National Institute Of Materials Physics - Romania

MgB2 has great potential for many applications, thanks to its relatively high critical temperature and low fabrication cost. Large efforts are done to improve the current carrying capabilities of bulks and tapes in view of different application fields, e.g. with the addition of Te and cubic-BN to MgB2. To elucidate the vortex pinning physics exploiting a different dynamic regime, we present here a microwave study of the pinning properties of spark plasma sintered bulk MgB2 with and without the addition of 0.01 % at. Te or cubic-BN. We show the surface resistance R-s of the MgB2 samples measured with a dielectric-loaded resonator at similar to 16.5 GHz and similar to 26.7 GHz in the 10 K-Tc temperature range at fields up to 1.0 T. Then, the MgB2 R., is studied with high frequency vortex motion models in order to obtain the pinning constant (Labusch parameter) and the depinning frequency. Finally, the microwave behavior of MgB2 in the mixed state is compared with the recent results obtained on Nb3Sn.

Neoplastic disease has multifactorial etiology and insidious evolution which make it unlikely to be detected in early stages and very difficult to treat at later times. The effectiveness of standard therapeutic approaches is limited by severe adverse effects, metastasis, and tumor capacity to develop multidrug resistance. The success of inorganic nanomaterial-based therapeutic agents depends on the degree to which these nanostructures satisfy general requirements for drug safety regarding biocompatibility, biodegradability, and stability and on their antitumor efficacy. Fabrication of such nanomedicines requires adequate assessment and engineering of nanomaterial physicochemical characteristics like particle size, specific surface area, surface charge, hydrodynamic size, and magnetic, optical, and photocatalytic properties. Together with surface functionalization and delivery method, these properties dictate the in vivo "biological identity" of the nanomaterial and its fate with respect to cellular uptake and distribution/accumulation inside the body. We reviewed recent literature on interdisciplinary studies regarding applications of inorganic nanomaterials in the treatment of cancer. The major functions that inorganic nanomaterials can play in cancer therapy are: 1. Nanocarriers for therapeutic agents and active targeting ligands for molecules overexpressed on tumor tissues as well as for altered signal transduction pathways. Inorganic nanomaterial-based therapeutic agents are able to reduce tumor growth acting on neoplastic vasculature (by inhibiting angiogenesis, vasculogenesis, and vasculogenic mimicry) or on malignant cells (blocking activation of overexpressed receptors and their specific signaling pathways, inducing oxidative stress, and reducing multidrug resistance). Moreover, inorganic nanomaterials are able to inhibit tumor invasiveness and metastasis by reducing degradation of extracellular matrix, exosome secretion, and cell proliferation at the secondary site. 2. Contrast agents and medical adhesives in cancer surgery: (i). Vital staining of sentinel lymph nodes (SLNs) where the first metastasis appears - the use of carbon nanoparticles, single-walled and multilayer carbon nanotubes, or superparamagnetic iron oxide nanoparticles was associated with a significantly higher number of harvested SLNs in breast and cervical tumors, lung cancer, papillary thyroid carcinoma, and prostate carcinoma. (ii). Nanoparticle-based medical adhesives used for surgical wound closure aqueous suspensions of iron oxide and silicon dioxide nanoparticles were shown to rapidly connect highly vascularized tissues (e.g., liver). 3. Inorganic sensitizers for radiotherapy - gold nanoparticles were reported to significantly enhance the efficiency of ionizing radiation and induce targeted cancer cell apoptosis, tumor growth inhibition, and increases of survival rates in tumor-bearing mice. 4. Antitumor agents based on specific material properties like surface plasmon resonance (photothermal heating), magnetic responsiveness (magnetic hyperthermia), and photocatalysis (photodynamic therapy) - heat generated by plasmonic (gold-based) or magnetic (iron oxide-based) nanomaterials exposed to laser light or alternating magnetic fields, respectively, was shown to efficiently destroy tumors in mouse models or leads to promising results in clinical trials; the antitumor action of photoactivated TiO2-based nanomedicines was assessed in numerous in vitro and several in vivo studies. 5. Adjuvant therapy (iron replacement therapy) - iron oxide colloids (IOC) are more efficient than free iron in treating iron-deficient anemia associated with cancer. Overall, inorganic-organic therapeutic nanoplatforms provide enhanced treatment efficiency, reduced adverse effects, multiple antitumor action mechanisms, facile cell internalization, and diminished multidrug resistance.

Indium-doped tin oxide (ITO) thin films were fabricated by radio frequency magnetron sputtering and were subjected to in-situ and ex-situ annealing, at 200 degrees C, 300 degrees C and 400 degrees C, respectively. The in-situ thermal treatment consisted to intentionally heating the samples' substrates, while the ex-situ annealing was performed using an oven, under ambient atmosphere. For the ITO samples subjected to ex-situ annealing, the density of oxygen vacancies increased leading to the decrease of the electrical resistivity. No significant changes were noticed in terms of transmission spectroscopy after the thermal treatment; while by evaluating the Skewness parameter was determined that the annealing improves the planarity of samples' surface.

MgB2 bulk superconductors are expected to be utilized as rare-earth-free and lightweight trapped field magnets. However, the flux jumps frequently happen during the magnetizing processes, and heavily degrade the field-trapping performances. We have investigated the effect of additives to the MgB2 bulk samples prepared by spark plasma sintering process, and observed various flux jumps during the pulsed field magnetizing processes, which were carried out at 14 K which was obtained by the 2-stage GM cryocooler. The authors classified the flux motions as three categories as "no flux flow", "fast flux flow", and "flux jump" regions, and investigated the conditions where the flux jumps happen. We observed some drastic flux jumps in the pristine and clarified the effect of graphene addition to the flux jumps. The experimental results showed us a possible expansion of no flux jump region, and suggested us the improvement of field trapping capability.

This paper presents the methodology and reports the results concerning the Laser Induced Damage Threshold (LIDT), surface quality and group delay dispersion (GDD) measurements of large aperture femtosecond laser mirrors, achieved in a project funded by IFA under the contract number 02 ELI/18.10.20.17., having, as a main goal, the manufacturing of large aperture mirrors (150mm effective diameter) and tests performing for use in high energy ultra-short pulse laser systems, such as ELI-NP and CETAL infrastructures. The manufacturing process of the mirror substrates was described in a previous paper [1] and the coating technology will be presented in a future article. The novelty of this paper consists, mainly, in the method, experimental arrangement and test procedure to determine the Laser Induced Damage Threshold (LIDT) but also in the entire testing protocol, including Group Delay Dispersion (GDD) and other measurements presented here.

The morphological and structural properties of the poly(vinyl chloride)/graphene oxide (PVC/GO) composites are reported. By the mixture of the two constituents, the PVC/GO composite membranes with a concentration of the GO sheets varying from 0 wt.% to 0.5, 1, 2, 3, 4 and 5 wt.% were prepared. Using scanning electron microscopy (SEM) and the analysis of the atomic force microscopy (AFM) images we observed that as increasing the GO concentration in the PVC mass from 0 wt.% to 5 wt.%, the average surface roughness decreases from 235 mu m to 227 mu m. Using Raman scattering, we report that as increasing the GO concentration in the PVC mass, the ratio between the relative intensities of the Raman lines situated in the spectral ranges 600-650 and 2850-3000 cm(-1) (I600-650/I2850-3000) increases as a consequence of the change of GO carbon atoms hybridization from sp(2) to sp(3). An increase in the number of C-C bonds, simultaneous with the appearance of O-C=O bonds and the decrease of the chlorine concentration, when the GO concentration increases in the PVC weight is reported by X-ray photoelectron spectroscopy (XPS). The down-shift of the main diffraction signal from 24 degrees to 26 degrees when the GO concentration increases in the PVC/GO composite mass from 0 wt.% to 5 wt.%, confirms the incorporation of GO in the polymeric matrix and the modification of the original PVC sample structure. Using transmission electron microscopy (TEM), no agglomerations of the GO structures within the PVC/GO matrix contrast limit were observed.

Polymer Dispersed Liquid Crystal (PDLC) films are composite materials consisting of LC droplets embedded in polymers. In order to decrease the switching voltage of these devices, we prepared PDLC films doped with single wall carbon nanotubes (SWCNTs). The mesomorphic properties of the films were investigated by polarizing optical microscopy (POM). The electrical characteristics have been investigated using a Broadband Dielectric Spectrometer in a frequency domain (0.01-10(7)) Hz and a temperature range (280-350) K. Some key aspects of an optical model for the analysis of the coherent transmittance of PDLC - NP films are presented.

The latest decades presented a large development of various size and types of Unmanned Aerial Vehicles (UAVs). Nowadays, there are over 200 million UAVs used in various applications and there it is a large effort to adopt national and international regulation for using them. There it is a real need for the development of a reliable system for UAVs identity verification that can be implemented and used at global level. To this moment the software-based methods such as MAC address, IDs memorized on devices are prone to a large number of cyber-security vulnerabilities and attacks. This paper presents an innovative hardware-based identification solution which could be adapted to UAVs in a non-intrusive manner. The proposed solution is based on physical unclonable functions (PUF), which are implemented by using memristors. The proposed solution is very low cost and high performance. By using memristors, it is possible to generate a very large number of unclonable IDs, using only a few electrical components. This solution could be incorporated in any UAVs systems without major modifications and not affecting their flight parameters.

In this paper an IGZO memristor with multiple states and analog tuning extended capability is reported. The device has a planar structure and is fabricated by magnetron sputtering on glass substrate. The device resistance could be gradually increased and decreased within the range of one order of magnitude. Larger resistance changes are also possible but they are mostly irreversible. The obtained memristor looks promising to be used as electronic synapse in hardware implemented artificial neural networks or for applications in analog computing and cryptography.

Carbon-Titanium multilayer thin films were obtained by Thermionic Vacuum Arc (TVA) method. The nanostructured films consisting by 100nm Carbon base layer and seven 40nm alternatively Titanium and Carbon layers were deposed on Silicon substrate. As well, to give C-Ti multilayer films with different percentages in Ti and C of layers, a 100nm thick Carbon base layer was deposed on Si substrate, and then seven Ti-C layers, each of these having thickness of 40nm. In order to achieve the successively layers with C, and Ti different percentages, were adjusted the discharge parameters of C and Ti plasma sources to obtain the desired composition of layers. Also, were obtained composite films having a variable C: Ti atomic ratio 9:1 at interface to 1:9 at the surface. By changing of substrate temperature from room temperature to 100 degrees C, 200 degrees C, 300 degrees C, 400 degrees C respectively, and on the other hand the bias potential up to -700V, different batches of samples were obtained. Characterization of structural properties of films was achieved by Electron Microscopy technique (TEM, STEM) and GIXRD techniques. The measurements show that increase of the substrate temperature reveal changes in TixCy lattice parameters. Thus, according to GIXRD analysis it was found out that the Ti:C atomic ratio changes with increase of synthesis temperature. Also, in the case of composite films an increase of amount and sizes of TiC nanocrystals with the increase of energy of Ti ions determined by increase of bias voltage was observed. The tribological measurements were performed using a ball-on-disk system with normal forces of 0.5, 1, 2, 3N respectively. Was found that the coefficient of friction depends on the synthesis temperature and on the bias voltage. It is also noted that the friction coefficient depends on the pure C content, Ti content and amount of TiC nanocrystallites. These results are due to atomic diffusion at Ti/C interfaces and also are associated with amount of TiC nanocrystallites. To characterize the electrical conductive properties, the electrical surface resistance versus temperature have been measured, and then the electrical conductivity is calculated. Using the Wiedemann-Frantz law was obtained the thermal conductivity.