National Institute Of Materials Physics - Romania

Raman enhancement in a layered structure of Bib was studied under optical excitation near the edge of the fundamental absorption band. This phenomenon simultaneously appears at a low temperature with the generation of the excitonic photoluminescence (PL) band, unequally across the Raman spectrum, i.e. in the Stokes and anti-Stokes Raman branches, being dependent on the superposition of the excitation laser line to the excitonic emission band. Performed with the use of different resonant laser light excitations, this effect is regarded as a signature of the exciton-phonon interaction, which is interpreted in terms of a stimulated Raman scattering process (SRS), resulting from the mixing inside of the sample to two optical fields, the pump laser light and the excitonic PL light. (C) 2016 Elsevier B.V. All rights reserved.

Water soluble gold nanoparticles protected by lipoic acid were obtained and further functionalized by standard coupling reaction with 1-naphtylamine, 4-aminoantipyrine, and 4 0 -aminobenzo-15-crown-5 ether. Derivatives of lipoic acid with 1-naphtylamine, 4-aminoantipyrine, and 4 0 -aminobenzo-15-crown-5 ether were also obtained and characterized. All these were tested for their antimicrobial activity, as well as for their influence on mammalian cell viability and cellular cycle. In all cases a decreased antimicrobial activity of the obtained bioactive nanoparticles was observed as compared with the organic compounds, proving that a possible inactivation of the bioactive groups could occur during functionalization. However, both the gold nanoparticles as well as the functionalized bioactive nanosystems proved to be biocompatible at concentrations lower than 50 mu g/mL, as revealed by the cellular viability and cell cycle assay, demonstrating their potential for the development of novel antimicrobial agents.

The present work investigates the photocatalytical abatement of trichlorethylene (TCE) under simulated solar irradiation (AM 1.5). The employed catalytic materials, Au and Pd-Au nanoparticles supported on TiO2, were prepared by incipient wetness and by deposition-precipitation methods. It is found out that TCE is converted efficiently (>80%) to CI- and CO2 over all scrutinized catalysts. Typically, the metal addition enhances to some extent the photooxidation activity of TiO2 via photogenerated center dot OH radicals, electrons, and holes. The photocatalytic abatement of TCE over the same catalytic materials was examined in the presence of small amount of methanol. The idea was to convert TCE to Cl- and C-2 (ethane and ethylene) over Au and Pd-Au/TiO2 catalysts by the H-2 generated photocatalytically in situ. The experimental results evidenced that, over Pd-Au/TiO2 catalysts, hydrodechlorination (HDC) and photomineralization reactions of TCE occurs simultaneously. In contrast, Au/TiO2 is inactive to catalyze the hydrogenation of TCE. The results of TCE abatement by combined photooxidation/HDC reactions in presence of methanol are corroborated with H-2 photocatalytic generation results, over the same catalytic materials, from water/methanol mixture. A reaction mechanism is advanced in light of experimental results. The photo generated center dot OH radicals, electrons, and holes participate in a complex reaction pathway to formation of oxygenated organic intermediates, Cl-, CO2, and H-2. (C) 2016 Elsevier Inc. All rights reserved.

TiO2-based photocatalysts were obtained during previous years in order to limit pollution and to ease human daily living conditions due to their special properties. However, obtaining biocompatible photocatalysts is still a key problem, and the mechanism of their toxicity recently received increased attention. Two types of TiO2 nanoparticles co-doped with 1% of iron and nitrogen (TiO2-1% Fe-N) atoms were synthesized in hydrothermal conditions at pH of 8.5 (HT1) and 5.5 (HT2), and their antimicrobial activity and cytotoxic effects exerted on human pulmonary and dermal fibroblasts were assessed. These particles exhibited significant microbicidal and anti-biofilm activity, suggesting their potential application for microbial decontamination of different environments. In addition, our results demonstrated the biocompatibility of TiO2-1% Fe-N nanoparticles at low doses on lung and dermal cells, which may initiate oxidative stress through dose accumulation. Although no significant changes were observed between the two tested photocatalysts, the biological response was cell type specific and time- and dose-dependent; the lung cells proved to be more sensitive to nanoparticle exposure. Taken together, these experimental data provide useful information for future photocatalytic applications in the industrial, food, pharmaceutical, and medical fields.

We report the synthesis of dextran-coated iron oxide magnetic nanoparticles (DIO-NPs) with spherical shape and uniform size distribution as well as their accumulation and toxic effects on Jurkat cells up to 72 h. The characterization of dextran-coated maghemite nanoparticles was done by X-ray diffraction and dynamic light scattering analyses, transmission electron microscopy imaging, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, magnetic hysteresis, and relaxometry measurements. The quantification of DIO-NPs intracellular uptake showed a progressive accumulation of iron as a function of time and dose accompanied by additional lysosome formation and an increasing darkening exhibited by a magnetic resonance imaging (MRI) scanner. The cytotoxicity assays revealed a decrease of cell viability and a loss of membrane integrity in a time-and dose-dependent manner. Exposure to DIO-NPs determined an increase in reactive oxygen species level up to 72 h. In the first two days of exposure, the level of reduced glutathione decreased and the amount of malondyaldehyde increased, but at the end of the experiment, their concentrations returned to control values. These nanoparticles could be used as contrast agents for MRI but several parameters concerning their interaction with the cells should be taken into consideration for a safe utilization.

Electrochemical impedance spectroscopy (EIS), X-ray spectroscopy (XPS), and atomic force microscopy (AFM) have been used to investigate the effects of the sodium dodecyl sulfate (SDS) interaction with the L-cysteine-thiolate covered p- and n-GaAs(100) electrodes in H2SO4 solution. The potential-induced reversible proton transfer found to occur within the L-cysteine-thiolate layer in the simple acid solution during the cathodic as well as the anodic potential scans at the p-doped semiconductor electrode and only in the anodic scan at the n-doped one is suppressed in both cases. XPS data revealed that the anionic surfactant has a complex interaction with the L-cysteine-thiolate covered GaAs(100) electrodes, which implicates both electrostatic and chemical forces. The SO42 head group interacts electrostatically with the NH3+ group of the cysteine-thiolate but it is also chemically involved in a chemisorption bond with the available Ga atoms. The amount of Ga-bound SDS species is much more pronounced at the L-cysteine-thiolate/p-GaAs(100) than at the L-cysteine thiolate/n-doped GaAs(100) electrodes meaning that cysteine-thiolate is mainly formed at As sites in the first case and at Ga sites in the latter one. This outcome strengthens the previous conclusions concerning the role of the dopant in determining the bonding way of the L-cysteine on GaAs(100) surfaces. (C) 2016 Elsevier Ltd. All rights reserved.

A new method based on transformation of magnetron sputtered platinum thin films into platinum nanostructures enclosed by high-index facets, using electrochemical potential cycling in a twin working electrode system is reported. The controllable formation of various Pt nanostructures, described in this paper, indicates that this method can be used to control a selective growth of high purity Pt nanostructures with specific shapes (facets or edges). The method opens up new possibilities for electrochemical preparation of nanostructured Pt catalysts at high yield. (C) 2016 Elsevier B.V. All rights reserved.

We study Coulomb interacting electrons confined in polygonal quantum rings. We focus on the interplay of localization at the polygon corners and Coulomb repulsion. Remarkably, the Coulomb repulsion allows the formation of in-gap states, i.e., corner-localized states of electron pairs or clusters shifted to energies that were forbidden for non-interacting electrons, but below the energies of corner-side-localized states. We specify conditions allowing optical excitation to those states.

Different aspects related to the sol-gel preparation and structural investigation of silico-phosphate glasses (SiO2-P2O5 system) doped with Fe ions are reported. During the preparation process, tetraethoxysilane was used as a precursor for SiO2 and phosphoric acid (H3PO4-HP) for P2O5. Ferric chloride was used as precursor for Fe ions, water as reagent for hydrolysis reaction and ethylic alcohol as solvent. The pH of the sols was modified by adding hydrochloric acid and ammonia. It was observed that a slight increase of the solution temperature (up to 40 degrees C) allows a drastic decrease of the gelation time (from days to hours). The structure of the obtained powders dried in air at room temperature and at 100 degrees C for 10 h and subsequently thermally treated at different temperatures was investigated by Fourier transformed infrared (FTIR) and Raman spectroscopy. Vibration modes specific to Si-O-Et, Si-OH, PO-P, P-O-Si, hydrogen bonds and H2O, as well as combined modes have been observed. The local structure and electron configurations of the doping Fe ions have been investigated by Fe-57 Mossbauer spectroscopy.