Publications

Smooth, transparent and highly oriented nanostructured ZnO films were synthesized by RF-magnetron sputtering onto Si(100) substrates. A mild-pressed zinc oxide powder target was used for all depositions. The sputtering parameters were varied in order to obtain structures with good adherence and crystallinity. The depositions were carried out in inert argon atmosphere at four sputtering pressures (0.2 Pa, 0.25 Pa, 0.3 Pa and 0.45 Pa). ZnO films were deposited at 150 degrees C. The films were characterized from structural (XRD) and morphological (AFM) point of view. The influence of each sputtering parameter on the morphological and structural properties is discussed.

In this study, copper sulfide CuS (covellite) was obtained, starting from the Cu(CH3COO)(2)center dot H2O and thiourea ((NH2CSNH2) system, and working in presence or absence of sodium-bis(2-ohylhexyl) sulfosuccinate (Na-AOT). Samples obtained from Cu(CH3COO)(2)center dot H2O:NH2CSNH2:Na-AOT system were deposited as thin films on the glass substrates. CuS samples obtained were characterized by X ray diffraction, IR spectroscopy, TEM transmission electron microscopy and SAED - selected area electron diffraction. The influence of surfactant on the shape and size of CuS (covellite) nanocrystals was established.

The Ba1-xPbxNd2Ti5O14 ceramic material (BNT) is very attractive for applications at frequencies around few GHz [1]. The temperature coefficient of the resonant frequency T-f decreases from + 70 ppm/degrees C to - 15 ppm/degrees C with the Pb content x increase up to 0.5. The samples with high Pb content exhibit a dielectric constant up to 86.6, but the product Q x f is several times lower than for such microwave ceramics as zirconium tin titanate [1-2]. When a product Q x f higher than 6000 is required in order to use the BNT materials at high frequencies, then the Pb content can result from the tradeoff between small temperature coefficient T-f and high quality factor Q. The features of the BNT dielectric resonators lead to the development of miniaturized dielectric resonator antenna (DRA) with improved characteristics. The DRAs of BNT ceramics presented in this paper exhibit an increased bandwidth due to an optimal height over diameter ratio. For an increased gain and shaping of the overall radiation pattern, an array of dielectric resonator antennas is proposed.

The effect of nitrogen (N) introduced by ion implantation at the SiO2/4H-SiC interface on the capacitance of the MOS capacitors is investigated. The Thermal Dielectric Relaxation Current (TDRC) technique and Capacitance-Voltage (C-V) measurements performed at different temperatures and probe frequencies on an N implanted sample and on a virgin sample were employed for this purpose. There are three types of defects located at or near the interface, D-it, NIToxfast and NIToxslow that can be distinguished. Only D-it and NIToxfast respond to the a.c. small, high frequency signal at temperatures above 150K. The separation of D-it from the NIToxfast states have enabled us to study the influence of the excess of interfacial Nitrogen on each of the mentioned defects. It has been found that the N-implantation process fully suppresses the formation of NIToxfast and partially NIToxslow and D-it. Theoretical C-V characteristics were computed, based on the defect distributions determined by TDRC, and compared with the experimental ones showing a close agreement.

Rolled-up nanostructures formed from lattice mismatched III-V heterojunction films by taking advantage of a strain-induced self-rolling mechanism represent a useful type of building blocks for nanotechnology, with possible applications in high-speed microelectronic and optoelectronic devices. This work investigated the effect of illumination on the hydrofluoric acid etching of AlAs sacrificial layers with systematically varied thicknesses in order to release and roll up MBE grown InGaAs/GaAs bilayers. Based on this "etch suppression effect" (ESE), we propose an illumination-assisted technique that offers an advantage over other methods of rolling up nano-objects on a substrate from inherently strained films because it allows control over the positioning of rolled-up micro- and nanotubes independently from lithographic methods. For thicknesses of AlAs below 10 nm, we found two etching regimes for the area under illumination: one at low illumination intensities, in which the etching and releasing proceeds as expected and one at higher intensities in which the etching and any releasing are completely suppressed. The "etch suppression" area is well defined by the illumination spot, which can be used to realize well-controlled heterogeneously etched regions on the same sample.

The low frequency collective movements of proteins associated with biologically relevant conformational transitions are situated in the terahertz (THz) spectral region. THz spectroscopy experiments have revealed that each molecular species has a unique absorption pattern in THz domain. We used time-domain THz spectroscopy (TDS) to study the conformation and flexibility of bovine serum albumin (BSA), a protein whose 3D structure is unknown. We performed THz spectroscopy experiments on lyophilized BSA. Theoretical spectra were obtained by normal modes analysis performed on BSA structures generated by homology modeling and molecular dynamics simulations. The agreement between experimental and theoretical data allowed us to validate the model of BSA and also to gain insight into BSA vibrations in THz domain.

Barium neodymium titanate (BNT) material was prepared and characterized. The very high dielectric constant, high Qxf product and controllable temperature coefficient recommend the BNT material for microwave applications. Slot coupled antennas with BNT resonators are investigated. The resonator shape effect on the antenna bandwidth is discussed.

A strong focus on Superparamagnetic Iron Oxide Nanoparticles (SPIOs) has been appreciated recently especially for their use in Magnetic Resonance Imaging (MRI). However, some questions are being raised over these particles due to their long-term toxicity related to the production of toxic free iron during their biodegradation. Here we show by Electron Microscopy how SPIOs (P904) (Guerbet, Paris) are degraded after they are taken up by macrophages, so that iron from the SPIO core is progressively incorporated into the iron-storing protein ferritin (a nontoxic form of iron).

In this paper we present a resonant antenna based on a composite right/left handed metamaterial structure. The antenna is designed to operate at the zero-order resonance. The antenna was fabricated and used in measuring the coverage of a UMTS cell.

3-[2-(dimethylamino) ethyl]-6-nitroquinazolin-4(3H)-one, labeled BG1188, is a new synthesized compound, out of a series of quinazoline derivatives developed to fight the multidrug resistance of antibiotics acquired by bacteria. A characterization of the BG1188 powder was made using FTIR spectra in order to evidence the functional groups in the medicine's molecule. The ultraviolet-visible (UV-Vis) absorption spectra were used to study the stability of the BG1188 solutions in two solvents and at different temperatures. BG1188 concentration in ultrapure water was varied between 2x10(-3)M (stock solution) and 10(-6)M. The concentration recommended by higher activity on bacteria was 10(-3)M. For the same reason, this was the utilized concentration of BG1188 in dimethyl sulfoxide (DMSO). Time stability was characterized by comparing the time evolution of the UV-Vis absorption spectra of the BG1188 solutions in ultrapure deionized water or in DMSO. The spectra were recorded daily for about 4 months after the preparation for the BG1188 solutions in ultrapure water. Generally, samples are stable within the experimental errors at concentrations higher than 10(-5)M, but the stability time interval may vary from 119 days at 10(-4)M to 34 days at 10-5M. Time evolution of the absorption spectra at 10-3M in ultrapure water shows reproducibility within the measuring errors (+/- 1.045%) for time intervals up to 1032 hours (more than 40 days) after preparation. On the other hand, BG1188 solutions in DMSO may be considered unstable because the absorption spectra modify in terms of peak shapes and intensities, indicating that the samples exhibit modifications immediately after preparation. Regardless the solvent used, some aggregation phenomena took place and wire-like aggregates were observed in all the solutions with the naked eye. These aggregates were analyzed, tentatively, using optical microscopy and FTIR.