans-methyl cinnamate with hydrogen peroxide led to copper leaching of 23%, experiments performed with N-methylmorpholine-N-oxide indicated no leaching, even after 72h of exposure. The obtained chiral MOF is an effective catalyst for the enantioselective epoxidation of trans-methyl cinnamate and leads to (2R,3S)-phenylglycidate with a high enantiomeric excess at room temperature.

Lead-free piezoelectric (Bi0.5Na0.5)(0.92)Ba0.08TiO3, (abbreviated as BNT-BT0.08) wires were prepared using its corresponding precursor sol and, a polycarbonate template membrane. The polycarbonate membrane used has a thickness of 30 mu m and pore diameter of 300 nm. Uniform surface morphology of the wires with average diameter of 145 nm and a length of about 20 mu m was obtained when the concentration of the sol was 0.3 M. The ferroelectric and piezoelectric properties of an individual BNT-BT0.08 wire were investigated using the PFM technique. The hysteresis loops between the PFM phase and DC bias and, the characteristic butterfly loops of the PFM amplitude versus DC bias, indicated a ferroelectric and piezoelectric behavior of as-obtained BNT-BT0.08 wires.

The topological transition from order to disorder in crystalline silicon was investigated by a computer simulation procedure. The gradually introduction of topological WootenWinerWeaire defect states makes the crystal change in a more and more disordered assembly of atoms. The characterization of deformation energy around a single defect state is analyzed. The topological transition from graphene structure to an amorphous carbon layer, by introduction of a high number of StoneWales defect-type states was evidenced. The comparison of the disordered structure in tetrahedrally bonded semiconductors (silicon) and a two-dimensional network based on graphene structure was made.

Cobalt environment and magnetic defects nature in hydrothermal synthesized anatase CoxTi1-xO2 nanopowders (0 <= x = 0.05, while the rest of the Co atoms gather into Co3O4 clusters. As found by electron paramagnetic resonance, the Co doping brings about hole-and electron-excess defects. (C) 2013 AIP Publishing LLC [http://dx.doi.org/10.1063/1.4802819]

Electrochemical deposition from a solution containing zinc and samarium ions, leads to a samarium oxide/zinc oxide sandwich-like structure with an intense, visible, broad luminescence peak centered at 550 nm. The successive deposition of the two materials is related to the bath composition and overpotential, taking place for values higher than a certain threshold. The zinc oxide film, first one to be deposited, presents typical hexagonal prism morphology while samaria coating films present a porous, nanowall like structure. The photoluminescence emission is at least 10 times more intense than in the case of typical electrodeposited ZnO films of similar thickness and does not appear in Sm2O3 films electrodeposited from solutions containing only Sm ions. Samples prepared in different conditions were characterized from the point of view of composition, structure, morphology and optical properties. The characteristics of the emission spectra of the films make them interesting for solid state lightning applications. (c) 2013 Elsevier Ltd. All rights reserved.

Arrays of microlenses have been created on the surface of thin amorphous films of As2S3 by localized photoexpansion induced by femtosecond laser pulses. The profile of a typical microlens has been mathematically described. Ray-tracing analysis has been performed to determine the focal points in the red and near-infrared spectrum of electromagnetic radiation. These lie at distances of 1.21m at =650nm and 1.33m at =1.5m above the top of the microlens. It is suggested that the microlenses could be used in two-dimensional optoelectronic circuits or in fibre optics.