Publications

Recent studies of mechanically alloyed Fe-Cu powder mixtures have suggested differences in the local magnetic environment of iron atoms. For a more accurate definition of this point, ball-milled Cu70Fe30 and Cu50Fe50 alloys were investigated by Mossbauer spectroscopy in the, temperature range 4.2-300 K. The low temperature Mossbauer spectra exhibit a broad magnetic pattern. typical of a defect structural configuration. The magnetic splitting strongly decreases with increasing temperature, especially in the case of Cu70Fe30 alloy. But even for this composition there is, at room temperature, an unresolved magnetic pattern. Applying a magnetic field of 3 T, parallel to gamma rays, at 4.2 K a rotation of all magnetic moments along the external field is observed. The samples behave as an alloy with continuously distributed local fields. (C) 2001 Elsevier Science BY. All rights reserved.

The high resolution spectroscopic and emission decay properties of Nd:YAG ceramics with up to 9 at.% Nd show that no major changes from the single crystals other than those induced by the increased Nd concentration occur and indicate that these materials can be used for construction of efficient and high power lasers. The laser emission of a 3.8 at.% Nd ceramic laser component under hot band resonant pump at 885 nm with a Ti:sapphire laser is demonstrated. (C) 2001 Elsevier Science B.V. All rights reserved.

The magnetic interactions between the nanograins in heterogeneous granular Cu-(SmCo5)-Fe ribbons were evaluated with a classical mean field model to obtain the exchange coupling as well as the magnetic moment per nanoparticle. The samples were subjected to various thermal treatments and a significant magnetoresistive effect was obtained when the optimal annealing conditions had been achieved. (C) 2001 Elsevier Science B.V. All rights reserved.

We consider semiconductor devices composed of a small quantum structure as the active device region and two classical environments constituting the source- and the drain contact. The contacts are taken as free electron gases with infinite conductivity defining the chemical potentials in the contacts. The transport through the quantum structure is described in the Landauer-Buttiker formalism using electronic scattering wave functions which determine the electron density in the quantum system. In our Hartree approximation these charges and the induced charges in the contacts are the sources of the self-consistent Coulomb field. As a particular quantum structure we study a GaAs heterostructure device consisting of a two-dimensional electron gas sandwiched between a gate contact and an AlGaAs blocking barrier [see V.T. Dolgopolov ct al., Phys. Low-Dim. Struct. 6 (1996) 1]. We demonstrate the quantitative agreement of our theory with the experimental results. (C) 2001 Elsevier Science B.V. All rights reserved.

The Letter presents an attempt to include the concentration dependence in the Landau-de Gennes theory for the nematic to isotropic phase transition for nematic lyotropic liquid crystals by introducing a critical concentration for the lyotropic solutions. This allows to describe phase transitions of micellar solutions as depending on temperature and concentration. An estimation of phenomenological coefficients of the CsPFO/water system is made, and we obtained the trends of the order parameter curves in function of temperature and concentration in good agreement with experimental results from literature. (C) 2001 Elsevier Science B.V. All rights reserved.

Polycrystalline diamond thick films were subjected to annealing in vacuum at temperatures of 1350-1450 degreesC. The films were examined by optical absorption, Raman spectroscopy, transmission electron microscopy and electron energy loss spectroscopy. The formation of amorphous carbon and/or of well-crystallized graphite layers up to 20 nm thick was evidenced along grain boundaries. Intra-granular nanometer-sized graphite islands were also observed, sometimes as transformed micro-twin bands. The diamond-to-graphite transition occurs in such a way that three (111) diamond planes transform into two (0002) graphitic sheets. The internal graphitization causes a severe degradation of the optical quality of the diamond films.

The CO consumption of tin dioxide, thick film sensors and their sensor signals have been investigated in order to study the GO-water interaction on the SnO2 surface. The mechanism of CO combustion, and the influence of the sensor's operation temperature (200-400 degreesC) and ambient humidity (0-50% r.h.) on the combustion has been characterised in detail. Here, the overall CO consumption of the sensors has been divided according to the contributions of the various individual sensor parts: alumina substrate; electrodes: heater; and the SnO2 based sensitive layer. It can be shown that CO combustion is a linear function of CO concentration. The influence of the substrate on total CO consumption has been proven to be significant. (C) 2001 Elsevier Science B.V. All rights reserved.

An Fe+-type center with axial (001) symmetry has been studied by electron nuclear double resonance (ENDOR) in the microwave X and Q bands. The Fe+(I) center is produced only after irradiation with x or gamma rays at 80 K of SrCl2:Fe2+ crystals grown in a Cl-2 atmosphere. It has a 3d(7) F-4 Gamma (8) ground state with spin S =3/2. As shown by the correlated analysis of the ENDOR data and electron paramagnetic resonance superhyperfine structure, the Fe+ ion is situated in the center of a tetragonally compressed cube of eight nearest Cl- ions. The simplest model of the Fe+(I) center, compatible with the magnetic resonance results, consists of an interstitial Fe+ ion with two substitutional monovalent cations, very likely K+ ions, in two opposite nearest-neighbor Sr2+ sites along the tetragonal axis of the center.

The formation of Ni silicides is studied by transmission electron microscopy during in situ heating experiments of 12 nm Ni layers on blanket silicon, or in patterned structures covered with a thin chemical oxide. It is shown that the first phase formed is the NiSi2 which grows epitaxially in pyramidal crystals. The formation of NiSi occurs quite abruptly around 400 degreesC when a monosilicide layer covers the disilicide grains and the silicon in between. The NiSi phase remains stable up to 800 degreesC, at which temperature the layer finally fully transforms to NiSi2. The monosilicide grains show different epitaxial relationships with the Si substrate. Ni2Si is never observed. (C) 2001 American Institute of Physics.

The RD48 (ROSE) collaboration has succeeded to develop radiation hard silicon detectors. capable to withstand the harsh hadron fluences in the tracking areas of LHC experiments. In order to reach this objective, a defect engineering technique was employed resulting in the development of Oxygen enriched FZ silicon (DOFZ), ensuring the necessary O-enrichment of about 2 x 10(17) O/cm(3) in the normal detector processing. Systematic investigations have been carried out on various standard and oxygenated silicon diodes with neutron, proton and pion irradiation up to a fluence of 5 x 10(14)cm(-2) (1 MeV neutron equivalent). Major focus is on the changes of the effective doping concentration (depletion voltage). Other aspects (reverse current, charge collection) are covered too and the appreciable benefits obtained with DOFZ silicon in radiation tolerance for charged hadrons are outlined. The results are reliably described by the "Hamburg model": its application to LHC experimental conditions is shown, demonstrating the superiority of the defect engineered silicon. Microscopic aspects of damage effects are also discussed. including differences due to charged and neutral hadron irradiation. (C) 2001 Elsevier Science B.V. All rights reserved.