National Institute Of Materials Physics - Romania

Hydrogen adsorption in Metal-Organic Frameworks is improved by using platinum and palladium on different carbon support: activated carbon or carbon nanofibres. Although, hydrogen adsorption is directly dependent of the specific surface area of the material, it is not the only factor contributing to the hydrogen adsorption, as presented in this work. Direct synthesis of metal-organic frameworks on supported Pt and Pd catalysts, reduces the surface area significantly, but the presence of the catalysts overcomes this drawback by improving hydrogen adsorption by a factor of 2.2, in case of platinum and by a factor of 1.4 in the case of palladium, compared to the metal-organic framework without catalysts.

Superconducting Y123 thin films with (001), (100/010) and (103/110) orientations were obtained by molecular-organic- source MBE (MOMBE) for optimum growth temperatures of 600, 515 and 600 degrees C, respectively, using a Ba(DPM)(2)(phen)2 source material and ozone atmosphere. Superconductivity was obtained without post processing. According to the literature, use of a Ba(DPM)(2)(phen)(2) precursor was expected to yield a lower optimum growth temperature, but there were no significant differences between the use of this source and a Ba(DPM)(2) precursor. For our c-axis oriented Y123 film, the optimum growth temperature was higher than the reported record-low growth temperature (500 degrees C by MOCVD using Ba(DPM)2(phen)2) but it was lower than the values for other growth techniques. This can have a positive impact on fabrication of layered devices or integration through the decrease of inter-diffusion between the layers. Results also suggest that processes are complex and other details than the source type should be carefully considered.

We report on an original technique for nanoengineered pinning centers that combine three previously reported approaches: substrate decoration, quasi-multilayers and targets with secondary phase nanoinclusions. We have used a 4% BZO-doped YBCO target, and Ag nanodots, all grown by PLD. Such an approach gave interesting results in terms of pinning landscape, as proved by TEM studies. Angle-dependent measurements of critical current I-c showed that, for smaller fields, the absolute maximum in I-c occur for fields perpendicular to the a-b planes, while at larger fields the absolute maximum in I-c occurs for fields parallel to the a-b planes, in both cases with a clear second, local maxima. Measurements also showed a smooth change in the character of pinning with magnetic field, from the out-of-plane to in-plane-dominant pinning. For the out-of-plane magnetic field, the highest Ic-w (critical current per cm width) obtained so far, at 77.3 K, occurred in a 5.8 mu m Ag nanodots / BZO-doped YBCO trilayer: 782 A/cm-w in self-field, 167 A/cm-w in 1 T and 18 A/cm-w in 3 T.

Photoluminescence (PL) and Raman spectroscopy were used to characterize the tin dioxide (SnO(2)) powder and the SnO(2)/single-walled carbon-nanotube (SWCNT) composites. The SnO(2) powder shows a strong PL broad band centered at 1.95 eV (635 nm) under excitation at 280 nm (4.43 eV) and four PL bands peaking at: 1.95 eV (635 nm), 2.67 eV (464 nm), 2.82 eV (439 nm), and 2.98 eV (416 nm) under excitation at 350 nm (3.54 eV). PL decay-time measurements of the SnO(2) powder indicates a PL lifetime of about 1.53 ns. In the SnO(2)/SWCNT composites, prepared mechanicochemically, a quenching of PL is observed as the concentration of SWCNT increases. The Raman spectra were recorded at two excitation wavelengths: 514.5 and 676.4 nm. At the excitation wavelength of 676.4 nm (1.83 eV), the Raman spectrum shows a narrowed asymmetric profile of the G band (similar to 1585 cm similar to 1), which indicates that in the SnO(2)/SWCNT composite there is an interaction between SnO(2) and metallic SWCNTs. (C) 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

We present the fabrication and the superconducting properties of MgB2 ceramic samples doped with carbon via preceramic polymers: linear and cyclic polysiloxane-co-styrene and linear polysiloxane-co-vinyl-ferrocene. The samples were produced using the spark plasma sintering technique. The use of polysiloxane copolymers was suggested by the appropriate content of carbon, silicon, and oxygen which are necessary to increase the upper critical field and to create pinning centers. The short processing time limits the diffusion length of the chemical elements from the polymer into the superconducting grains. Therefore, in addition to doping with carbon, the rest of the components create pinning centers along the polymeric chain, able to better pin the flux lines. The copolymerization allowed us to obtain both linear and cyclic copolymers as well as to control the content of chemical elements, including the presence of small amounts of iron oxides. The latter are responsible for magnetic pinning.

In this paper, we demonstrate that, by continuous single beam excitation, one can generate an abnormal anti-Stokes Raman emission (AASRE) whose properties are similar to a coherent anti-Stokes Raman scattering (CARS). The effect has been observed in materials which possess intrinsically nonlinear properties (LiNbO(3) and CdS), which have the electric susceptibility of third order different from zero, chi((3)) not equal 0, as well as in materials that become nonlinear under resonant optical excitation. In the latter case, we used poly-3,4-ethylendioxythiophene (PEDOT) in its undoped state deposited electrochemically on Au support. Raman studies corroborated with images of optical microscopy demonstrate that the production of AASRE is conditioned by the existence of a particular morphology of the sample able to ensure efficient transport of the light inside the sample through a multiple light scattering mechanism. In this context, it was found that LiNbO3 and CdS in powder form as well as the PEDOT films layered on a rough Au substrate are suitable morphological forms. We explain AASRE as resulting from a wave-mixing mechanism of the incident laser light omega(l) with a Stokes-shifted Raman light omega(S) produced by a spontaneous Raman light scattering process, both strongly scattered inside the sample. As a CARS process, AASRE is conditioned by the achievement of phase-matching requirements, which makes the difference between the wave vectors of mixing light close to zero, Delta k = /2k(l) - k(S) - k(CARS) /approximate to 0. In condensed media, the small dispersion of the refractive index makes Delta k approximate to 0 so that the formation of a favourable phase-matching geometry may be accomplished even at a crossing angle. of travelling scattered light omega(l) and omega(S). For tightly focused beams, the requirement of phase matching relaxes; it is no longer sensitive to the Raman shift, so that a wide intense anti-Stokes Raman spectrum is observed at an angle larger than the Stokes Raman spectrum.

A passively Q-switched Nd:YAG/Cr4+:YAG micro-laser with three-beam output was realized. A single active laser source made of a composite, all-ceramics Nd: YAG/Cr4+:YAG monolithic cavity was pumped by three independent lines. At 5 Hz repetition rate, each line delivered laser pulses with similar to 2.4 mJ energy and 2.8-MW peak power. The M-2 factor of a laser beam was 3.7, and stable air breakdowns were realized. The increase of pump repetition rate up to 100 Hz improved the laser pulse energy by 6% and required similar to 6% increase of the pump pulse energy. Pulse timing of the laser-array beams can by adjusted by less than 5% tuning of an individual line pump energy, and therefore simultaneous multi-point ignition is possible. This kind of laser can be used for multi-point ignition of an automobile engine. (C) 2011 Optical Society of America

A highly durable and versatile micro scale biocatalytic reactor has been designed and investigated in the heterogeneous enzyme-catalytic oxidation of phenols. It consisted of optical or electron beam lithographic gold deposited layer with different thickness from nano- to micro-scale on a semiconductor surface. Horseradish peroxidase (H RP) enzyme was immobilized on the gold-surface using two different approaches (i.e., physical adsorption and self-assembled monolayer). Characterization of those HRP-gold surfaces was made using AFM (atomic force microscopy) coupled with ellipsometry measurements, SEM (scanning electron microscopy), STM (scanning tunneling microscopy) and spectrophotometric technique. The catalytic performances of the developed structures were investigated after their incorporation in microreactors using a recycling-flow system dedicated to phenols oxidation. In order to optimize the efficiency of the oxidation process it was checked the effect of the successively addition of the reagent, the influence of the reaction time, the stability and the reuse of the biocatalytic micro-system. Maximum phenol conversion was of 35.1%. In addition to phenol the system has also been investigated in oxidation of other phenolic compounds such as cathecol, hydroquinone, rezorcine, beta-naphtol, o/p-aminophenol and 4-metoxyphenol. (C) 2011 Elsevier B.V. All rights reserved.

The telomerization of 1,3-butadiene with homogeneous palladium/phosphine catalysts is an efficient method to transform biomass-based oxygenates into useful fine and bulk chemicals, e.g. surfaetants. Recovery and reuse of the expensive noble metal-based catalyst is highly desired for these systems and therefore a heterogeneous telomerization catalyst would be preferred. Layered double hydroxides (LDH) were investigated as supports for the heterogenization of the Pd/TPPTS (trisodium salt of 3, 3',3 ''-phosphanetriyl benzene sulfonic acid) telomerization catalyst. Turn over numbers (TONs) up to 1300 were obtained with heterogeneous (immobilized palladium and ligand) and pseudo-heterogeneous (immobilized ligand) catalysts in the telomerization of 1,3-butadiene with ethylene glycol (EG) and methanol (MeOH) under solvent- and base-free conditions; TONs are comparable to those obtained with the homogeneous catalysts under similar conditions. Importantly, the LDH support was found to induce a change in product selectivity. In addition to the expected C8 telomers, higher telomers with C16 or C24 chains were observed with rather high selectivities (up to 48% forEG and 77% for MeOH).

Clean Si(001) single crystal surfaces are obtained by cycles of long (30 mins.) annealings in ultrahigh vacuum (fairly below 1 x 10(-9) mbar). The surface reconstruction is investigated by low energy electron diffraction (LEED). This paper reports, in addition to the well-known p(2 x 1) reconstruction, the first observation of c(4 x 2) at room temperature and also the completely new c(6 x 2) reconstruction. The in situ oxidation of these surfaces was investigated by Auger electron spectroscopy (AES) and by X-ray photoelectron spectroscopy (XPS). It is found that, in similar ultrahigh vacuum conditions (6 x 10(-10) mbar), much faster contamination (about 500 times) occurs when the samples are investigated by AES than by XPS, owing mainly to the interaction of the electron beam with the sample surface. Also, much gentler surface bombardment with electrons, such as in LEED, still enhances sample oxidation. Therefore, XPS proves to be a much more convenient technique for non-destructive assessment of the surface composition. When the surface is subjected to the AES investigation, we found that the contamination occurs by forming >Si2C=O complexes based on the Si dimers.