National Institute Of Materials Physics - Romania

Publications

5714 articles found

2891. Coulomb interaction and transient charging of excited states in open nanosystems

Authors: Moldoveanu, V; Manolescu, A; Tang, CS; Gudmundsson, V

Published: APR 15 2010, PHYSICAL REVIEW B, 81, DOI: 10.1103/PhysRevB.81.155442

We obtain and analyze the effect of electron-electron Coulomb interaction on the time-dependent current flowing through a mesoscopic system connected to biased semi-infinite leads. We assume the contact is gradually switched on in time and we calculate the time-dependent reduced density operator of the sample using the generalized master equation. The many-electron states (MES) of the isolated sample are derived with the exact-diagonalization method. The chemical potentials of the two leads create a bias window which determines which MES are relevant to the charging and discharging of the sample and to the currents, during the transient or steady states. We discuss the contribution of the MES with fixed number of electrons N and we find that in the transient regime there are excited states more active than the ground state even for N=1. This is a dynamical signature of the Coulomb-blockade phenomenon. We discuss numerical results for three sample models: short one-dimensional chain, two-dimensional (2D) lattice, and 2D parabolic quantum wire.

2892. Engineered beam shaping effect in anisotropic photonic crystals

Authors: Rasoga, O; Dragoman, D

Published: APR 10 2010, APPLIED OPTICS, 49, 2167, DOI: 10.1364/AO.49.002161

We demonstrate that an anisotropic photonic crystal can modify the shape of a highly convergent incident optical beam. The beam shape engineering is relatively easy, and the photonic crystal is less alignment demanding than beam shapers that incorporate several optical systems. The shape of the output beam can be controlled by an appropriate choice of the angular divergence of the beam, the number of periods and the birefringence values and layer widths of the constituent materials. (C) 2010 Optical Society of America

2893. Second-harmonic generation of 400nm blue-violet light in Gd1-xRxCa4O(BO3)(3) (R = Lu, Sc) crystals through noncritical phase-matching

Authors: Gheorghe, L; Loiseau, P; Aka, G

Published: APR 2010, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 12, 823, DOI:

The optical birefringence of Gd1-xRxCa4O(BO3)(3) (R = Lu or Sc) crystals can be controlled by changing the compositional parameter x. Two nonlinear crystals of Gd0.884Lu0.116Ca4O(BO3)(3) and Gd0.952Sc0.048Ca4O(BO3)(3) with large size and good quality have been grown by Czochralski method. According to our assumptions, the obtained results demonstrate that both crystals convert the near-infrared radiation of 800nm into blue-violet light (400nm) by type-I noncritical phase-matching (NCPM) second-harmonic generation (SHG) processes along Y axis.

2894. Involvement of cyan and ester groups in surface interactions of aerosil-cyanophenyl alkyl benzoate systems with high silica density: Infrared investigations

Authors: Frunza, L; Frunza, S; Zgura, I; Beica, T; Gheorghe, N; Ganea, P; Stoenescu, D; Dinescu, A; Schonhals, A

Published: APR 2010, SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 75, 1235, DOI: 10.1016/j.saa.2009.12.029

Composites prepared from aerosil A380 and liquid crystals (LCs) of 4-n-alkyl-4'-cyanophenyl benzoate type, with four to six carbon atoms in the alkyl chain were investigated by infrared spectroscopy. Their high silica content (of 2-7 g aerosil/1 g of LC) was given by thermogravimetric investigations and allows the observation of a rather thin LC layer on the silica particles. Several surface species onto the external surface of the grains were demonstrated. Arguments are given that monomer and dimer species are present in the bulk cyanophenyl benzoate materials while bulk-like species along with hydrogen-bonded ones coexist in the so-called surface layer of the composites. The main interaction of LC molecules with the aerosil surface is by hydrogen bonding taking place with the involvement of the cyan group. There is a contribution of ester carbonyl group to these surface interactions but this cannot be well quantified. (C) 2009 Elsevier B.V. All rights reserved.

2895. Biomineralization capability of adherent bio-glass films prepared by magnetron sputtering

Authors: Stan, GE; Pina, S; Tulyaganov, DU; Ferreira, JMF; Pasuk, I; Morosanu, CO

Published: APR 2010, JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 21, 1055, DOI: 10.1007/s10856-009-3940-9

Radiofrequency magnetron sputtering deposition at low temperature (150A degrees C) was used to deposit bioactive glass coatings onto titanium substrates. Three different working atmospheres were used: Ar 100%, Ar + 7%O(2), and Ar + 20%O(2). The preliminary adhesion tests (pull-out) produced excellent adhesion values (similar to 75 MPa) for the as-deposited bio-glass films. Bioactivity tests in simulated body fluid were carried out for 30 days. SEM-EDS, XRD and FTIR measurements were performed. The tests clearly showed strong bioactive features for all the prepared films. The best biomineralization capability, expressed by the thickest chemically grown carbonated hydroxyapatite layer, was obtained for the bio-glass coating sputtered in a reactive atmosphere with 7% O(2).

2896. Left-handed structures for microwave applications

Authors: Mihai, IA; Banciu, MG; Ioachim, A; Militaru, N; Lojewski, G; Petrescu, T

Published: APR 2010, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 12, 908, DOI:

In this paper, dispersion/attenuation diagrams are investigated for purely left-handed (PLH) and for composite right/left handed (CRLH) transmission lines. The magnitude and phase of the S parameters of these structures are analyzed in a broadband (1-7 GHz) range. The investigations on microstrip CRLH lines demonstrate the presence of the left-handed range, the stop-band (only for the unbalanced lines) and the right-handed range. By edge-coupling two such CRLH lines, devices with new properties, different from conventional microstrip devices were obtained. Symmetric and asymmetric 0 dB backward couplers working in the stop-band of the CRLH line were achieved. Very short 3 dB couplers (with only 2 or 3 unit cells) were also investigated.

2897. Modifications of the Catalytic Activity for Cyanoethylation Induced by the Memory Effect of Mg/Al-Type Modified Hydrotalcites

Authors: Pavel, OD; Birjega, R; Angelescu, E; Zavoianu, R; Florea, M; Mitran, G

Published: APR 2010, , DOI:

2898. Design of microwave bandpass filters with cross couplings, using electromagnetic field simulation and linear circuit optimization

Authors: Militaru, N; Lojewski, G; Banciu, MG

Published: APR 2010, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 12, 912, DOI:

In this paper a band-pass filter in microstrip technology, with cross couplings and with a pair of attenuation poles, is investigated. The equi-ripple in-band response and the location of the poles on the frequency axis can be precisely controlled through a new technique which combines accurate electromagnetic-field simulation and fast linear circuit optimization, allowing this way the design of band-pass filters with improved performances. To illustrate the procedure, a microstrip band-pass filter was designed, verified by em-field simulation, fabricated and tested. The response of the designed filter is in good agreement with the specification, confirming the possibilities of realizing microwave band-pass filters with rigorously controlled characteristics, with reduced design time and non-prohibitive computational effort.

2899. Multisegment CdTe nanowire homojunction photodiode

Authors: Matei, E; Ion, L; Antohe, S; Neumann, R; Enculescu, I

Published: MAR 12 2010, NANOTECHNOLOGY, 21, DOI: 10.1088/0957-4484/21/10/105202

Electrochemical deposition in nanoporous ion track membranes is used for the preparation of multisegment CdTe-homojunction diode nanowires. Our study is based on the fact that the deposition overpotential strongly influences the composition of the compound semiconductor nanowires. Therefore, the transport behavior of the nanowire devices can be tailored by appropriately choosing a certain sequence of electrodeposition potentials. The wires were characterized using scanning electron microscopy, energy dispersive x-ray analysis, optical spectroscopy and x-ray diffraction. The current-voltage characteristics measured prove that, by appropriately choosing the voltage pulse pattern, one can fabricate nanowires with ohmic or rectifying behavior. The semiconducting nanowires are sensitive to light, their spectral sensitivity being characteristic of CdTe. The preparation of functional nanostructures in such a simple approach provides, as a major advantage, an increase in the process reproducibility and opens a wide field of potential optoelectronic applications.

2900. MAPLE deposited thin monomer films of maleimidic derivatives for photonics

Authors: Stanculescu, A; Albu, AM; Socol, G; Stanculescu, F; Socol, M; Preda, N; Rasoga, O; Girtan, M; Iulian, I

Published: MAR 2010, JOURNAL OF OPTOELECTRONICS AND ADVANCED MATERIALS, 12, 739, DOI:

This paper presents a study of some thin monomer films deposited by MAPLE. These monomers have been synthesised from maleic anhydride and aniline derivatives and are characterized by a molecular structure adequate for the generation of optical non-linear phenomena. UV-VIS, FTIR, Raman and Photoluminescence spectroscopy have been used to investigate the influence of the experimental conditions on the properties of the films. X-Ray Diffraction has evidenced a certain degree of disorder in the thin films, which is correlated with the randomly orientated molecules and AFM images have revealed different roughness for different monomer layers and different substrates. Second harmonic measurements have shown a strong signal emitted by the thin film prepared from the monomer with one [-NH-NH-] donor and two [-NO(2)] acceptor groups. This thin film is characterized by good transparency and low photoluminescence emission at excitation with the wavelength of the second harmonic (lambda-400 nm).