National Institute Of Materials Physics - Romania

The absorption and photoluminescence (PL) spectra, PL decays, Raman spectrum, cyclic voltammetry (CV) and nuclear magnetic resonance of heteroleptic Ir-compound IrQ(ppy)(2) compound with two phenylpyridine (ppy) ligands and one quinoline (Q) ligand have been investigated experimentally and theoretically. Two very weak absorption bands due to the transitions to the triplet states are found at about 560 and 595 nm in IrQ(ppy)(2) doped in CH2Cl2 solution. IrQ(ppy)(2) exhibits a dual emission of red and green phosphorescence bands. The red emission intensity is much higher than the green one in IrQ(ppy)(2) powder, but much lower than the green one in lightly IrQ(ppy)(2)-doped CH2Cl2 solution and PMMA film. The intensity ratio of the red emission to the green emission, however, is observed to increase with increasing the IrQ(ppy)(2) concentration in CH2Cl2 solution and PMMA film. The enhancement of the red emission is suggested to be caused by the Forester energy transfer from Ir-ppy component to Ir-Q components between two neighboring IrQ(ppy)(2) molecules. The HOMO energy is estimated to be -4.865 eV from the CV measurement, which is close to the HOMO energy of -4.844 eV calculated using the time dependent density function theory (TD-DFT). The LUMO energy is estimated as -2.856 eV from the HOMO energy and the long-wavelength absorption edge found at 617 nm in the absorption spectrum. The absorption spectrum of IrQ(ppy)(2) is calculated by the TD-DFT. Discussion is given on a deviation of the calculated spectrum from the measured spectrum. (C) 2015 Elsevier B.V. All rights reserved.

The recent observation of a fundamental direct bandgap for GeSn group W alloys and the demonstration of low temperature lasing provide new perspectives on the fabrication of Si photonic circuits. This work addresses the progress in GeSn alloy epitaxy aiming at room temperature GeSn lasing. Chemical vapor deposition of direct bandgap GeSn alloys with a high Gamma- to L-valley energy separation and large thicknesses for efficient optical mode confinement is presented and discussed. Up to 1 mu m thick GeSn layers with Sn contents up to 14 at. % were grown on thick relaxed Ge buffers, using Ge2H6 and SnCl4 precursors. Strong strain relaxation (up to 81%) at 12.5 at. % Sn concentration, translating into an increased separation between Gamma- and L-valleys of about 60 meV, have been obtained without crystalline structure degradation, as revealed by Rutherford backscattering spectroscopy/ion channeling and transmission electron microscopy. Room temperature reflectance and photoluminescence measurements were performed to probe the optical properties of these alloys. The emission/absorption limit of GeSn alloys can be extended up to 3.5 mu m (0.35 eV), making those alloys ideal candidates for optoelectronics in the mid-infrared region. Theoretical net gain calculations indicate that large room temperature laser gains should be reachable even without additional doping.

Homogeneous hybrids in which iron oxide nanoparticles are entrapped within polymer structure are of interest for their potential applications in biomedical field, such as diagnostic, therapeutic and theranostic purposes. For this reason, hybrid nanomaterials based on branched polyethyleneimine (PEI) and iron oxide with different ratios were synthesized in a single step by hydrothermal procedure at high pressure and low temperature. Iron oxide is formed in the presence of branched PEI and the interaction between them takes place in the reaction medium. The influence of synthesis parameters on the hybrid formation, as well as chemical and structural properties was studied by means of FTIR, DSC-TG, HRTEM, electron paramagnetic resonance (EPR), magnetic measurements (SQUID) and Fe-57 Mossbauer analyses. It has been shown that synthesis parameters influence thermal stability and morphology of the hybrids. FeO(OH) crystallites of 2-5 nm are formed. Iron oxyhydroxide nanoparticles strongly entrapped in PEI structure are obtained. The low and distributed values of the specific spontaneous magnetisation in samples prepared under the same pressure conditions support the presence of very fine FeO(OH) nanoparticles, which formation and magnetic properties are depending on the mass ratio between iron oxide and PEI. (C) 2015 Elsevier B.V. All rights reserved.

A phenomenological 2D model, simulating the martensitic transformation, is built upon existing experimental observations that the size of the formed plates - in direct transformation - decreases as the temperature is lowered; then they transform back in reversed order. As such, if a reverse transformation is incomplete (arrested), the subsequent direct one will show anomalously a large number of big size plates - old plus newly formed - but consequentially a depletion of intermediate sizes, due to geometrical constraints, phenomenon that generates thermal memory. (C) 2015 Elsevier Ltd. All rights reserved.

The current paper reports on a sonochemical synthesis method for manufacturing nanostructured (typical grain size of 50 nm) SrTi0.6Fe0.4O2.8 (Sono-STFO40) powder. This powder is characterized using X ray-diffraction (XRD), Mossbauer spectroscopy and Scanning Electron Microscopy (SEM), and results are compared with commercially available SrTi0.4Fe0.6O2.8 (STFO60) powder. In order to manufacture resistive oxygen sensors, both Sono-STFO40 and STFO60 are deposited, by dip-pen nanolithography (DPN) method, on an SOI (Silicon-on-Insulator) micro-hotplate, employing a tungsten heater embedded within a dielectric membrane. Oxygen detection tests are performed in both dry (RH = 0%) and humid (RH = 60%) nitrogen atmosphere, varying oxygen concentrations between 1% and 16% (v/v), at a constant heater temperature of 650 degrees C. The oxygen sensor, based on the Sono-STFO40 sensing layer, shows good sensitivity, low power consumption (80 mW), and short response time (25 s). These performance are comparable to those exhibited by state-of-the-art O-2 sensors based on STFO60, thus proving Sono-STFO40 to be a material suitable for oxygen detection in harsh environments.

We present the synthesis of tungsten nanoparticles using a gas aggregation cluster source based on a magnetron sputtering discharge. The nanoparticles have sizes between 70 and 100 nm and a dendritic morphology, with branches emerging from the center and evolving in a flower-like pattern. Structural investigations revealed the presence of alpha-W and residual beta-W crystalline phases. Post deposition oxidation of the nanoparticles is also investigated.

The aim of this paper is to present a reliable procedure for the experimental determination of the specific absorption rate (SAR) in case of superparamagnetic Fe oxide nanoparticles dispersed in liquid environments. It is based on the acquisition of consecutive steps of time-temperature dependences along of both heating and cooling processes. Linear fitting of these recorded steps provides the heating and cooling speeds at different temperatures, which finally allow the determination of the heating profile in adiabatic-like conditions over a broad temperature range. The presented methodology represents on one hand, a useful alternative tool for the experimental evaluation of the heating capability of nanoparticulate systems for magnetic hyperthermia applications and on the other hand, gives support for a more accurate modeling of bio-heat transfer phenomena.

The purpose of the present study is to develop novel nanocomposites based on diglycidylether of bisphenol A (DGEBA) combined with diglycidylether-terminated polydimethylsiloxane (DG-PDMS), reinforced with 10 wt.% (mono-/octa) epoxy POSS nanocages (MEP or OEP-POSS). DG-PDMS and POSS compounds were covalently incorporated into DGEBA resin via copolymerization of epoxy groups. The effect of both DG-PDMS and POSS nanoparticles on the curing reaction, glass transition temperature (T-g), thermal stability, hardness and morphology of DGEBA/DG-PDMS +/- POSS nanocomposites were studied by DSC, FTIR, DMA, TGA, SEM/EDX, AFM and contact angle measurements. SEM/EDX and AFM results prove that OEP-POSS is well dispersed within DGEBA/DG-PDMS polymer matrix, while MEP-POSS forms large POSS aggregates. The thermo-mechanical properties of POSS based nanocomposites are also in good correlation with morphology features. MEP-POSS based nanocomposite with heterogeneous dispersion of FOSS aggregates exhibits lower T-g value and thermal stability in comparison with OEP-POSS nanocomposite which exhibits a nanoscale dispersion of the PUSS cages. The obtained T-g of OEP-POSS based nanocomposite increases with 31 degrees C in comparison with the unreinforced matrix. Moreover, this nanocomposite shows the highest storage modulus (E') and hardness. (C) 2015 Elsevier Ltd. All rights reserved.

High aspect ratio CuO nanowires are synthesized by a simple and scalable method, thermal oxidation in air. The structural, morphological, optical, and electrical properties of the semiconducting nanowires were studied. Au-Ti/CuO nanowire and Pt/CuO nanowire electrical contacts were investigated. A dominant Schottky mechanism was evidenced in the Au-Ti/CuO nanowire junction and an ohmic behavior was observed for the Pt/CuO nanowire junction. The Pt/CuO nanowire/Pt structure allows the measurements of the intrinsic transport properties of the single CuO nanowires. It was found that an activation mechanism describes the behavior at higher temperatures, while a nearest neighbor hopping transport mechanism is characteristic at low temperatures. This was also confirmed by four-probe resistivity measurements on the single CuO nanowires. By changing the metal/semiconductor interface, devices such as Schottky diodes and field effect transistors based on single CuO p-type nanowire semiconductor channel are obtained. These devices are suitable for being used in various electronic circuits where their size related properties can be exploited. (c) 2015 AIP Publishing LLC.

Rh-m-TPPTC complex was successful immobilized onto a hydrotalcite Zn-Al to convert selectively in aqueous media both the symmetric and nonsymmetric alkynes into functionalized alkenes, with boronic acids. The complex preserved its activity after the ionic exchange, leading to excellent results (similar to 87%) for the symmetric alkynes and also for the non-symmetrical alkynes (up to 99%). (C) 2014 Elsevier B.V. All rights reserved.