Publications

In this work, the effect of the single-walled carbon nanotubes (SWNTs) as the mixtures of metallic and semiconducting tubes (M + S-SWNTs) as well as highly separated semiconducting (S-SWNTs) and metallic (M-SWNTs) tubes on the photoluminescence (PL) of poly(3-hexyl thiophene) (P3HT) was reported. Two methods were used to prepare such composites, that is, the chemical interaction of the two constituents and the electrochemical polymerization of the 3-hexyl thiophene onto the rough Au supports modified with carbon nanotubes (CNTs). The measurements of the anisotropic PL of these composites have highlighted a significant diminution of the angle of the binding of the P3HT films electrochemical synthetized onto Au electrodes covered with M + S-SWNTs. This change was attributed to metallic tubes, as was demonstrated using the anisotropic PL measurements carried out on the P3HT/M-SWNTs and P3HT/S-SWNTs composites. Small variations in the angle of the binding were reported in the case of the composites prepared by chemical interaction of the two constituents. The proposed mechanism to explain this behavior took into account the functionalization process of CNTs with P3HT. The experimental arguments of the functionalization process of CNTs with P3HT were shown by the UV-VIS-NIR and FTIR spectroscopy as well as surface-enhanced Raman scattering (SERS). A PL quenching process of P3HT induced both in the presence of S-SWNTs and M-SWNTs was reported, too. This process origins in the various de-excitation pathways which can be developed considering the energy levels diagram of the two constituents of each studied composite.

Due to its physical and chemical properties, the n-type tungsten oxide (WO3) semiconductor is a suitable photoanode for water decomposition reaction. The responses of the photoelectrochemical PEC water-splitting properties as an effect of structural and optical changes of WO3 thin films, as well as the nature of electrolyte solutions, were studied in this work. The WO3 thins films have been obtained by pulsed laser deposition (PLD) on silicon (Si(001)) covered with platinum substrates using three different laser wavelengths. As the XRD (X-ray diffraction) and XTEM (cross-section transmission electron microscopy) analysis shows, the formation of highly crystalline monocline WO3 phase is formed for the film deposited at 1064 nm wavelength and poor crystalline phases with a large ordering anisotropy, characteristic of 2D structures for the films deposited at 355 nm and 193 nm wavelengths, respectively. The photogenerated current densities J(ph) depend on the laser wavelength, in both alkaline and acidic electrolyte. The maximum values of the photocurrent density have been obtained for the sample prepared with laser emitting at 355 nm. This behavior can be correlated with the coherent crystallized atomic ordering that appear for long distances (10-15 nm) in the (001) plane of the monoclinic WO3 phase structure films obtained at 355 nm laser wavelength. All the samples show poor current density in dark conditions and they are very stable in both acidic and alkaline solutions. The highest photocurrent density value is obtained in acidic solution for the WO3 thin film prepared by 355 nm laser (29 mA/cm(2) at 1.6 V vs. RHE (1.35 V vs. Ag/AgCl)).

In the last few decades, the intensive use of agricultural lands affected crop productivity and thus raised serious concerns due to competing demands for food to feed the ever-growing world population (projected to be 9.7 billion by 2050). In this context, the development of nanotechnology-based fertilizers for crop nutrition has been suggested as an alternative tool to overcome the drawbacks arising from the current agricultural practices. Unfortunathelly, there is little studies about the effects of nanomaterials on plants. In this study we presented the effect of hydroxyapatite (nHA) and iron oxides (nIO) nanoparticles obtained in Romania on growth and photosintesis of corn and winter wheat plants. The results show that hydroxyapatite (nHA) and iron oxides (nIO) treatments applied by watering the soil had a positive effect on the photosynthesis of maize and winter wheat plants. In the case of treatments with solutions of iron oxides a negative effect on the length of main root was observation, but a compensating effect was found by increasing root density. This and also the higher chlorophyll content. led to a positive effect on height of maize and winter wheat plants.

Commercial nanopowders of MgB2 were characterized from the viewpoint of granulometric distribution, structure, microstructure, and pH behavior in water. The powders are very different: a higher amount of the MgB2 phase with a lower tendency for agglomeration determines a higher rate of pH-increase. A higher rate of pH-increase usually produces a stronger antimicrobial activity against Staphylococcus aureus, Enterococcus faecium, Escherichia coli, Pseudomonas aeruginosa, Candida albicans, and Candida parapsilosis reference strains. The variation of the pH-increase rate suggests the possibility of temporo-spatial control of MgB2 bioactivity, although the contribution of other factors should not be neglected. Remarkably, the efficiency of the MgB2 powders is higher against biofilms than on microbes in the planktonic state. Further, our experiments confirm the antimicrobial efficiency of MgB2 in the in vitro tests against 29 methicillin resistant clinical S. aureus isolates and 33 vancomycin resistant E. faecium/faecalis strains, but in this case the biofilms are more resistant than planktonic cells. The MgB2 treatment of infected mice led to a significant decrease of E. coli colonization in liver, spleen and peritoneal liquid and it also caused changes in the intestinal microbiota. The activity of powders on HeLa and HT-29 tumor cell lines was assessed by inverted microscopy, flow cytometry, and evaluation of the cellular cycle. MgB2 inhibits tumor cell growth influencing DNA synthesis (S-phase). The obtained results indicate that the tested powders could provide promising solutions for the development of large-spectrum multifunctional antimicrobial and anti-biofilm agents, and/or for anti-cancer therapies. (C) 2021 The Authors. Published by Elsevier B.V.

Green chemistry principles were used to phytosynthesis of three types of silver nanoparticles (AgNPs) from aqueous extracts of: nettle (Urtica dioica) leaves, black grapes (Vitis vinifera fruits), and their mixture. The combination of these extracts proved to be the most potent bioreductant for Ag+, as compared to each extract alone. UV-Vis absorption and FT-IR spectroscopy proved the formation of silver nanoparticles. Total polyphenols' quantification of vegetal extracts and "green" AgNPs was carried out by Folin-Ciocalteu analysis. Structural (XRD) analysis revealed crystalline nature of bio-developed AgNPs. Morphological studies (AFM) showed spherical shape and the nano-scale dimensions of the obtained metallic nanoparticles. Physical stability of "green" developed nanoparticles was estimated by zeta potential measurements, and their biological activity was checked by evaluating the antimicrobial and the antioxidant potency. AgNPs phyto-generated from a combination of two extracts (nettle and grapes) proved to be the most bio-active, combining in a synergistic manner, the properties of nettle and grapes. These nanoparticles exhibited high antioxidant activity (AA = 89.4%) evaluated through chemiluminescence method, and strong antibacterial effect (showing an inhibition zone diameter of 20 mm) against Escherichia coli.

Graded structures with different architectures were obtained by spark plasma sintering from (Ba1-xSrx)TiO3 (BST, x = 0.10; 0.20; 0.30) powders. The presence of the composition gradient was confirmed by structural and compositional investigations using X-ray diffraction and electron microscopy combined with energy dispersive X-ray spectroscopy. The concentration gradient was either asymmetric (3 layers, starting with x = 0.10 and ending with x = 0.30) or symmetric (5 or 6 layers, starting and ending with x = 0.10, and with a single or double x = 0.30 layer in the middle, respectively). Electrical measurements reveal a decrease of the dielectric constant with increasing the number of the layers. It was found that the symmetric graded structure with 6 layers has the best thermal stability of both, the dielectric constant (variation of only 8% between zero and 100 degrees C) and the py-roelectric coefficient (6% variation between zero and 80 degrees C). In addition, an enhancement of the pyroelectric signal for frequencies above 100 Hz is obtained in symmetric structures, an effect that is attributed to the additive contributions of the signals originated from the layers with different Sr content. (C) 2021 The Author(s). Published by Elsevier B.V.

Wheat is the most cultivated plant and an important source of carbohydrates in the world. The Fe deficiency reduces quality of grain wheat leading to Fe deficiency in human. The purpose of this study was to investigate the effects of foliar and ground application of iron oxide nanoparticles (made in Romania) on growth components, yield and morphological and anatomical modifications of wheat plants. The ground application of iron oxide decreased height of plant, length of root and increased root volume and chlorophyll content more than foliar application. For the wheat plants fertilized with iron oxide nanoparticles, the decrease of root length was compensated by an increase of radicular density, which led to the development of new adventitious roots that could help the plants have a better uptake of water and nutrients. This meant that the production was not negatively influenced by the treatments performed, regardless of the application method. Our studies revealed that the fertilized wheat plants (foliar and root zone) presented anatomical changes in relation to control plants. The studies presented in this paper can contribute to achieve the necessary framework for the innovative development strategy regarding the efficiency of magnetic nanoparticles in foliar and ground fertilization of different crops.

UV-nanoimprint lithography is currently seen like an alternative to the classical lithographic techniques (electron beam or optical lithography) for large scale patterning in industrial applications. The present study is oriented on the fabrication of silicon nano-cones (pyramids) by using the UV-nanoimprint technique with polymeric stamps and deep reactive ion etching using the UV-cured resist as etching mask at cryogenic temperatures. The results show that the resist can act successfully as etching mask for the cryogenic silicon etching process.

In this paper we present the results obtained by depositing the nanocomposite materials based on nano TiO2/TiO2:N, Ag, SiO2, single-walled carbon nanotube (SWCNTs), single-walled functionalized carboxylic acid, (SWCNT-COOH), poly(2,2' bithiophene) (PBTh) and poly(dipheylamine) (PDPA) by conventional and unconventional methods on the surface of sheepskin leathers. The nanocomposite materials were integrated in film forming polymers and were applied on sheepskin leather surfaces by spraying (conventional method) or by activating the surface with cold atmospheric plasma followed by electrospraying (unconventional methods). The leather surfaces were tested for antimicrobial properties against Grampositive and Gram-negative bacteria and fungi according to ISO 20743: 2007. The photocatalytic properties under visible light exposure were also tested using two organic stain models (methylene blue and orange II). The stain discoloring was evaluated by measuring the color differences between the blank and the samples with DATA Color Check Plus II portable device assisted by CIELab color management software. The evaluation of the physical-mechanical resistance and comfort properties for the sheepskin leathers was determined by measuring the water vapor permeability, rubbing tests and abrasion resistance. The results showed that the sheepskin leather surfaces treated with nanocomposite materials have improved antibacterial, self-cleaning, physical-mechanical and comfort properties as compared to untreated samples, with potential applications for added value multifunctional products. (c) 2021 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the International Conferences & Exhibition on Nanotechnologies, Organic Electronics & Nanomedicine - NANOTEXNOLOGY 2020. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/

Herein we show the terahertz (THz) time-domain ellipsometry investigation of the InSb semiconductor. At room temperature, the carriers of InSb are thermally excited to the conduction band due to its narrow bandgap. We, nevertheless, show that THz ellipsometry can detect subtle differences between carrier densities of undoped and lightly doped InSb bulk semiconductors. The advantage of THz ellipsometry over other THz time-domain spectroscopy techniques is that it does not require reference measurements through an aperture or standard mirrors.