National Institute Of Materials Physics - Romania

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5781 articles found

3341. Measurement-induced decoherence in electronic interferometry at nanoscale

Authors: Moldoveanu, V; Tanatar, B; Tolea, M

Published: SEP 29 2008, PHYSICS LETTERS A, 372, 6196, DOI: 10.1016/j.physleta.2008.07.079

We introduce a theoretical formalism describing a wide class of 'Which Path' experiments in mesoscopic/nanoscopic transport. The physical system involves a mesoscopic interferometer (e.g. an Aharonov-Bohm ring with embedded dots or a side-coupled quantum dot) which is electrostatically coupled to a nearby quantum point constriction. Due to the charge sensing effect the latter acts as a charge detector. Therefore the interference pattern can be monitored indirectly by looking at the current characteristics of the detector as shown in the experimental work of Buks et al. [E. Buks, R. Schuster, M. Heiblum, D. Mahalu, V. Umansky, Nature (London) 391 (1998) 871]. We use the non-equilibrium Green-Keldysh formalism and a second order perturbative treatment of the Coulomb interaction in order to compute the relevant transport properties. it is shown that in the presence of the Coulomb interaction the current through the detector exhibits oscillations as a function of the magnetic field applied on a single-dot AB interferometer. We also discuss the dependence of the visibility of the Aharonov-Bohm oscillations on the gate potential applied to the dot. (C) 2008 Elsevier B.V. All rights reserved.

3342. AC-Susceptibility study on vortex-molecule lattice in supermultilayer cuprate HgBa2Can-1CunO2n+2+delta (n=14)

Authors: Shivagan, DD; Shirage, PM; Crisan, A; Tanaka, Y; Iyo, A; Tokiwa, K; Watanabe, T; Terada, N

Published: SEP 15 2008, PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 468, 1286, DOI: 10.1016/j.physc.2008.05.213

We investigated that in HgBa2Can-1CunO2n+2+delta, [Hg-1 2(n-1)n], for n >= 6, T-c of about 105 K, vortex melting lines remains constant and independent of number of inner plane CuO2 layers. However the vortex dynamics of the supermultilayer system could be crucially different from that of single or double layer cuprates. Therefore we measured the fundamental and third harmonic AC susceptibility responses to see the vortex dynamics and vortex matter phase diagram of Hg-12(n-1)n (n= 14), the higher member of super-multilayered cuprate superconductors. The Lindemann type vortex melting line was estimated using onset of third harmonic susceptibility (chi 3), at very low h(AC) (50 mOe), and represented by 3D Ginzburg Landau rescaling. Frequency dependence of out of phase susceptibility chi"(T) measured at lower fields of 500 and 1000 Oe. for 10 Hz to 10 kHz, showed resonance behaviour in the temperature region 55-68 K, suggesting rotational and translational creep dynamics of vortex molecule, even below usual melting line. We present schematic vortex phase diagram, considering the response of vortex dynamics to applied AC frequencies, taking into account the crossover temperatures obtained from critical slowing down of spin glass model and extended thermal activated model. (C) 2008 Elsevier B.V. All rights reserved.

3343. Absence of an elastic vortex glass in disordered HTS

Authors: Miu, L

Published: SEP 15 2008, PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 468, 1257, DOI: 10.1016/j.physc.2008.05.008

Analyses of standard current-voltage (I-V) characteristics of disordered high-temperature superconductors (HTS) indicate that the vortex phase at high magnetic fields H should be an elastic vortex glass, where the vortex pinning barriers diverge at low current densities, whereas do magnetization relaxation measurements reveal the presence of nondiverging (plastic) pinning barriers in a wide H-T domain. We show that the different conclusions concerning the nature of the vortex phase at high H in disordered HTS seem to be due to the ordering effect of the driving force existing in various experiments. (C) 2008 Elsevier B.V. All rights reserved.

3344. Critical current densities and irreversibility fields of a HgBa2Can-1CunO2n+2+delta sample containing n=6-15 phases

Authors: Shirage, PM; Iyo, A; Shivagan, DD; Crisan, A; Tanaka, Y; Kodama, Y; Kito, H

Published: SEP 15 2008, PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 468, 1290, DOI: 10.1016/j.physc.2008.05.049

A recent report on multilayered superconductors establishes unique constant T-c although the number of inner CuO2 plane (IP) increases. Many hypotheses proposed that the irreversibility field (B-irr) and critical current density (J(c)) are depends on the crystal structures. We have measured the J(c) and B-irr of the HgBa2Can-1CunO2n+2+delta sample containing n = 6-15 phases to investigate the effect of the number of IP's on the B-irr and J(c) and its pinning properties. The rate of fall of J(c) increases and irreversible lines (IL's) shift to lower temperatures with increasing the number of IP's, which suggests that anisotropy increases with n. The IL settled in between those for Bi2Sr2CaCu2Oy with high anisotropy value and YBa2Cu3O7 with less anisotropy value. The double logarithmic plot of irreversibility field versus [1 - (T/T-c)] analysis suggests that the flux line melting model is adopted. The flux pinning force density F-p (approximate to J(c)B) exhibits scaling behavior when the magnetic field B is normalized by the irreversibility field B;- Analysis of the normalized pinning force reveals that a surface pinning mechanism is dominant and reduced magnetic field b(max) = 0.2 agree with surface pinning mechanism with closely spaced pins. (C) 2008 Elsevier B.V. All rights reserved.

3345. An anelastic spectroscopy, differential scanning calorimetry and X-ray diffraction study of the crystallization process of Mg-Ni-Fe alloys

Authors: Palumbo, O; Paolone, A; Cantelli, R; Giannini, C; Guagliardi, A; Reale, P; Scrosati, B; Lo Russo, S; Maddalena, A; Palade, P; Principi, G; Schinteie, G

Published: SEP 8 2008, JOURNAL OF ALLOYS AND COMPOUNDS, 463, 152, DOI: 10.1016/j.jallcom.2007.08.081

The effects of heating-induced crystallization on the structural and mechanical properties of Mg-Ni-Fe amorphous ribbons were studied by anelastic spectroscopy, differential scanning calorimetry (DSC) and X-ray diffraction. DSC results show that the crystallization occurs through several non-reversible steps, which correspond to significant changes in the Young's modulus and concomitant irreversible elastic energy loss peaks. Moreover, an anelastic peak is found at 215 K, which for the first time indicates the presence of some dynamical process related to the simultaneous presence of different phases. The formation of a metastable Mg(6)Ni phase is detected, which transforms into Mg and Mg(2)Ni stable phases. A quantitative analysis of the different phases present at the different steps was also carried out. (C) 2007 Elsevier B.V. All rights reserved.

3346. Revealing nanoscale structural TEM/HRTEM. Application on ferroelectric ordering by PMN-PT relaxor ferroelectric

Authors: Ghica, C; Nistor, L; Van Tendeloo, G

Published: SEP 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 2333, DOI:

Nano-scale ordering may be revealed in transmission electron microscopy (TEM) by at least three techniques that will be presented in this work: selected area electron diffraction, conventional TEM and high-resolution TEM. Digital image processing is used to extract additional information from the high-resolution micrographs. The described methods are illustrated in a microstructural and compositional study of a 90%Pb(Mg1/3Nb2/3)O-3-10%PbTiO2 ceramic sample. High-resolution images reveal the presence of ordered compositional nano-domains, observable in two specific crystallographic orientations. Antiphase boundaries lying in the (111) planes separate them, while (100) and (111) facets separate the ordered domains from the disordered matrix.

3347. Polypyrrole - porous silicon nanocomposites

Authors: Popa, C; Turcu, R; Craciunescu, I; Nan, A; Ciurea, ML; Stavarache, I; Iancu, V

Published: SEP 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 2324, DOI:

In this work we report the synthesis and characterization of the polypyrrole - porous silicon nanocomposites. Our main goal is to control the growth of conducting polypyrrole into the alveolar pores of porous silicon, in order to get a functionalized nanocomposite with the required properties for application as electrode in microfluidic devices. Porous silicon was electrochemically etched from (100) p-type silicon wafers. Different silicon resistivities (from 1.8 to 11 Omega cm) and preparation conditions (different electrolyte concentrations and current densities) were used. The electrodeposition of polypyrrole into porous silicon was carried out galvanostatically, at a constant current density 2.5 mA/cm(2) from a solution containing acetonitrile, the monomer, pyrrole and p-toluensulfonic acid as electrolyte. The polymerization time was varied in order to investigate the growing process of polypyrrole into the pores. The morphology and of the as-prepared nanocomposites was investigated by SEM. The existence of PPY into porous silicon is evidenced by the EDX spectra of the nanocomposite. The electrical characterization evidences the relative contributions of the polypyrrole and the substrate resistivity, respectively.

3348. Vortex melting line and anisotropy of a Ba2Ca3Cu4O8(O1-yFy)(2) multilayered superconductor

Authors: Shivagan, DD; Shirage, PM; Crisan, A; Tanaka, Y; Iyo, A; Kodama, Y; Tokiwa, K; Watanabe, T; Terada, N; Hamada, N

Published: SEP 2008, SUPERCONDUCTOR SCIENCE & TECHNOLOGY, 21, DOI: 10.1088/0953-2048/21/9/095002

We have measured the vortex melting lines of high-pressure-synthesized Ba2Ca3Cu4O8(O1-yFy)(2) (nominal composition, 2y = 1.3, 1.6 and 2.0) F(2y)-0234 multilayered high-T-c superconductor using fundamental and third harmonic susceptibility responses carried out on preferentially oriented crystallites with very low ac field amplitude (5 mu T) and in applied dc fields up to 6 T. The vortex melting lines of all three F-substituted samples show interesting doping dependence and are very well described by the commonly accepted theory of melting lines. Interestingly, we discovered that the models describing the temperature dependence of the in-plane London penetration depth also depend on the doping level: the 3D XY model for the nearly-optimum-doped sample [F(1.3)], the mean-field theory for the under-doped sample [F(1.6)] and the two-fluid model for the heavily-under-doped sample [F(2.0)]. We found that the vortex melting lines in F-0234 are determined by the interplay in the coupling of pancake vortices through the charge reservoir layer (CRL), and through the block of inner CuO2 planes (IPs), respectively. The anisotropy values (47 for the near-optimally-doped sample) derived from experimental vortex melting lines are consistent with the values obtained by first-principles electronic-band-structure calculations.

3349. Simulation of nanoparticle formation by condensation from the gaseous phase

Authors: Nicolae, I; Popescu, M

Published: SEP 2008, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 10, 2473, DOI:

The paper reports the computer simulation of nanoparticle formation based on classical homogenous condensation theory with the purpose of understanding nanoparticle formation and the dependence of their size distribution on process parameters. The simulation has been performed for the case of silicon. The process of condensation with the formation of clusters due to the high cooling speed (similar to 10(4)-10(5) K/s) is considered.

3350. Hybrid metal (gold)-inorganic (silica) nanoparticles: Synthesis, characterization, and spin-labeling

Authors: Ionita, P; Ghica, C; Caproiu, MT; Ionita, G

Published: SEP 2008, JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 18, 419, DOI: 10.1007/s10904-008-9210-3

Water-soluble gold nanoparticles, capped with captopril, have been synthesized and characterized. Their average size is 2.3 nm, with a spherical shape. These gold nanoparticles can be easily labeled with stable free radicals (4-amino-tempo) by a coupling reaction performed in the presence of 2-ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ). Both synthesized and spin-labeled gold nanoparticles can be incorporated into much bigger (100 nm) silica nanoparticles using the Stober method, thus forming hybrid metal (gold)-inorganic (silica) nanoparticles. These hybrid silica nanoparticles (containing or not spin-labeled gold nanoparticles) can be easily spin-labeled with another stable free radical (4-isocyanato-tempo), leading to the formation of a double spin-labeled material. In this way, some stable free radicals are attached on the gold surface while others are attached on the silica surface. Three types of EPR spectra were recorded and discussed for the hybrid gold-silica nanoparticles: (1) where the spin labels are attached to the embedded gold nanoparticles, (2) where the spin labels are attached to the silica nanoparticles, and (3) in the case of the double spin labeled material where both gold and silica nanoparticles are spin-labeled. Influence of different solvents on the EPR spectra is also discussed.