Publications

Spectrophotometric behavior of riboflavin (RF) adsorbed on silver nanoparticles as well as its interaction with two serum albumins, BSA and HSA, respectively, has been evidenced. The time evolution of the plasmonic features of the complexes formed by RF/BSA/HSA and Ag(0) nanoparticles having an average diameter of 10.0 +/- 2.0 nm have been investigated by UV-Vis absorption spectroscopy. Using steady-state and time-resolved fluorescence spectroscopy, the structure, stability, and dynamics of the serum albumins have been studied. The efficiency of energy transfer process between RF and serum albumins on silver nanoparticles has been estimated. A reaction mechanism of RF with silver nanoparticles is also proposed and the results are discussed with relevance to the involvement of the silver nanoparticles to the redox process of RF and to the RF-serum albumins interaction into a silver nanoparticles complex.

Iron oxide nanoparticles (IONs) coated with different biological (dextran, sucrose) polymers have been synthesized by the coprecipitation method. Biological polymers coated iron oxide nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM). Zero field cooled and field cooled magnetizations measurements are also reported. We present a preliminary study of the influence of biological polymer on the interaction effects in powders. The temperature, T (max), of the maximum, increased from 25 K (dextran) to 52 K (sucrose). These values are due to the decrease of interparticle interactions, mainly as a result of the interparticle distance increase.

TiO2-Au aerogels containing different amounts of gold nanoparticles of different sizes (5 and 16 nm) were successfully synthesized using a sol-gel procedure, and were tested for salicylic acid photo-degradation under UV irradiation. The structure and morphology of the obtained materials were investigated using X-ray diffraction, transmission electron microscopy, and N-2 adsorption-desorption measurements. UV-Vis spectroscopy was used to study the optical properties. The effects of the gold nanoparticles on the TiO2 crystallization process were twofold, as follows: (i) the number of crystallized zones was strongly related to the concentration of the gold nanoparticles, and (ii) the smaller gold particles increased the time taken for the crystallization of the samples. It was found that the noble metal-doped samples exhibited higher degradation rates compared with bare titania. It was found that the most active photocatalyst in each studied system was the sample with the highest concentration of gold nanoparticles. Additionally, the highest degradation rate value was obtained with the smallest Au nanoparticles (46.4 x 10(-3) mu mol/(L.s). (C) 2013, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier By. All rights reserved.

We investigated the effect of tritium upload in the dense, polycrystalline MgB2 superconductor for 2 and 216 h. One basic property, the critical temperature T-c, slowly changes in time but is independent of the duration of tritium uptake. Immediately after tritiation, T-c shows a slight increase to 39.1 K but decreases to the critical temperature of the untritiated (pristine) sample, T-c = 38.8 K, after 370 days. The critical current density is strongly dependent on the tritium upload time, mainly at high magnetic fields. The underlying physics is discussed. This behaviour makes the use of MgB2 based conductors advantageous in tritium environments like fusion reactors.

The structure and electronic properties of the system resulted by epitaxial growth of a single atomic Au layer on a heated Ge(001) surface featured by (2 x 1) reconstruction are studied. The deposition at similar to 750 K results in a well-ordered Au surface featured by ripples separated by four times the theoretical distance between two neighboring Au atoms. As revealed by valence-band photoemission studies, the Au/Ge(001) system has metallic character. Correlating X-ray photoelectron spectroscopy results with first-principles calculations we derive the implications on the covalent bonding of Au on the Ge dimer surface. (C) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

The cryogenic detectors in the form of bolometers are presently used for different applications, in particular for very rare or hypothetical events associated with new forms of matter, specifically related to searches for dark matter. In the detection of particles with a semiconductor as target and detector, usually two signals are measured: ionization and heat. The amplification of the thermal signal is obtained with the prescriptions from the Luke-Neganov effect. The energy deposited in the semiconductor lattice as stable defects in the form of Frenkel pairs at cryogenic temperatures, following the interaction of a dark matter particle, is evaluated and consequences for measured quantities are discussed. This contribution is included in the energy balance of the Luke effect. Applying the present model to germanium and silicon, we found that for the same incident weakly interacting massive particle the energy deposited in defects in germanium is about twice the value for silicon. (C) 2013 Elsevier B.V. All rights reserved.

The specific topology of the line-centered square lattice (known also as the Lieb lattice) induces remarkable spectral properties such as the macroscopically degenerated zero-energy flat band, the Dirac cone in the low-energy spectrum, and the peculiar Hofstadter-type spectrum in a magnetic field. We study here the properties of the finite Lieb lattice with periodic and vanishing boundary conditions. We investigate the behavior of the flat band induced by disorder and external magnetic and electric fields. We show that in the confined Lieb plaquette threaded by a perpendicular magnetic flux there are edge states with nontrivial behavior. The specific class of twisted edge states, which have alternating chirality, are sensitive to disorder and do not support integer quantum Hall effect (IQHE), but contribute to the longitudinal resistance. The symmetry of the transmittance matrix in the energy range where these states are located is revealed. The diamagnetic moments of the bulk and edge states in the Dirac-Landau domain, and also of the flat states in crossed magnetic and electric fields are shown. DOI: 10.1103/PhysRevB.87.125428

The impact of non-resonant background emitters in semiconductor quantum-dot microcavity lasers is addressed within theoretical investigations based on the solution of the von Neumann equation. Off-resonant coupling between emitter resonances and the cavity mode is enabled via phonons, which are included in the von Neumann dynamics by an effective Lindblad contribution. The results show enhanced coherent emission from non-resonantly coupled quantum dots, while the frequently used phenomenological cavity feeding mechanism only enhances the thermal component of the emission.

Ex situ spark plasma sintering was used to obtain dense MgB2 co-doped with SiC and Te. The composition (MgB2) + (SiC)(0.025) + Te-0.01 shows critical current densities J(c)(20 K, 5 T) of 3.5 x 10(2) A cm(-2) and J(c)(5 K, 9 T) of 2 x 10(3) A cm(-2). These values are higher than for pristine samples or those separately doped with Te or SiC. They are also comparable at high fields and temperatures with the best reported values for the co-doped MgB2 bulks produced by conventional in situ methods. (C) 2012 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Over the last decade, field emission miniature x-ray tubes emerged as cutting-edge applications of nanotechnology, possessing massive potential for use in various important fields, including that of precision medical therapy. The article essentially presents a review of such new devices reported in the literature. Additional discussions on the necessity of stabilizing the electron beam that generates x-rays are also included, and a simple technique for minimizing the current fluctuations is described. It is also pointed out that further miniaturization of field emission x-ray sources may need new concepts in designing the tube in shapes acting as "self focusing" structures for the electron beams.