National Institute Of Materials Physics - Romania

The synthesis of a new garnet, Er3Li0.275Nb0.275Ga4.45O12 (ErLNGG), by solid-state reaction, is reported. A comparison of the fluorescence spectra of Er3+ in ErLNGG and in Er-doped (5 at. %) Calcium Lithium Niobium Gallium Garnet (CLNGG) suggests an ordering of the partially disordered CLNGG when Ca2+ ions are completely substituted by Er3+ ions.

A designed experimental configuration for the simultaneous study of magnetization reversal and giant magnetoresistance effects in layered systems is reported. The suitability of the device, designed mainly for didactical purposes, to prove giant magneto-resistance effects is exemplified in case of exchange coupled spin valve structures. The multilayer structures were prepared by theromo-ionic vacuum arc methods and initially characterized by X-ray diffractometry and energy dispersive Xray spectroscopy. According to the performed experiments, it has been clearly proven the presence of magnetoresistance maxima ever ranges of applied fields inducing antiparallel magnetizations of the two ferromagnetic layers interfacing a thin conductive layer.

Chalcogenide phase change materials are one of the major contenders for the new non-volatile memory applications. Here is reported that the switching speed of Ge2Sb2Te5 is strongly dependent on the percent of defects in the material. Using cellular automata simulations it was shown that the size of the percolation cluster is minimum, thus the switching speed is maximum, for a percent of around 25% defects in the material. This is a property of the Ge2Sb2Te5 that can be useful for new phase change materials and devices design with better switching properties.

We present calculations on the transport properties of a double quantum dot (DQD) capacitively coupled to another individually biased dot. The effects of the intradot and interdot Coulomb interaction are included within the random-phase approximation (RPA) implemented in the Keldysh formalism. We show that by increasing the bias on the nearby dot the inelastic Coulomb scattering modifies the current in the double dot. The sign of the current depends on the detuning of the double dot levels and intradot transitions lead to negative differential conductance. The enhancement of the current due to the energy quanta transferred from the strongly biased dot suggests a quantum ratchet or Coulomb drag mechanism.

A series of xSnO(2)-(1-x)alpha-Fe2O3 (x=0.0-1.0) was prepared by a hydrothermal route starting with an aqueous mixture of iron (III) chloride hexahydrate, FeCl3 center dot 6H(2)O, and tin (IV) chloride pentahydrate, SnCl4 center dot 5H(2)O. The as resulted nanoscaled powders have been investigated by X-ray diffraction (XRD) and Sn-119 Mossbauer spectroscopy in transmission geometry and conversion electron. Under x = 0.300, the spectra reveal the appearance of magnetic hyperfine induced structure. At x = 0.300, the spectrum shows a magnetic phase (M) with the percentage of about 17%. The appearance of hyperfine magnetic fields suggests the location of the nonmagnetic Sn4+ ions, surrounded by the Fe3+ ions, in the interstitial and substitutional sites of alpha-Fe2O3 phase. On the other hand, the dependence of the total spectrum areas, vs. molar concentration x, displays a jump around x similar to 0.45, suggesting a change of the characteristic Debye temperature in the Mossbauer factor. The reported spectra have been fitted and the obtained hyperfine parameters are discussed in terms of reduced dimensional effects, super-transferred hyperfine interactions (STHI) and magnetic hyperfine field distribution (MHFD).

A new synthesis method for 70Ga(2)S(3)30La(2)S(3) (GLS) lanthanum based glass, which uses a RF-heating inductor, has been developed. The method gives the possibility to quench the melt without taking the crucible out of the reaction chamber. Glasses with good optical quality were obtained. The samples characterized by X-ray diffraction prove the amorphous state. The re-heating of GaLaS at temperatures of 620 degrees C leads to the appearance of large 30-80 mu m crystals, Ga3La1.66S7 structure being the main crystal form. High quality GLS thin films have been obtained by RF sputtering. The calculated refractive index was 2.48 for the thin films obtained by RF sputtering and 2.55 for bulk samples. Two kinds of the Urbach-density of state distribution are distinguished from optical transmission measurements corresponding to activation energies of 0.12 eV and 0.66 eV.

Electrochemical behavior of hemin on p-GaAs(1 0 0) electrodes was examined by cyclic voltammetry (CV) and impedance spectroscopy (EIS) in phosphate buffer solutions (PBS) at pH 7.45. CV investigations in 0.6 mM hemin in PBS revealed a pair of reversible peaks at -0.44 and -0.32 V vs. SCE resulting in stable adsorbed species. EIS spectra analysis pointed out that these adsorbed species bring significant changes in the semiconductor surface state population and the potential drop distribution between the semiconductor space charge region and the Helmholtz layer. (C) 2010 Elsevier Ltd. All rights reserved.

The first step of the smartcut (TM) process consists in inducing structural defects below the free surface of a silicon wafer, usually by implantation of light elements, such as hydrogen or helium. An alternative way to induce subsurface defects is by plasma treatment. In this work, we present a morphological and structural study on silicon wafers submitted to hydrogen plasma treatment, using two plasma-processing geometries. The parameters of the plasma treatment have been varied in order to limit the surface roughness and to confine the induced defects in a narrow region (50 nm) below the wafer surface. The morphological and structural investigations have been performed by AFM and TEM.

In this work, an improved version of the radio frequency magnetron sputtering (RF-MS) technique was used to prepare highly adherent B-type carbonated hydroxylapatite (B-CHA) thin films. Fourier transform infrared spectroscopy (FTIR) and grazing incidence X-ray diffraction studies proved that the coatings maintained the composition and revealed the polycrystalline structure of HA. Scanning electron microscopy analysis showed that the CHA films are rough and exhibit a homogeneous microstructure. Energy-dispersive Xray spectroscopy (EDX) mapping demonstrated a uniform distribution of the Ca and P cations while a Ca/P ratio of 1.8 was found. In addition, the FTIR experiments showed a remarkable reproducibility of the nanostructures. Human mesenchymal stem cells (hMSCs), in vitro differentiated osteoblasts, and explanted bone cells were grown over the surface of CHA coatings for periods between a few hours and 21 days. Osteoprogenitor cells maintained viability and characteristic morphology after adhesion on CHA coatings. Ki67-positive osteoblasts were the evidence of cell proliferation events. Cells showed positive staining for markers of osteoblast phenotype such as collagen type I, bone sialoprotein and osteonectin. Our data showed the formation of mineralized foci by differentiation of hMSCs to human primary osteoblasts after cultivation in osteogenic media on RF-sputtered films. The results demonstrate the capacity of B-type CHA coating to support MSCs adhesion and osteogenic differentiation ability. (C) 2010 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 95A: 1203-1214,2010.

Many nanovectors used for therapy (drug targeting radiation therapy) or diagnostic such as Magnetic Resonance Imaging (MRI) have a composite structure consisting of an organic core or organic coverage encapsulating magnetic nanoparticles and they are commonly dispersed in liquid suspensions for intravenous injection Here is presented the application of a new Environmental Scanning Electron Microscopy (ESEM) mode in transmission so called Wet-STEM for transmission imaging of droplets of such suspensions This is illustrated by Wet-STEM images from PLLA/Re nanospheres (about 100-300 nm in diameter) loaded with magnetite nanoparticles (about 10 nm in diameter) and from iron oxide core (about 5 nm in size) MRI contrast agents both examples in aqueous suspensions It is shown that the Wet STEM mode allows both the collective behavior of such nanovectors in suspension to be characterized and the inner composite structure of individual vectors to be revealed Such experimental results are discussed by comparison with Monte Carlo computer simulations of the distribution of the electrons scattered through the samples in rather large solid angles (between 20 degrees and 47 degrees) corresponding to the detection conditions (C) 2010 Elsevier Inc All rights reserved