National Institute Of Materials Physics - Romania

Publications

5714 articles found

2421. A facile hydrothermal route for the synthesis of alpha-FeOOH with controlled morphology

Authors: Raditoiu, V; Diamandescu, L; Corobea, MC; Raditoiu, A; Popescu-Pogrion, N; Nicolae, CA

Published: JUN 1 2012, JOURNAL OF CRYSTAL GROWTH, 348, 46, DOI: 10.1016/j.jcrysgro.2012.03.032

Nanoscaled alpha-FeOOH (goethite) with controlled morphology was synthesized via hydrothermal reaction at 145-155 degrees C from ferrous ions and an oxidant in the presence of a cationic surfactant. The formation of alpha-FeOOH was confirmed by X-ray diffraction (XRD), Mossbauer spectroscopy, FT-IR analysis and visible diffuse reflectance spectroscopy. The morphology of the product was analyzed by transmission electron microscopy (TEM). The particles obtained by the proposed method have a medium size of about 35 nm. The proposed growth mechanism takes into account two possible simultaneous pathways consisting of direct electrostatic interaction between FeOH groups and cetyltrimethylammonium bromide (CTAB) and adsorption of bicarbonate ions on the alpha-FeOOH surface followed by complexation of CTAB through ammonium head groups. (C) 2012 Elsevier B.V. All rights reserved.

2422. X-ray photoelectron spectroscopy of pulsed laser deposited Pb(Zr,Ti)O3-delta

Authors: Dragoi, C; Gheorghe, NG; Lungu, GA; Trupina, L; Ibanescu, AG; Teodorescu, CM

Published: JUN 2012, PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 209, DOI: 10.1002/pssa.201127740

High quality pulsed laser deposited lead zirconate titanate (PZT) films are obtained by pulsed laser deposition on SrRuO3(111) single crystal layers and characterized by X-ray photoelectron spectroscopy (XPS), to determine the surface composition. It is found that a minor amount of Pb forms PbO2 at the surface and also some Pb is included into the contamination layer, in form of a Pb(CO3)2 layer of about 1?nm thickness, occupying about one quarter of the PZT surface. The stoichiometry of the outermost 45?nm layers yielded as PbZr0.25Ti0.80O2.5, which suggest the formation of an oxygen depleted, Brownmillerite-like layer at the surface, of at least 5?nm thickness.

2423. Magnetic glass-ceramics

Authors: Sandu, V; Nicolescu, MS; Kuncser, V; Damian, R; Sandu, E

Published: JUN 2012, JOURNAL OF ADVANCED CERAMICS, 1, 143, DOI: 10.1007/s40145-012-0010-4

We present the magnetic properties of magnetic glass ceramics obtained by crystallization of Fe containing borosilicate glass. Two types of nucleators have been used: Cr2O3 and P2O5. The role of the nucleators proved to be crucial in the size and morphology of the crystallites developed within glassy matrix as well in the magnetic response. The former stimulates the growth of regular single crystals uniformly dispersed within the matrix whereas the latter leads to the formation of grains made of tiny (30 nm), nanocrystals. The magnetic response depends on the amount of Fe ions left dispersed within glassy matrix as paramagnetic ions. Although P2O5 leads to the best structural magnetite, almost 42% of Fe ions are left dispersed in the matrix without magnetic interaction. In the case of Cr2O3, the paramagnetic Fe is decreased to 12% but structural deficiency in the occupancy of the Fe sites of magnetite is revealed by Mossbauer spectroscopy.

2424. Spectroscopic ellipsometry investigations of Eu-doped oxy-fluoride glass and glass-ceramics

Authors: Galca, AC; Preda, N; Secu, CE; Luculescu, CR; Secu, M

Published: JUN 2012, OPTICAL MATERIALS, 34, 1496, DOI: 10.1016/j.optmat.2012.03.015

Oxyfluoride glass-ceramics in the system SiO2-Al2O3-CaF2-EuF3 containing Eu3+-doped CaF2 nanocrystals were produced by using controlled crystallization of melt-quenched glass. X-ray diffraction and scanning electron microscopy data have revealed the formation of CaF2 nanocrystals of about 50 nm size. The Eu3+-dopant ions act as the nucleating agent necessary to initiate the crystallization process. The refractive index is higher in the glass ceramics than in the initial glass and varies as the annealing time increases. Two competitive processes are responsible for this behavior, the crystallization of the CaF2 phase and the decrease of the glass ceramic mass density. (C) 2012 Elsevier B.V. All rights reserved.

2425. Structure and Magnetic Properties of Nanosized Magnetite Obtained by Glass Recrystallization

Authors: Sandu, V; Nicolescu, MS; Kuncser, V; Popa, S; Pasuk, I; Ghica, C; Sandu, E

Published: JUN 2012, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 12, 5050, DOI: 10.1166/jnn.2012.4943

We present the preparation, structural and magnetic properties of nanosized magnetite obtained by the crystallization of a series of Fe-containing borosilicate glasses. Several compositions with the ratio Fe2O3/SiO2 spanning from 0.37 to 0.67 were investigated as a function of two nucleators Cr2O3 and P2O5, respectively, and modifiers and intermediates (Al2O3 and MgO). Mossbauer spectroscopy revealed the degree, the type and the location of disorder induced by a specific composition and nucleators. In addition to magnetite, it was also revealed the presence of large amounts of Fe-rich paramagnetic phases. The magnetic response is analysed in relation with the amount of Fe ions which remain dispersed in the glassy matrix as noninteracting (paramagnetic) ions. We discuss the role of the nucleators on the disorder in both tetrahedral and octahedral sites of the magnetite.

2426. Treatment of carrier scattering in quantum dots beyond the Boltzmann equation

Authors: Steinhoff, A; Gartner, P; Florian, M; Jahnke, F

Published: MAY 29 2012, PHYSICAL REVIEW B, 85, DOI: 10.1103/PhysRevB.85.205144

As quantum dots (QD) can confine a small number of carriers in localized states with discrete energies, it is questionable to neglect correlations between the carriers when describing their dynamics. We analyze the influence of carrier correlations in a single QD on Coulomb scattering processes, which are due to the contact with a quasicontinuum of wetting-layer (WL) states. Results obtained from a Boltzmann equation are compared with the fully correlated dynamics governed by a von Neumann-Lindblad equation. In a first step, we take into account correlations generated by the exact treatment of Pauli blocking due to the contributing QD carrier configurations. Subsequently, we include correlations generated by energy renormalizations due to Coulomb interaction between the QD carriers. It is shown that at low WL carrier densities, neither Pauli correlations nor Coulomb correlations can be safely neglected, if the dynamics of single-particle states in the QD are to be predicted qualitatively and quantitatively. In the high-density regime, both types of correlations play a lesser role and thus a description of carrier dynamics by a Boltzmann equation becomes reliable. Furthermore, the efficiency of WL-assisted scattering processes as well as scattering-induced dephasing rates depending on the WL carrier density are discussed.

2427. Tartarate precursors to CoxZn1-xGa2O4 spinel oxides

Authors: Mindru, I; Gingasu, D; Marinescu, G; Patron, L; Diamandescu, L; Feder, M; Calderon-Moreno, JM; Stanica, N

Published: MAY 15 2012, MATERIALS CHEMISTRY AND PHYSICS, 134, 483, DOI: 10.1016/j.matchemphys.2012.03.019

The CoxZn1-xGa2O4 spinels (x=0.25, 0.5, 0.75, 1) were synthesized by a wet chemistry method-the precursor route via tartarate decomposition. The complex precursors have been characterized by IR. UV-Vis, magnetic measurements and luminescence spectroscopy. XRD, SEM, IR. UV-Vis and luminescence spectroscopy were used for the structural and morphological investigation of CoxZn1-xGa2O4 spinels; magnetic susceptibilities of the spinel were also measured. The X-ray diffraction patterns confirmed the formation of gallate spinet phase. CoxZn1-xGa2O4. (C) 2012 Elsevier B.V. All rights reserved.

2428. Preparation of nanostructured ZnO nanorods in a hydrothermal-electrochemical process

Authors: Sima, M; Vasile, E; Sima, M

Published: MAY 1 2012, THIN SOLID FILMS, 520, 4636, DOI: 10.1016/j.tsf.2011.10.116

An array of ZnO nanorods, each nanorod being covered with a shell of porous ZnO was prepared in two steps by hydrothermal-electrochemical processes. The growth of ZnO nanorods was achieved in a zinc nitrate and hexamethylenetetramine aqueous solution on fluorine-doped tin oxide film. The porous ZnO shell was grown from a similar solution in the presence of eosin Y as nanostructuring agent. A dye-sensitized solar cell was assembled using as photoanode an eosin Y sensitized ZnO nanorod/shell layer. (C) 2011 Elsevier B.V. All rights reserved.

2429. Ferroelectric and dielectric multilayer heterostructures based on KTa0.65Nb0.35O3 and Bi1.5-xZn0.92-yNb1.5O6.92-1.5x-y grown by pulsed laser deposition and chemical solution deposition for high frequency tunable devices

Authors: Le Febvrier, A; Deputier, S; Bouquet, V; Demange, V; Ollivier, S; Galca, AC; Dragoi, C; Radu, R; Pintilie, L; Guilloux-Viry, M

Published: MAY 1 2012, THIN SOLID FILMS, 520, 4567, DOI: 10.1016/j.tsf.2011.10.142

Epitaxial growth of Bi1.5-xZn0.92-yNb1.5O6.92-1.5x-y (BZN) thin films was achieved on (100)(pc) LaAlO3 substrate by pulsed laser deposition (PLD) and by chemical solution deposition based on Pechini process. Effect of bismuth and zinc deficiency on the BZN thin films obtained by PLD was discussed, in relation with the starting target composition. Dielectric permittivity and bandgap values were determined from electrical and spectroscopic ellipsometry measurements performed on randomly oriented films grown on Pt/Si substrate. BZN thin films obtained by PLD exhibit, at 100 kHz, a dielectric constant of epsilon(r) = 203 and quite low dielectric losses of tan delta = 5 x 10(-2). Epitaxial ferroelectric - dielectric KTa0.65Nb0.35O3 (KTN) -Bi1.5-xZn0.92-yNb1.5O6.92-1.5x-y (KTN on BZN and BZN on KIN) bilayers were obtained by PLD on (100)(pc) LaAlO3 with the insertion of a suitable buffer layer of KNbO3 in the case of KTN on BZN. Such multilayer heterostructures with an epitaxial growth control of each layer are promising candidates for potential integration in microwave devices. (C) 2011 Elsevier B.V. All rights reserved.

2430. Interactions of exotic particles with ordinary matter

Authors: Lazanu, I; Lazanu, S

Published: MAY 1 2012, NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 278, 77, DOI: 10.1016/j.nimb.2012.02.008

Weakly interacting massive particles (WIMPs) and strangelets are two classes of "exotic" particles not yet discovered, and in agreement with theoretical scenarios most probably produced in different early stages of evolution of the Universe. Some peculiarities of their energy loss in the electronic and nuclear interactions with ordinary matter are investigated. For the direct detection of WIMPs the signals produced by the stopping of recoils in matter are used for their identification. The influence of the orientation of the recoil in respect to crystal axes for crystalline silicon (as material for detectors) is analysed as average quantities: energy loss, and as transient thermal effects. For strangelets, the mechanisms of picking-up neutrons during their penetration into matter and the effects on electronic and nuclear stopping are considered. The clarification of the aspects related to the stopping of these hypothetical particles in matter will permit a better interpretation of some experimental results and could also contribute to the search for new techniques or materials for their detection, if they exist. (C) 2012 Elsevier B.V. All rights reserved.