National Institute Of Materials Physics - Romania

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5781 articles found

4121. Ba1-xSrxTiO3 ceramics for tunable microwave devices

Authors: Ioachim, A; Toacsan, MI; Banciu, MG; Nedelcu, L; Ghetu, D; Dutu, AC; Vasiliu, F; Alexandru, HV; Berbecaru, C; Stoica, G; Nita, P

Published: 2005, CAS 2005: INTERNATIONAL SEMICONDUCTOR CONFERENCE, 1-2, 280, DOI:

The paper describes the investigations of Ba1-xSrxTiO3 ceramic materials prepared by solid-state reaction techniques. The addition of MgO and MnO2 improves sintering process and decreases the dielectric loss. The materials exhibit a dielectric constant epsilon(r) similar to 1000 and low loss tan delta similar to 10(-3) at microwave frequencies.

4122. X-band filter manufactured with ZST dielectric resonators

Authors: Ioachim, A; Banciu, MG; Toacsin, MI; Nedeleu, L; Dutu, CA; Radu, I; Nicolaescu, I

Published: 2005, CAS 2005: INTERNATIONAL SEMICONDUCTOR CONFERENCE, 1-2, 102, DOI:

Band-pass filters with dielectric resonators of (Zr-0.8, Sn-0.2,)TiO4 ceramic materials (ZST) were developed for X-band applications. The ZST materials exhibit a dielectric constant of about 36.8 and low loss in microwave range. A Qxf product higher than 50,000 was achieved for the ZST samples with 0.2% wt NiO sintering addition. The external coupling was performed Using microstrip lines on a substrate of 9.22 dielectric constant and 0.635 mm height. Filters with minimum insertion loss between 0.46 dB and 1.74 dB, the bandwidth between 40 MHz and 170 MHz and with the central frequency around 10 GHz were manufactured.

4123. CNT-based cathode material for DMFC

Authors: Rohland, B; Pietrzak, M; Moller, S; Bunescu, MC; Wienecke, M; Barfels, T; Bunescu, MC

Published: 2005, FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 13, 522, DOI: 10.1081/FST-200039478

New cathode material for Direct Methanol Fuel Cells (DMFC) based on multi-wall carbon nanotubes (MWCNT), aiming to improving the power density of the cell was analysed. Commercially available MWCNTs were oxidized in a mixture of HNO3 and H2SO4. Pt catalyst was electroless deposited using a chloroplatinic acid solution, based on H-2 (PtCl6) center dot 6H(2)O. The morphology of the deposits was analysed by TEM and SEM. Uniformly distributed nano particles of Pt with diameters of approximately 5 nm along the MWCNTs surface, agglomerates of thick Pt deposits, as well as complete uncoated nanotubes were observed. An optimisation of the size and distribution of the Pt particles could be obtained by varying the process parameters (dispersion time and solution concentration). The MWCNTs + Pt were used to produced a paste, which was screen-printed on Nation foil. The membrane electrode assembly (MEA) was tested at 40 degrees C with air and 3% methanol in water. The performances were improved as compared with the standard DMFC electrodes.

4124. Cornpact cross-coupled filters for UMTS applications

Authors: Banciu, MG; Lojewski, G; Ioachim, A; Militaru, N

Published: 2005, ISSCS 2005: International Symposium on Signals, Circuits and Systems, Vols 1 and 2, Proceedings, 728, DOI:

Very compact planar resonators were developed for the 1950 MHz frequency band. Resonators are of the stepped-impedance (SIR) type and they are folded, in order to occupy a very small surface area. On a 6.635 mm height commercial substrate with a 10.8 dielectric constant, a resonator can be fitted into a square with an edge size of 5.8 m. Small-size filters were designed by cross-coupling the compact resonators. The four-pole filters have an improved response due to the cross-couplings, which introduces transmission zeros on each side of the pass-band. The filters were manufactured and characterized. The measurement data are in good agreement with the electromagnetic field simulations. The developed filters are small-size and cost-effective and their technology is simple,. without any via holes, air-bridges or lumped elements.

4125. Size Anisotropy and Lognormal Size Distribution in the Powder Diffraction Whole Pattern Fitting

Authors: Popa, N; Balzar, D

Published: 2005, ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 61, C79, DOI: 10.1107/S0108767305096674

4126. High-K ZST material for microwave and millimeter wave applications

Authors: Ioachim, A; Ramer, R; Toacsan, MI; Banciu, MG; Nedelcu, L; Ghetu, D; Stoica, G; Annino, G; Cassetari, M; Martinelli, M

Published: 2005, Smart Materials III, 5648, 376, DOI: 10.1117/12.582428

Wireless communications systems require new materials with special properties in specific frequency bands. The investigations on ZST type ceramics, (Zr0.8Sn0.2)TiO4, presented in this paper, recommend this materials for applications in microwaves and millimeter waves. The ZST materials were prepared using a standard solid-state reaction technology. The samples morphology, phase-composition and microstructure investigations were performed by using the scanning electron microscopy (SEM), and energy-disperse X-ray spectrometry (EDX). The crystalline phases were identified by X-ray diffractometry (XRD). The electromagnetic properties were investigated on ZST resonators by using a Computer Aided Measurement (CAM) in microwaves, combining a HP 8757C network analyzer and a HP 8350B sweep oscillator. The dielectric characteristics at millimeter waves were analyzed by investigation of the Whispering Gallery Modes on ZST disks. The low level NiO doping provides ZST materials with temperature coefficient tau(f) in the range (-2 divided by +4) ppm/degrees C and decreases the dielectric loss. Materials with high values of the Q f product up to 50,000 and a dielectric constant about 36 at microwave frequencies were obtained. ZST dielectric resonators and substrates for hybrid integrated circuits with dimensions 1" x 1" and thickness in the range 0.6 divided by 1 mm were manufactured.

4127. Surface-enhanced Raman scattering studies on C-60 fullerene self-assemblies

Authors: Baibarac, M; Mihut, L; Preda, N; Baltog, I; Mevellec, JY; Lefrant, S

Published: 2005, CARBON, 43, 9, DOI: 10.1016/j.carbon.2004.08.020

Surface-enhanced Raman scattering (SERS) was used to investigate C-60 self-assembling in solvents like pyrrolidine (Py) and Nmethyl-2-pyrrolidinone (NMP) as well as in binary mixtures of o-dichlorobenzene (DCB)/acetonitrile (ACN) and DCB/NMP. For a correct evaluation of the modifications of Raman spectra induced by the C-60 aggregation, we have also presented the variations due to the measuring method, i.e., the signal dependence of the metallic support type and the surface roughness. The interaction between C-60 and the Au substrate, appearing as a chemical component in SERS generation, is mainly evidenced by a band at similar to342cm(-1). In the aggregated phase, the intermolecular interactions lead to a reduction in the parent I-h C-60 symmetry as observed by a modified phonon spectrum. As a general feature, the spectral range below 800cm(-1) is the most diagnostic for the aggregate assignment, the main indicative being the disappearance of the Raman bands associated to the radial vibration modes. SERS measurements have revealed two stages in the self-assembling of C-60 in NMP. In the beginning, charge-transfer molecular complexes that associate slowly in stable aggregates are formed by the binding of an NMP molecule to the C-60 cage. These complexes are noticed in the SERS spectrum by the replacement of the original H-g(l) band at similar to269cm(-1) with two others at similar to255 and similar to246cm(-1). In the aggregated phase, when using NMP and P as a solvent, the Raman spectrum reveals new bands that appear around 94 and 110-118cm(-1), which are associated with the interball interactions. In a DCB/ACN solvent mixture, the self-assembling process is driven by weak van der Waals type forces and resembles a precipitation, yielding C60 clusters of different size. (C) 2004 Published by Elsevier Ltd.

4128. Magnetic properties of iron-modified amorphous carbon

Authors: Yastrebov, SG; Ivanov-Omskii, VI; Pop, V; Morosanu, C; Slav, A; Voiron, J

Published: 2005, SEMICONDUCTORS, 39, 844, DOI: 10.1134/1.1992645

The structure and magnetic properties of films of iron-modified amorphous carbon (a-C:Fe) prepared by magnetron cosputtering of iron and graphite targets are studied. X-ray diffraction measurements show that iron enters the samples in the form of Fe nanocrystals that are typically about 20 nm in size and also forms nanocrystals of hexagonal iron carbide. The temperature dependences of the magnetization, measured under cooling in zero and nonzero magnetic fields, are studied. At temperatures T less than or similar to 8 K, a magnetic transition, which provides evidence for the onset of magnetic ordering in the material, is observed to occur. The magnetization isotherms obtained in the 8- to 20-K temperature range are in agreement with this observation. It is shown that a modified version of Langevin's formalism adequately describes the observed features of a-C:Fe film magnetization. (c) 2005 Pleiades Publishing, Inc.

4129. Radiation effects and defects in cubic boron nitride. A promising multifunctional material for severe environment conditions.

Authors: Nistor, SV

Published: 2005, MATERIALS FOR SPACE APPLICATIONS, 851, 316, DOI:

Cubic boron nitride (c-BN) is a synthetic material which exhibits exceptional physicochemical properties such as: hardness, thermal conductivity, thermo-chemical stability, semiconducting properties and radiations resistance. Such outstanding properties make it a promising multifunctional material for applications in extreme conditions, as those found in the outer space environment. Its further use for such applications requires, however, a much better understanding of the lattice defects and radiation damage properties. Here we present the results of multifrequency ESR studies concerning the native and radiation induced point defects in crystalline c-BN under irradiation with high intensity 1MeV electron beams.

4130. Lead-based ferroelectric compounds: Insulators or semiconductors?

Authors: Pintilie, L; Lisca, M; Alexe, M

Published: 2005, INTEGRATED FERROELECTRICS, 73, 48, DOI: 10.1080/10584580500413434

Lead zirconate-titanate (PZT) epitaxial thin films are considered wide-gap p-type semiconductors with standard Schottky contacts. Capacitance-voltage, current-voltage, as well as the dielectric hysteresis are analyzed using a model based on the conventional metal-semiconductor Schottky contact in which the effect of the ferroelectric polarization on band-bending was considered. In addition, presence of the deep traps and its effect on the measured quantities were considered and discussed. For a single-crystal like PZT films with a remnant polarization of 40 mu C/cm(2) the free carrier concentration is estimated to about 3 x 10(18) cm(-3), whereas the effective density of the fixed charges in the depletion region is of about 1.8 x 10(19) cm(-3) .